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991.
One-pot reduction/allylic diazene rearrangement of lactic acid- and mandelic acid-derived alpha,beta-unsaturated tosyl hydrazones leads to 1,4-syn- or 1,4-anti-E-2-alkenyl arrays in high yield and diastereoselectivity. Either the syn or the anti diastereomer can be prepared by choosing the appropriate alkene stereoisomer of the hydrazone. The E-alkenes led to the 1,4-syn isomers, while the Z-alkenes led to the 1,4-anti isomers, both with > or =20:1 diastereoselectivity. 相似文献
992.
Room-temperature ring-closing alkyne metathesis of 1,2-, 1,3-, and 1,4-bis(3-pentynyloxymethyl)benzenes has been investigated in the presence of catalytic amounts of an imidazolin-2-iminato tungsten alkylidyne complex. The m- and p-diynes selectively form the respective [10]metacyclophane or [10.10]paracyclophane, respectively, whereas a mixture of monomeric and dimeric cycloalkynes is obtained in the case of the o-diyne. DFT calculations reveal that the different selectivities can be attributed to the relative thermodynamic stability of the emerging cyclophanes. 相似文献
993.
Matthias Kurzke 《Journal of Functional Analysis》2008,255(3):535-588
We consider the Gamma limit of the Abelian Chern-Simons-Higgs energy
994.
We characterize the domain of the realizations of a linear parabolicoperator defined in L2 spaces with respect to a suitable measurethat is invariant for the associated evolution semigroup. Asa byproduct, we obtain optimal L2 regularity results for evolutionequations with time-dependant Ornstein–Uhlenbeck operators. 相似文献
995.
Cotí KK Wang Y Lin WY Chen CC Tak For Yu Z Liu K Shen CK Selke M Yeh A Lu W Tseng HR 《Chemical communications (Cambridge, England)》2008,(29):3426-3428
A new type of dynamic micromixer combining the concepts of parallel multi-lamination and hydrodynamic focusing was developed for arbitrary control of disguised chemical selectivity. 相似文献
996.
997.
The geometry of Re2Cl82− has been optimized for the eclipsed (D
4h
) equilibrium conformation and for the staggered (D
4d
) conformation at BP86/TZ2P. The nature of the Re–Re bond which has a formal bond order four has been studied with an energy
decomposition analysis (EDA). The EDA investigation indicates that the contribution of the b
2 (δ
xy
) orbitals to the Re–Re bond in the ground state is negligibly small. The vertical excitation of one and two electrons from the bonding δ orbital into the antibonding δ* orbitals yielding the singly and doubly excited states and gives a destabilization of 17.5 and 36.1 kcal/mol, respectively, which is nearly the same as the total excitation energies.
The preference for the D
4h
geometry with eclipsing Re–Cl bonds is explained in terms of hyperconjugation rather than δ bonding. This is supported by the calculation of the triply bonded Re2Cl8 which also has an eclipsed energy minimum structure. The calculations also suggest that the Re–Re triple bond in Re2Cl8 is stronger than the Re–Re quadruple bond in Re2Cl82−. A negligible contribution of the δ orbital to the metal–metal bond strength is also calculated for Os2Cl8 which is isoelectronic with Re2Cl82−.
Contribution of the Mark S. Gordon 65th Birthday Festschrift Issue.
Theoretical Studies of Inorganic Compounds. 38. Part 37 (2006) Bessac F, Frenking G, Inorg Chem 45:6956. 相似文献
998.
999.
1000.