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81.
A simple and expedient process for the Heck aminocarbonylative synthesis of Weinreb and MAP amide acylating agents, from aryl halides, is reported. This methodology utilizes solid sources of CO making it readily accessible to chemists working in small-scale laboratory applications. 相似文献
82.
Wang E Ma Z Zhang Z Henriksson P Inganäs O Zhang F Andersson MR 《Chemical communications (Cambridge, England)》2011,47(17):4908-4910
A new low band gap polymer (E(g) = 1.6 eV) with alternating thiophene and isoindigo units was synthesized and characterized. A PCE of 3.0% and high open-circuit voltage of 0.89 V were realized in polymer solar cells, which demonstrated the promise of isoindigo as an electron deficient unit in the design of donor-acceptor conjugated polymers for polymer solar cells. 相似文献
83.
Takwa M Larsen MW Hult K Martinelle M 《Chemical communications (Cambridge, England)》2011,47(26):7392-7394
Based on molecular modelling, the enzyme Candida antarctica lipase B was redesigned as a catalyst for the ring opening polymerization of D,D-lactide. Two mutants with 90-fold increased activity as compared to the wild-type enzyme were created. In a preparative synthesis of poly(D,D-lactide) the mutants greatly improved the rate and the degree of polymerization. 相似文献
84.
Unger EL Morandeira A Persson M Zietz B Ripaud E Leriche P Roncali J Hagfeldt A Boschloo G 《Physical chemistry chemical physics : PCCP》2011,13(45):20172-20177
The hole transporting medium in solid-state dye-sensitized solar cells can be utilized to harvest sunlight. Herein we demonstrate that a triphenylamine-based dye, used as hole-transporting medium, contributes to the photocurrent in a squaraine-sensitized solid-state dye-sensitized solar cell. Steady-state photoluminescence measurements have been used to distinguish between electron transfer and energy transfer processes leading to energy conversion upon light absorption in the hole-transporting dye. 相似文献
85.
In the recent paper [E. C. Balreira, S. Elaydi, and R. Luís, J. Differ. Equ. Appl. 23 (2017), pp. 2037–2071], Balreira, Elaydi and Luís established a good criterion for competitive mappings to have a globally asymptotically stable interior fixed point by a geometric approach. This criterion can be applied to three dimensional Kolmogorov competitive mappings on a monotone region with a carrying simplex whose planar fixed points are saddles but globally asymptotically stable on their positive coordinate planes. For three dimensional Ricker models, they found mild conditions on parameters such that the criterion can be applied to. Observing that Balreira, Elaydi and Luís' discussion is still valid for the monotone region with piecewise smooth boundary, we prove in this note that the interior fixed point of three dimensional Kolmogorov competitive mappings is globally asymptotically stable if they admit a carrying simplex and three planar fixed points which are saddles but globally asymptotically stable on their positive coordinate planes. This result is much easier to apply in the application. 相似文献
86.
J. Johnsson H. Bladh N.-E. Olofsson P.-E. Bengtsson 《Applied physics. B, Lasers and optics》2013,112(3):321-332
Soot aggregates formed in combustion processes are often described as clusters of carbonaceous particles in random fractal structures. For theoretical studies of the physical properties of such aggregates, they have often been modelled as spherical primary particles in point contact. However, transmission electron microscopy (TEM) images show that the primary particles are more connected than in a single point; there is a certain amount of bridging between the primary particles. Particle sizing using the diagnostic technique laser-induced incandescence (LII) is crucially dependent on the heat conduction rate from the aggregate to the ambient gas, which depends on the amount of bridging. In this work, aggregates with bridging are modelled using overlapping spheres, and it is shown how such aggregates can be built to fulfil specific fractal parameters. Aggregates with and without bridging are constructed numerically, and it is investigated how the bridging influences the heat conduction rate in the free-molecular regime. The calculated heat conduction rates are then used in an LII model to show how LII particle sizing is influenced by different amounts of bridging. For realistic amounts of bridging ( $C_{\rm{ov}}\leq0.25$ ), the primary particle diameters were overestimated by up to 9 % if bridging was not taken into account. 相似文献
87.
H. Wabnitz Y. Mairesse L. J. Frasinski M. Stankiewicz W. Boutu P. Breger P. Johnsson H. Merdji P. Monchicourt P. Salières K. Varjú M. Vitteau B. Carré 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,40(2):305-311
We investigate the carrier-envelope phase dependence of the total ionization yield for single and double ionization of xenon.
We compare our results to theoretical calculations and to the phase dependent asymmetry in photoelectron emission. We observe
that the phase dependence of the photoion yields, regardless if single or double ionization, is at least 2-3 orders of magnitude
below the photoelectron emission signal. We conclude that total photoionization yields are only very weakly dependent on the
carrier envelope phase, and that they are not a useful means for measurement of the phase. It seems possible that the broad
bandwidth of few-cycle pulses facilitates multiphoton ionization, which leads to a randomization of strong field ionization
phase dependencies. Besides, we observe that the spatial asymmetry in photoelectron emission appears to be useful as an indicator
for the laser pulse duration in the few cycle regime. 相似文献
88.
Pekka NikkilÄ Tom Johnsson Heikki Rosenqvist Leena Toivonen 《Applied biochemistry and biotechnology》1996,59(3):245-257
Growth and fatty acid composition of two lactobacilli,Lactobacillus büchneri andLactobacillus fermentum, were studied at different pHs of the media in a small-scale fermenter with particular interest in lactobacillic acid production
of the cultures. Generally, the total fatty acid content of the bacterial cells increased with increasing culture age. The
production of lactobacillic acid was affected in the two lactobacilli by both culture age and pH of the media, but in a very
different manner. In L.büchneri cultures, the relative proportion of lactobacillic acid was highest when the pH was lowest (pH 4.5), whereas inL. fermentum cultures, the proportion of lactobacillic acid was highest at pH 7.0. The pH of the medium affected not only the relative
proportion of lactobacillic acid, but also biomass production and total fatty acid accumulation of the cultures. Thus, by
controlling the pH of the cultures, the volumetric yield of lactobacillic acid could be improved considerably compared to
cultures without pH control. 相似文献
89.
90.
Laili Mahmoudian Jonas Melin Mohamad Reza Mohamadi Keiko Yamada Michio Ohta Noritada Kaji Manabu Tokeshi Mats Nilsson Yoshinobu Baba 《Analytical sciences》2008,24(3):327-332
We have developed a new method for a fast and precise analysis of circle-to-circle amplification (C2CA) product for specific gene detection by microchip electrophoresis. In this method, we have added a new enzymatic step to the C2CA reaction, which could be carried out isothermally at 37 degrees C. Compared to the original single-stranded DNA, the double-stranded DNA that is produced by this enzymatic reaction is more reliable for analysis by microchip electrophoresis. C2CA product was detected within 55 s with high reproducibility by this method which was successfully applied to the detection of 10-ng genomic DNA of the pathogenic bacteria Vibrio. cholerae within 110 s. Purification was found to be an indispensable step for the analysis of the C2CA product of genomic DNA samples. 相似文献