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61.
Schanda P Meier BH Ernst M 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,210(2):246-259
The accurate experimental determination of dipolar-coupling constants for one-bond heteronuclear dipolar couplings in solids is a key for the quantification of the amplitudes of motional processes. Averaging of the dipolar coupling reports on motions on time scales up to the inverse of the coupling constant, in our case tens of microseconds. Combining dipolar-coupling derived order parameters that characterize the amplitudes of the motion with relaxation data leads to a more precise characterization of the dynamical parameters and helps to disentangle the amplitudes and the time scales of the motional processes, which impact relaxation rates in a highly correlated way. Here. we describe and characterize an improved experimental protocol--based on REDOR--to measure these couplings in perdeuterated proteins with a reduced sensitivity to experimental missettings. Because such effects are presently the dominant source of systematic errors in experimental dipolar-coupling measurements, these compensated experiments should help to significantly improve the precision of such data. A detailed comparison with other commonly used pulse sequences (T-MREV, phase-inverted CP, R18(2)(5), and R18(1)(7)) is provided. 相似文献
62.
The charge-density-wave phase of TiSe(2) was studied by angle-resolved photoelectron spectroscopy and resistivity measurements investigating the influence of the band gap size and of a varying population of the conduction band. A gradual suppression of the charge-density-wave-induced electronic superstructure is observed for a variation of the band gap in the ternary compounds TiC(x)Se(2-x) with C=(S,Te) as well as for an occupation of only the conduction band by H(2)O adsorption-induced band bending. These observations point to an optimum band gap and support an excitonic driving force for the charge-density wave. 相似文献
63.
Reconstruction of dynamic contrast enhanced magnetic resonance imaging of the breast with temporal constraints 总被引:1,自引:0,他引:1
A number of methods using temporal and spatial constraints have been proposed for reconstruction of undersampled dynamic magnetic resonance imaging (MRI) data. The complex data can be constrained or regularized in a number of different ways, for example, the time derivative of the magnitude and phase image voxels can be constrained separately or jointly. Intuitively, the performance of different regularizations will depend on both the data and the chosen temporal constraints. Here, a complex temporal total variation (TV) constraint was compared to the use of separate real and imaginary constraints, and to a magnitude constraint alone. Projection onto Convex Sets (POCS) with a gradient descent method was used to implement the diverse temporal constraints in reconstructions of DCE MRI data. For breast DCE data, serial POCS with separate real and imaginary TV constraints was found to give relatively poor results while serial/parallel POCS with a complex temporal TV constraint and serial POCS with a magnitude-only temporal TV constraint performed well with an acceleration factor as large as R=6. In the tumor area, the best method was found to be parallel POCS with complex temporal TV constraint. This method resulted in estimates for the pharmacokinetic parameters that were linearly correlated to those estimated from the fully-sampled data, with Ktrans,R=6=0.97 Ktrans,R=1+0.00 with correlation coefficient r=0.98, kep,R=6=0.95 kep,R=1+0.00 (r=0.85). These results suggest that it is possible to acquire highly undersampled breast DCE-MRI data with improved spatial and/or temporal resolution with minimal loss of image quality. 相似文献
64.
T. Engel M. Würtz S. Borneis St. Becker I. Klaft A. Kohl T. Kühl F. Laeri D. Marx K. Meier R. Neumann F. Schmitt P. Seelig L. Völker 《Hyperfine Interactions》1997,108(1-3):251-258
Laser spectroscopy at storage rings often suffers from a limited resolution due to Doppler-broadened resonances. Broadening
is caused by the velocity spread of the ions stored in the beam. In the following, the present status of our work on laser
systems specialized on the specific needs of laser spectroscopy at storage rings is reported.
Two pulsed laser systems were developed. One is a dye laser whose spectral bandwidth can be switched by inserting different
Littrow-prisms into the resonator. An increase in bandwidth up to a factor of 45 was achieved. This laser was used for fast
qualitative scans and high resolution measurements. The other laser system is a Nd : YAG laser pumped optical parametric oscillator.
It is a tunable laser system covering the spectral range from 410 to 4000 nm. Furthermore, a continuous wave laser with a
frequency shifted feedback cavity is described. It shows broadband emission with an adjustable bandwidth of up to 4.5 GHz.
This laser can be advantageous for laser cooling of ion beams.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
65.
