On then-cutset property

For a partially ordered setP and an elementx ofP, a subsetS ofP is called a cutset forx inP if every element ofS is noncomparable tox and every maximal chain ofP meets {x}∪S. We letc(P) denote the smallest integerk such that every elementx ofP has a cutsetS with ‖S‖?k: Ifc(P)?n we say thatP has then-cutset property. Our results bear on the following question: givenP, what is the smallestn such thatP can be embedded in a partially ordered set having then-cutset property? As usual, 2 ⁿ denotes the Boolean lattice of all subsets of ann-element set, andB _n denotes the set of atoms and co-atoms of 2 ⁿ . We establish the following results: (i) a characterization, by means of forbidden configurations, of whichP can be embedded in a partially ordered set having the 1-cutset property; (ii) ifP contains a copy of 2 ⁿ , thenc(P)?2^[n/2]?1; (iii) for everyn>3 there is a partially ordered setP containing 2 ⁿ such thatc(P)<c(2 ⁿ ); (iv) for every positive integern there is a positive integerN such that, ifB _m is contained in a partially ordered set having then-cutset property, thenm?N.     

Converged properties of clean metal surfaces by all-electron first-principles calculations

All-electron full-potential linearized augmented plane-wave calculations of the surface energy, work function, and interlayer spacings of close-packed metal surfaces are presented, in particular, for the free-electron-like metal surfaces, Mg(0 0 0 1) and Al(1 1 1), and for the transition metal surfaces, Ti(0 0 0 1), Cu(1 1 1), Pd(1 1 1), and Pt(1 1 1). We investigate the convergence of the surface energy as a function of the number of layers in the slab, using the Cu(1 1 1) surface as an example. The results show that the surface energy, as obtained using total energies of the slab and bulk from separate calculations, converges well with respect to the number of layers in the slab. Obviously, it is necessary that bulk and surface calculations are performed with the same high accuracy. Furthermore, we discuss the performance of the local-density and generalized gradient approximations for the exchange-correlation functional in describing the various surface properties.     

Infinite products for power series

An algorithm is introduced and shown to lead to a unique infinite product representation for a given formal power series A(z) with A(0) = 1. The infinite product is , where all b_n ≠ 0, r_n , and r_n+1 > r_n. The degree of approximation by the polynomial (1 + b₁z^r₁) · · · (1 + b_nz^r_n) is also considered.     

A C-symplectic free -manifold with contractible orbits and

An interesting question in symplectic geometry concerns whether or not a closed symplectic manifold can have a free symplectic circle action with orbits contractible in the manifold. Here we present a c-symplectic example, thus showing that the problem is truly geometric as opposed to topological. Furthermore, we see that our example is the only known example of a c-symplectic manifold having non-trivial fundamental group and Lusternik-Schnirelmann category precisely half its dimension.

     

Fluorinations with complex metal fluorides. Part 6 [1] fluorination of yridine and related compounds with caesium tetrafluorocobaltate(III) [2]

Pyridine has been fluorinated over caesium tetrafluorocobaltate(III) (CsCo^IIIF₄) at 300–400°C to give a mixture of undecafluoro-N-methylpyrrolidine, bis(trifluoromethyl)amine, pentafluoropyridine and several polyfluoropyridines; the product composition depended to some extent on the geometry of the reactor. The fluorinations of pentafluoropyridine, piperidine and undecafluoropiperidine were also investigated.     

Approximately Optimal Recovery of a Multicohort Fishery from Depleted Stocks and Excess Vessel Capacity

Journal of the Operational Research Society - The effect of current harvesting on future fish stocks is best captured with a multicohort model. In principle, numerical dynamic programming can be...