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41.
The unstable periodic orbits of a chaotic system provide an important skeleton of the dynamics in a chaotic system, but they can be difficult to find from an observed time series. We present a global method for finding periodic orbits based on their symbolic dynamics, which is made possible by several recent methods to find good partitions for symbolic dynamics from observed time series. The symbolic dynamics are approximated by a Markov chain estimated from the sequence using information-theoretical concepts. The chain has a probabilistic graph representation, and the cycles of the graph may be exhaustively enumerated with a classical deterministic algorithm, providing a global, comprehensive list of symbolic names for its periodic orbits. Once the symbolic codes of the periodic orbits are found, the partition is used to localize the orbits back in the original state space. Using the periodic orbits found, we can estimate several quantities of the attractor such as the Lyapunov exponent and topological entropy. 相似文献
42.
Ironside MS Stein RS Duer MJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,188(1):49-55
A key problem in solid-state NMR is resolving overlapping isotropic signals. We present here a two-dimensional method which can enable sites with the same isotropic chemical shift to be distinguished according to their chemical shift anisotropy and asymmetry. The method involves correlating sideband spectra at different effective spinning rates using CSA-amplification pulse sequences. The resulting two-dimensional correlation pattern allows very accurate determination of the chemical shift principal values in addition to the recovery of parameters for two overlapping patterns which allows the resolution of overlapping signals. 相似文献
43.
44.
Mild Bioconjugation Through the Oxidative Coupling of ortho‐Aminophenols and Anilines with Ferricyanide 下载免费PDF全文
Allie C. Obermeyer John B. Jarman Chawita Netirojjanakul Kareem El Muslemany Prof. Dr. Matthew B. Francis 《Angewandte Chemie (International ed. in English)》2014,53(4):1057-1061
Using a small‐molecule‐based screen, ferricyanide was identified as a mild and efficient oxidant for the coupling of anilines and o‐aminophenols on protein substrates. This reaction is compatible with thiols and 1,2‐diols, allowing its use in the creation of complex bioconjugates for use in biotechnology and materials applications. 相似文献
45.
Laura L. Adduci Dr. Matthew P. McLaughlin Trandon A. Bender Dr. Jennifer J. Becker Prof. Dr. Michel R. Gagné 《Angewandte Chemie (International ed. in English)》2014,53(6):1646-1649
The conversion of readily available cellulosic biomass to valuable feedstocks and fuels is an attrative goal but a challenging transformation that requires the cleavage of multiple nonactivated C? O bonds. Herein, the Lewis acid trispentafluorophenylborane (B(C6F5)3) is shown to catalyze the metal‐free hydrosilylative reduction of monosaccharides and polysaccharides to give hydrocarbons with reduced oxygen content. The choice of the silane reductant influences the degree of deoxygenation, with diethylsilane effecting the complete reduction to produce hexanes while tertiary silanes give partially deoxygenated tetraol and triol products. 相似文献
46.
Kanyal Supriya S. Jensen David S. Dadson Andrew E. Vanfleet Richard R. Davis Robert C. Linford Matthew R. 《平面色谱法杂志一现代薄层色谱法》2014,27(3):151-156
JPC – Journal of Planar Chromatography – Modern TLC - We describe the direct, conformal, atomic layer deposition (ALD) of silica onto carbon nanotubes (CNTs) in the microfabrication of... 相似文献
47.
Antonio Dell'Isola Dr. Matthew M. W. McLachlan Dr. Benjamin W. Neuman Hawaa M. N. Al‐Mullah Alexander W. D. Binks Warren Elvidge Dr. Kenneth Shankland Dr. Alexander J. A. Cobb 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(37):11685-11689
An efficient synthesis of spirocyclic triazolooxazine nucleosides is described. This was achieved by the conversion of β‐D ‐psicofuranose to the corresponding azido‐derivative, followed by alkylation of the primary alcohol with a range of propargyl bromides, obtained by Sonogashira chemistry. The products of these reactions underwent 1,3‐dipolar addition smoothly to generate the protected spirocyclic adducts. These were easily deprotected to give the corresponding ribose nucleosides. The library of compounds obtained was investigated for its antiviral activity using MHV (mouse hepatitis virus) as a model wherein derivative 3 f showed the most promising activity and tolerability. 相似文献
48.
Preparation of Stereoregular Isotactic Poly(mandelic acid) through Organocatalytic Ring‐Opening Polymerization of a Cyclic O‐Carboxyanhydride 下载免费PDF全文
Dr. Antoine Buchard Dr. David R. Carbery Prof. Matthew G. Davidson Dr. Petya K. Ivanova Dr. Ben J. Jeffery Dr. Gabriele I. Kociok‐Köhn Dr. John P. Lowe 《Angewandte Chemie (International ed. in English)》2014,53(50):13858-13861
Poly(mandelic acid) (PMA) is an aryl analogue of poly(lactic acid) (PLA) and a biodegradable analogue of polystyrene. The preparation of stereoregular PMA was realized using a pyridine/mandelic acid adduct (Py?MA) as an organocatalyst for the ring‐opening polymerization (ROP) of the cyclic O‐carboxyanhydride (manOCA). Polymers with a narrow polydispersity index and excellent molecular‐weight control were prepared at ambient temperature. These highly isotactic chiral polymers exhibit an enhancement of the glass‐transition temperature (Tg) of 15 °C compared to the racemic polymer, suggesting potential future application as high‐performance commodity and biomedical materials. 相似文献
49.
Simultaneous In Situ Quantification of Two Cellular Lipid Pools Using Orthogonal Fluorescent Sensors 下载免费PDF全文
Dr. Shu‐Lin Liu Dr. Ren Sheng Matthew J. O'Connor Yang Cui Dr. Youngdae Yoon Svetlana Kurilova Dr. Daesung Lee Dr. Wonhwa Cho 《Angewandte Chemie (International ed. in English)》2014,53(52):14387-14391
Lipids regulate a wide range of biological activities. Since their local concentrations are tightly controlled in a spatiotemporally specific manner, the simultaneous quantification of multiple lipids is essential for elucidation of the complex mechanisms of biological regulation. Here, we report a new method for the simultaneous in situ quantification of two lipid pools in mammalian cells using orthogonal fluorescent sensors. The sensors were prepared by incorporating two environmentally sensitive fluorophores with minimal spectral overlap separately into engineered lipid‐binding proteins. Dual ratiometric analysis of imaging data allowed accurate, spatiotemporally resolved quantification of two different lipids on the same leaflet of the plasma membrane or a single lipid on two opposite leaflets of the plasma membrane of live mammalian cells. This new imaging technology should serve as a powerful tool for systems‐level investigation of lipid‐mediated cell signaling and regulation. 相似文献