Romain Fardel Matthias Nagel Thomas Lippert Alexander Wokaun 《Applied Surface Science》2009,255(10):5430-5434
Thin films of a photodecomposible triazene polymer are used as sacrificial layer for the micro-deposition of sensitive materials by laser-induced forward transfer. To understand the ablation process of this sacrificial layer, the ultraviolet laser ablation of triazene films was investigated by time-resolved shadowgraphy. Irradiation from the film side shows a complete decomposition into gaseous fragments, while ablation through the substrate causes ejection of a solid flyer of polymer. The occurence of the flyer depends on the film thickness as well as on the applied fluence, and a compact flyer is obtaind when these two parameters are optimized. 相似文献
66.
Schmidt M Voth E Schneider CA Theissen P Wagner R Baer FM Schicha H 《Magnetic resonance imaging》2004,22(2):229-236
Identification of akinetic but viable myocardium is important for the selection of patients for coronary revascularization. In order to assess predictive values of end-diastolic wall thickness and dobutamine induced wall thickening obtained by magnetic resonance imaging (MRI) and [18F]Fluorodeoxyglucose uptake assessed by positron emission tomography (F-18-FDG-PET), these parameters were compared to recovery of left ventricular function after successful revascularization. Forty patients with chronic myocardial infarction and regional a- or dyskinesia by ventriculography underwent rest- and dobutamine-MRI studies (10 microg dobutamine/kg body weight/min) and F-18-FDG-PET. Viability of the infarct region was considered to be present if; 1) end-diastolic wall thickness was > or =5.5 mm; 2) dobutamine induced wall thickening > or =2 mm could be measured; and 3) normalized F-18-FDG-uptake was > or =50% in > or =50% of akinetic segments. Preserved end-diastolic wall thickness was found in 32/40 patients, functional improvement during dobutamine infusion in 26/40 patients and preserved F-18-FDG-uptake in 29/40 patients. After revascularization regional left ventricular function improved in 25/40 patients. Positive and negative predictive values and diagnostic accuracy were 78%, 100%, and 83% for preserved end-diastolic wall thickness, 92%, 93%, and 93% for dobutamine inducible contraction reserve and 86%, 100%, and 90% for preserved F-18-FDG-uptake. Quantitative assessment of dobutamine induced systolic wall thickening by MRI and F-18-FDG-uptake by PET are highly accurate techniques for the identification of viable myocardium and prediction of functional recovery after successful revascularization. Preserved end-diastolic wall thickness results in an overestimation of viable myocardium compared to functional improvement, but wall thickness <5.5 mm excludes recovery of regional function. 相似文献
67.
Electromagnetically induced transparency is an effect observed in atomic systems, originating from quantum interference, in which electromagnetic transitions to and from a certain quantum state become suppressed. This dark state is also characterized by a quantum phase, relative to other states, which theoretically should stop evolving, but remain phase coherent, during transparency. We test this theoretical prediction using techniques developed for liquid-state nuclear magnetic resonance quantum computation, applied to a spin-7/2 nuclear spin system. A sequence of quantum operations is applied to create the dark state, and during transparency its phase evolution is measured relative to a reference state using Ramsey interferometry. Experimental measurements of the fringe visibility are in excellent agreement with theoretical expectations, taking into account measured decoherence rates. 相似文献
68.
We use quantum Monte Carlo simulations to determine the finite temperature phase diagram and to investigate the thermal and quantum melting of stripe phases in a two-dimensional hard-core boson model. At half filling and low temperatures the stripes melt at a first order transition. In the doped system, the melting transitions of the smectic phase at high temperatures and the superfluid smectic (supersolid) phase at low temperatures are either very weakly first order, or of second order with no clear indications for an intermediate nematic phase. 相似文献
69.
We study the nature of the ground state of the two-dimensional extended boson Hubbard model on a square lattice by quantum Monte Carlo methods. We demonstrate that strong but finite on-site interaction U along with a comparable nearest-neighbor repulsion V result in a thermodynamically stable supersolid ground state for densities larger than 1/2, in contrast to fillings less than 1/2 or for very large U, where the checkerboard supersolid is unstable towards phase separation. We discuss the relevance of our results to realizations of supersolids using cold bosonic atoms in optical lattices. 相似文献
70.
We consider a magnetic impurity coupled to both fermionic quasiparticles with a pseudogap density of states and bosonic spin fluctuations. Using renormalization group and large-N calculations we investigate the phase diagram of the resulting Fermi-Bose Kondo model. We show that the Kondo temperature is strongly reduced by low-energy spin fluctuations, and make connections to experiments in cuprate superconductors. Furthermore, we derive an exact exponent for the critical behavior of the conduction electron T matrix, and propose our findings to be relevant for certain scenarios of local quantum criticality in heavy-fermion metals. 相似文献