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61.
Atsuya Muranaka Yoshiaki Asano Akihiko Tsuda Atsuhiro Osuka Nagao Kobayashi 《Chemphyschem》2006,7(6):1235-1240
The electronic excited states of a meso-meso beta-beta doubly linked bis-porphyrin are comprehensively investigated by measuring its circular dichroism (CD) and magnetic circular dichroism (MCD) spectra. The observed spectroscopic properties are rationalized by DFT calculations. The frontier molecular orbitals (MOs) are constructed by the linear combinations of the constituent monomers' four MOs. Comparison of a theoretical CD spectrum based on time-dependent DFT (TDDFT) with the experimental spectra resulted in the assignment of the helical conformation of the dimer. This assignment is contrary to the previous assignment based on the point-dipole approximation (exciton coupling theory). 相似文献
62.
Uto Y Hirata A Fujita T Takubo S Nagasawa H Hori H 《The Journal of organic chemistry》2002,67(7):2355-2357
We have demonstrated that prenylation of p-halophenols was dependent on the solvent effect and succeeded in o,o'-diprenylation of p-halophenols in water. Following the Mizoroki-Heck coupling of the diprenyl-p-iodophenol 3c with methyl acrylate and then hydrolysis, we first synthesized artepillin C [3-(4-hydroxy-3,5-di(3-methyl-2-butenyl)phenyl)-2(E)-propenoic acid] (1), which is a biologically active constituent of propolis. These reactions may be applicable to the synthesis of various useful natural products such as 2,4,6-trisubstituted phenol derivatives. 相似文献
63.
Temperature sensitivity of Ge-B-SiO(2) waveguide Bragg gratings on a crystallized glass substrate 总被引:1,自引:0,他引:1
Waveguide Bragg gratings were fabricated by plasma-enhanced chemical-vapor deposition followed by irradiation with KrF excimer laser light through a phase mask. The period of the Bragg grating was 0.53 mum, and the Bragg wavelength was ~1.53 mum . The temperature dependence of the Bragg wavelength was 11 pm/ degrees C for a 10GeO(2) -90SiO(2)(mol.%) core waveguide on a Si substrate, and the Bragg wavelength shift was successfully reduced to 5.0pm/ degrees C by use of a 14GeO(2)-12B(2)O(3)-74SiO(2) (mol.%) core and a crystallized glass substrate with a thermal-expansion coefficient of -2.0x10(-6)(/ degrees C) . 相似文献
64.
Iyoda M Kondo T Nakao K Hara K Kuwatani Y Yoshida M Matsuyama H 《Organic letters》2000,2(14):2081-2083
1,8-[1,8-Naphthalenediylbis(4',4-biphenyldiyl)]naphthalene, a very stable strained cyclophane, has been synthesized in moderate yield using the copper-catalyzed coupling of 1, 8-bis(4-(tributylstannyl)phenyl)naphthalene. The X-ray analysis of the titled compound discloses bent p,p'-biphenylylene chains with splayed naphthalene rings, and the p,p'-biphenylylene chains located face-to-face indicate a fairly strong pi-pi interaction. 相似文献
65.
66.
Zusammenfassung Zusatz von Säure oder anorganischen Salzen, insbesondere von mehrwertigen Kationen, bewirkt die Fällung nichtionogener Tenside vom Typus des Polyoxyäthylens aus Wasser in Gegenwart von Polymersäuren wie Polyakrylsäure und Polymethakrylsäure, und zwar der Wirkung nach zunehmend mit der Temperatur. Die nichtionogenen Tenside bilden wasserlösliche Komplexe mit diesen Polymersäuren, und die Kationen und H+ veranlassen Kontraktion der Komplexe und führensomit zu ihrer Fällung. Die Rolle der Gegenionen (Anionen) ist bei hohen Salzkonzentrationen nicht zu vernachlässigen. Der Komplex von Polymersäure und nichtionogenen Tensiden mit län geren Polyoxyäthylenketten ist auf die Fällung hin sichtlich ihrer Zusätze weniger von Einfluß.
Mit 9 Abbildungen 相似文献
Summary Addition of acid or inorganic salts, particularly of polyvalent cations, causes precipitation of nonionic surfactants of the polyoxyethylene type from water in the presence of polymeric acids, such as polyacrylic and polymethacrylic acids. The precipitation takes place more remarkably at higher temperature. The non-ionics form water-soluble complexes with these polymeric acids, and the cations and H+ give rise to contraction of the complexes, thus leading them to precipitation. The counterions (anions) also play some part in the precipitation reaction at high salt concentrations. The complex of polymeric acid and nonionics with longer polyoxyethylene chains is less affected by these additives on precipitation.
Mit 9 Abbildungen 相似文献
67.
68.
The generation and recognition of a record-length 511-chip optical code is experimentally demonstrated by use of a superstructured fiber Bragg grating (SSFBG) with a chip rate of 640 Gchips/s. Very high reflectivity (92%) is achieved with high-quality correlation properties. The temperature deviation tolerance is approximately +/- 0.3 degrees C, which is within the package's temperature stability range (+/- 0.1 degrees C). Experimental results show good agreement with the theory. They indicate the SSFBG's potential for processing a long optical code with an ultrahigh chip rate, which could significantly improve the system's performance. 相似文献
69.
Akihiko Inoue 《Journal of multivariate analysis》2004,89(1):135-147
Let be a fractional ARIMA(p,d,q) process with partial autocorrelation function α(·). In this paper, we prove that if d∈(−1/2,0) then |α(n)|∼|d|/n as n→∞. This extends the previous result for the case 0<d<1/2. 相似文献
70.
Controllable photoinduced optical attenuation in a single-mode optical fiber by irradiation of a femtosecond pulse laser 总被引:1,自引:0,他引:1
Novel optical attenuation fibers were fabricated by the irradiation of a focused infrared femtosecond pulsed laser onto the core of a silica glass single-mode optical fiber. Optical attenuation at a wavelength of 1.55 microm proportionally increased with increasing numbers of irradiation points and was controllable under laser irradiation conditions. The single-mode property of the waveguide and the mode-field diameter of the optical fiber were maintained after irradiation of the femtosecond laser. It is suggested that the attenuation results from optical scattering at photoinduced spots formed inside the fiber core. 相似文献