全文获取类型
收费全文 | 7947篇 |
免费 | 540篇 |
国内免费 | 26篇 |
专业分类
化学 | 6272篇 |
晶体学 | 53篇 |
力学 | 98篇 |
数学 | 992篇 |
物理学 | 1098篇 |
出版年
2023年 | 73篇 |
2022年 | 95篇 |
2021年 | 131篇 |
2020年 | 268篇 |
2019年 | 235篇 |
2018年 | 106篇 |
2017年 | 108篇 |
2016年 | 308篇 |
2015年 | 308篇 |
2014年 | 354篇 |
2013年 | 404篇 |
2012年 | 540篇 |
2011年 | 604篇 |
2010年 | 338篇 |
2009年 | 301篇 |
2008年 | 462篇 |
2007年 | 431篇 |
2006年 | 384篇 |
2005年 | 352篇 |
2004年 | 335篇 |
2003年 | 256篇 |
2002年 | 248篇 |
2001年 | 158篇 |
2000年 | 121篇 |
1999年 | 106篇 |
1998年 | 103篇 |
1997年 | 112篇 |
1996年 | 100篇 |
1995年 | 103篇 |
1994年 | 114篇 |
1993年 | 84篇 |
1992年 | 73篇 |
1991年 | 72篇 |
1990年 | 66篇 |
1989年 | 69篇 |
1988年 | 53篇 |
1987年 | 50篇 |
1986年 | 41篇 |
1985年 | 35篇 |
1984年 | 36篇 |
1983年 | 21篇 |
1982年 | 25篇 |
1981年 | 38篇 |
1980年 | 33篇 |
1979年 | 29篇 |
1978年 | 37篇 |
1977年 | 33篇 |
1976年 | 27篇 |
1974年 | 17篇 |
1973年 | 15篇 |
排序方式: 共有8513条查询结果,搜索用时 15 毫秒
61.
Matthias Gelbrich 《Mathematische Nachrichten》1990,147(1):185-203
For a separable metric space (X, d) Lp Wasserstein metrics between probability measures μ and v on X are defined by where the infimum is taken over all probability measures η on X × X with marginal distributions μ and v, respectively. After mentioning some basic properties of these metrics as well as explicit formulae for X = R a formula for the L2 Wasserstein metric with X = Rn will be cited from [5], [9], and [21] and proved for any two probability measures of a family of elliptically contoured distributions. Finally this result will be generalized for Gaussian measures to the case of a separable Hilbert space. 相似文献
62.
Ronny Kleinhempel Gunar Kaune Matthias Herrmann Hartmut Kupfer Walter Hoyer Frank Richter 《Mikrochimica acta》2006,156(1-2):61-67
Indium tin oxide (ITO) thin films were deposited by mid frequency pulsed dual magnetron sputtering using a metallic alloy
target with 10 wt.% tin in an atmosphere of argon and oxygen. The aim of the work was to study the interdependence of structural,
electrical and optical properties of ITO films deposited in the reactive and transition target mode, respectively. The deposition
rate in the transition mode exceeds the deposition rate in the reactive mode by a factor of six, a maximum value of 100 nm·m min−1 could be achieved. This corresponds to a static deposition rate of 200 nm min−1. The lowest electrical resistivity of 1.1·10−3 Ω cm was measured at samples deposited in the high oxygen flow range in the transition mode. The samples show a good transparency
in the visible range corresponding to extinction coefficients being below 10−2. X-ray diffraction was used to characterise crystalline structure as well as film stress. ITO films prepared in the transition
mode show a slightly preferred orientation in (211) direction, whereas films deposited in the reactive mode are strongly (222)
oriented. Compared to undoped In2O3 all samples have an enlarged lattice. The lattice strain perpendicular to the surface is about 0.8% and 2.0% for films grown
in the transition and the reactive mode, respectively. Deposition in the transition mode introduces a biaxial film stress
in the range of −300 MPa, while stress in reactive mode samples is −1500 MPa. 相似文献
63.
64.
The equilibrium phase behavior of a binary mixture of charged colloids and neutral, nonadsorbing polymers is studied within free-volume theory. A model mixture of charged hard-sphere macroions and ideal, coarse-grained, effective-sphere polymers is mapped first onto a binary hard-sphere mixture with nonadditive diameters and then onto an effective Asakura-Oosawa model [S. Asakura and F. Oosawa, J. Chem. Phys. 22, 1255 (1954)]. The effective model is defined by a single dimensionless parameter-the ratio of the polymer diameter to the effective colloid diameter. For high salt-to-counterion concentration ratios, a free-volume approximation for the free energy is used to compute the fluid phase diagram, which describes demixing into colloid-rich (liquid) and colloid-poor (vapor) phases. Increasing the range of electrostatic interactions shifts the demixing binodal toward higher polymer concentration, stabilizing the mixture. The enhanced stability is attributed to a weakening of polymer depletion-induced attraction between electrostatically repelling macroions. Comparison with predictions of density-functional theory reveals a corresponding increase in the liquid-vapor interfacial tension. The predicted trends in phase stability are consistent with observed behavior of protein-polysaccharide mixtures in food colloids. 相似文献
65.
