全文获取类型
收费全文 | 684篇 |
免费 | 5篇 |
国内免费 | 6篇 |
专业分类
化学 | 424篇 |
力学 | 15篇 |
数学 | 77篇 |
物理学 | 179篇 |
出版年
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 11篇 |
2015年 | 12篇 |
2014年 | 10篇 |
2013年 | 28篇 |
2012年 | 42篇 |
2011年 | 51篇 |
2010年 | 25篇 |
2009年 | 29篇 |
2008年 | 34篇 |
2007年 | 35篇 |
2006年 | 56篇 |
2005年 | 43篇 |
2004年 | 40篇 |
2003年 | 33篇 |
2002年 | 32篇 |
2001年 | 10篇 |
2000年 | 9篇 |
1999年 | 6篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 9篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 5篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 9篇 |
1985年 | 13篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1973年 | 3篇 |
1964年 | 2篇 |
1943年 | 2篇 |
1942年 | 2篇 |
1935年 | 2篇 |
1929年 | 3篇 |
1896年 | 2篇 |
排序方式: 共有695条查询结果,搜索用时 15 毫秒
71.
72.
73.
F. W. Zerban L. Sattler G. Steinhoff R. F. Jackson J. A. Mathews und N. Bengtsson 《Fresenius' Journal of Analytical Chemistry》1943,125(7-8):296-298
Ohne Zusammenfassung 相似文献
74.
The main objective of this paper is to develop an adaptive finite element method for computation of the values, and different sensitivity measures, of the Asian option with both fixed and floating strike. The pricing is based on Black–Scholes PDE-model and a method developed by Ve?e? where the resulting PDEs are of parabolic type in one spatial dimension and can be applied to both continuous and discrete Asian options. We propose using an adaptive finite element method which is based on a posteriori estimates of the error in desired quantities, which we derive using duality techniques. The a posteriori error estimates are tested and verified, and are used to calculate optimal meshes for each type of option. The use of adapted meshes gives superior accuracy and performance with less degrees of freedom than using uniform meshes. The suggested adaptive finite element method is stable, gives fast and accurate results, and can be applied to other types of options as well. 相似文献
75.
Camilla Nilsson Eva Malmström Mats Johansson Stacy M. Trey 《Journal of polymer science. Part A, Polymer chemistry》2009,47(2):589-601
A series of well‐defined allyl‐ether functionalized polyester dendrimers has been synthesized via the divergent approach using traditional esterification reactions. Two commercially available trifunctional thiols, trimethylolpropane tri(3‐mercaptopropanoate) (TRIS) and ethoxylated trimethylolpropane tri(3‐mercaptopropanoate) (ETTMP), were incorporated with the dendrimers into the thiol‐ene polymer networks. The thiol‐ene reactions were conducted at room temperature and cured by UV light without the addition of photoinitiatior. Highly crosslinked films were obtained and characterized with respect to mechanical (DMA) and thermal (DSC and TGA) properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 589–601, 2009 相似文献
76.
Camilla Nilsson Neil Simpson Michael Malkoch Mats Johansson Eva Malmström 《Journal of polymer science. Part A, Polymer chemistry》2008,46(4):1339-1348
Well‐defined, allyl‐ether functional, first‐generation dendrimers have been synthesized. The convergent growth approach was utilized, using the anhydride of the allyl‐ether terminated building block. Three different core moieties were used: trimethylolpropane, trisphenol, and ditrimethylolpropane. The coupling reactions proceeded in good yields and all compounds were characterized by NMR, MALDI‐TOF, and SEC. The allyl‐terminated dendrimers were crosslinked by thiol–ene chemistry, using a multifunctional thiol, TriThiol, to give clear and smooth films. The photopolymerization was conducted in the presence of a photoinitiator, Irgacure 651, and no traces of either allyl‐ether groups or thiols were observed by FT‐Raman after cure. All crosslinked films were characterized with respect to mechanical (DMA) and thermal (DSC) properties. It was found that homogeneous networks were formed and that the core functionality and structure had little effect on the network properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1339–1348, 2008 相似文献
77.
78.
The chemical bonding, electronic structure, and optical properties of metal-organic framework-5 (MOF-5) were systematically investigated using ab initio density functional calculations. The unit cell volume and atomic positions were optimized with the Perdew-Burke-Ernzerhof (PBE) functional leading to a good agreement between the experimental and the theoretical equilibrium structural parameters. The calculated bulk modulus indicates that MOF-5 is a soft material. The estimated band gap from a density of state (DOS) calculation for MOF-5 is about 3.4 eV, indicating a nonmetallic character. As MOFs are considered as potential materials for photocatalysts, active components in hybrid solar cells, and electroluminescence cells, the optical properties of this material were investigated. The detailed analysis of chemical bonding in MOF-5 reveals the nature of the Zn-O, O-C, H-C, and C-C bonds, that is, Zn-O having mainly ionic interaction whereas O-C, H-C, and C-C exhibit mainly covalent interactions. The findings in this paper may contribute to a comprehensive understanding about this kind of material and shed insight into the synthesis and application of novel and stable MOFs. 相似文献
79.
Two complex lanthanide(III) transition metal(II) tellurium(IV) oxyhalides, Cu3Yb2(TeO3)4Cl4 and Cu3Yb3(TeO3)4Cl6 have been synthesized and the crystal structures were determined by single-crystal X-ray diffraction. Both compounds are layered with only weak connections in between the layers. The layers are made up of [YbO8], [TeO3] and [CuOxCly] polyhedra. In both compounds the strong Lewis acid cations Yb3+ and Te4+ only form bonds to oxygen while Cu2+ form bonds to both oxygen and chlorine. This leads the Cl? ions to be expelled from the bonding volumes of the crystal structures and protrude from the layers. Magnetic susceptibility measurements were performed on a powder sample of Cu3Yb2(TeO3)4Cl4. The Curie–Weiss law found at low temperatures indicates a Curie–Weiss temperature of ca. ?5(1) K. However, indication for long-range magnetic ordering could not be observed down to 1.87 K. The two new phases are to the best of our knowledge the first containing all three of Cu, Yb and Te. 相似文献
80.
T-junctions are common elements in flow duct networks. It is shown that for low Strouhal numbers, based on the duct diameter, their acoustic scattering properties can be described using an incompressible quasi-steady model. Models are derived for systems subjected to combinations of grazing and bias mean flow, and are shown to work in both the limiting cases—that is, grazing or bias flow alone—as well as for the joining or dividing flow configurations. The upper Strouhal number for which the quasi-steady models are applicable is limited by flow-acoustic interaction effects, which differ significantly between the different flow configurations. Generally the models are applicable up to Strouhal numbers of approximately 0.1-0.2, which is comparable with previous published models for other configurations such as bends and orifices. This range is sufficient to make the model useful in many important engineering applications. 相似文献