Trace analysis of rapamycin in human blood by micellar electrokinetic chromatography 总被引:1,自引:0,他引:1
A capillary electrophoretic method with UV detection at 278 nm has been developed for analysis of the immunosuppressant rapamycin (sirolimus) in human blood at low microgram per liter levels. Separation has been achieved in an acidic carrier electrolyte containing sodium dodecylsulfate and 30% (v/v) acetonitrile. For sample clean-up and preconcentration, an off-line solid-phase extraction step using a silica-based reversed-phase material and an on-capillary focussing technique were employed. The latter allows the injection of increased sample volumes without excessive band broadening. Although this new method is less sensitive than existing liquid chromatographic procedures combined with mass spectrometry, it is fully suited to routine analysis of rapamycin in blood from patients treated with this drug. Last but not least the low costs make it an attractive alternative to established methods. 相似文献
66.
Horn M Ihringer J Glink PT Stoddart JF 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(17):4046-4054
A template-directed dynamic clipping procedure has generated a library of nine [2]rotaxanes that have been formed from three dialkylammonium salts-acting as the dumbbell-shaped components-and three dynamic, imino bond-containing, [24]crown-8-like macrocycles-acting as the ring-shaped components-which are themselves assembled from three dialdehydes and one diamine. The rates of formation of these [2]rotaxanes differ dramatically, from minutes to days depending on the choice of dialkylammonium ion and dialdehyde, as do their thermodynamic stabilities. Generally, [2]rotaxanes formed by using 2,6-diformylpyridine as the dialdehyde component, or bis(3,5-bis(trifluoromethyl)benzyl)ammonium hexafluorophosphate as the dumbbell-shaped component, assembled the most rapidly. Those rotaxanes containing this particular electron-deficient dumbbell-shaped unit, or 2,5-diformylfuran units in the macroring, were the most stable thermodynamically. The relative thermodynamic stabilities of all nine of the [2]rotaxanes were determined by competition experiments that were monitored by (1)H NMR spectroscopy. 相似文献
67.
68.
69.
S. Barlag H. Becker T. Böhringer M. Bosman V. Castillo V. Chabaud D. Buchholz C. Damerell C. Daum H. Dietl H. Fawcett S. Gill A. Gillman R. Gilmore T. Gooch L. Görlich P. Gras Z. Hajduk E. Higon B. D. Hyams D. P. Kelsey J. Kemmer R. Klanner U. Kötz S. Kwan B. Lücking G. Lütiens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson G. De Rijk K. Rybicki H. J. Seebrunner U. Stierlin H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1987,37(1):17-23
We have measured the lifetimes of hadronically produced charged and neutralD mesons using silicon microstrip detectors and an active silicon target in the NA32 spectrometer at the CERN SPS. We obtainτ D± = (10.9± 1.5 1.9 )·10?13s andτ D (?)10 = (4.2±0.5)·10?13s based on 59 and 90 fully reconstructed decays respectively, giving a ratioτ D±/τ D (?)10 of 2.6 ±0.5. 相似文献
70.
H. Dijkstra R. Bailey E. Belau T. Böhringer M. Bosman V. Chabaud C. Damerell C. Daum G. de Rijk S. Gill A. Gillman R. Gilmore Z. Hajduk C. Hardwick W. Hoogland B. D. Hyams R. Klanner S. Kwan U. Kötz G. Lütjens G. Lutz J. Malos W. Männer E. Neugebauer H. Palka M. Pepé J. Richardson K. Rybicki H. J. Seebrunner U. Stierlin R. J. Tapper H. G. Tiecke M. Turala G. Waltermann S. Watts P. Weilhammer F. Wickens L. W. Wiggers A. Wylie T. Zeludziewicz ACCMOR Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,32(3):353-358
The joint production of ? mesons andπ ±,π 0,p, \(\bar p\) ,K s 0 andK ± is investigated using a sample of 600,000 inclusive ? meson events obtained in hadron Be interactions with incidentπ ±,p, \(\bar p\) andK ± beams. Evidence is presented for the joint production of ? mesons and strange particles produced with non-strange incident beams. With incidentK ± beam the number of additional strange particles is suppressed. The results are found to be in agreement with the qualitative predictions of a parton fusion model. The comparison with the Lund model for lowp T processes is fair. 相似文献