Simultaneous self-focusing of two laser beams in a subthreshold coherent population trapping regime

The propagation of two-component laser radiation in a medium consisting of atoms with a Λ level scheme is investigated. The simultaneous self-focusing of two beams is considered. The main features of this phenomenon are: 1) lowering of the self-focusing threshold by several orders of magnitude in comparison with the known case of saturation of a transition in a two-level atom; 2) a strong dependence of the character of the propagation of the radiation on the difference between the detunings of the two frequency components of the field from resonance, which is associated with fulfillment of the two-photon resonance condition. Zh. Tekh. Fiz. 67, 126–129 (July 1997)     

Chemiluminescence of ozonized polyvinylchloride

Time dependences of decomposition of peroxides in samples of polyvinylchloride (PVC) ozonized under different conditions and containing different concentrations of peroxidic groups were followed by chemiluminescence method. The kinetic characteristics of the chemiluminescence reaction were determined and the mechanism accounting for the formation of hydroperoxides in PVC during ozonization was suggested.     

Chemiluminescence in the thermal decomposition of dicumyl peroxide

Chemiluminescence accompanying the dicumyl peroxide decomposition in cumene and tetraline with different content of tetralyl hydroperoxide has been studied under nitrogen at 140°C. Simultaneously, the main reaction products of dicumyl peroxide decomposition have been determined chromatographically. Chemiluminescence intensity is proportional to the square root of dicumyl peroxide concentration in the system. Chemiluminescence intensity increases with increasing concentration of tetraline in cumene and also with increasing concentration of tetralyl hydroperoxide. The amount of acetophenone formed decreases. The various elementary processes responsible for the chemiluminescence are suggested.     

Fast gas chromatography for pesticide residues analysis using analyte protectants

Fast GC-MS with narrow-bore columns combined with effective sample preparation technique (QuEChERS method) was used for evaluation of various calibration approaches in pesticide residues analysis. In order to compare the performance of analyte protectants (APs) with matrix-matched standards calibration curves of selected pesticides were searched in terms of linearity of responses, repeatability of measurements and reached limit of quantifications utilizing the following calibration standards in the concentration range 1-500 ng mL(-1)(the equivalent sample concentration 1-500 microg kg(-1)): in neat solvent (acetonitrile) with/without addition of APs, matrix-matched standards with/without addition of APs. For APs results are in a good agreement with matrix-matched standards. To evaluate errors of determination of concentration synthetic samples at concentration level of pesticides 50 ng mL(-1) (50 microg kg(-1)) were analyzed and quantified using the above given standards. For less troublesome pesticides very good estimation of concentration was obtained utilizing APs, while for more troublesome pesticides such as methidathion, malathion, phosalone and deltamethrin significant overestimation reaching up to 80% occurred. According to presented results APs can be advantegously used for "easy" pesticides determination. For "difficult" pesticides an alternative calibration approach is required for samples potentially violating MRLs. An example of real sample measurement is shown. In this paper also the use of internal standards (triphenylphosphate (TPP) and heptachlor (HEPT)) for peak areas normalization is discussed in terms of repeatability of measurements and quantitative data obtained. TPP normalization provided slightly better results than the use of absolute peak areas measurements on the contrary to HEPT.     

Comparison of sample preparation methods combined with fast gas chromatography-mass spectrometry for ultratrace analysis of pesticide residues in baby food

Four sample preparation techniques were compared for the ultratrace analysis of pesticide residues in baby food: (a) modified Schenck's method based on ACN extraction with SPE cleaning; (b) quick, easy, cheap, effective, rugged, and safe (QuEChERS) method based on ACN extraction and dispersive SPE; (c) modified QuEChERS method which utilizes column-based SPE instead of dispersive SPE; and (d) matrix solid phase dispersion (MSPD). The methods were combined with fast gas chromatographic-mass spectrometric analysis. The effectiveness of clean-up of the final extract was determined by comparison of the chromatograms obtained. Time consumption, laboriousness, demands on glassware and working place, and consumption of chemicals, especially solvents, increase in the following order QuEChERS < modified QuEChERS < MSPD < modified Schenck's method. All methods offer satisfactory analytical characteristics at the concentration levels of 5, 10, and 100 microg/kg in terms of recoveries and repeatability. Recoveries obtained for the modified QuEChERS method were lower than for the original QuEChERS. In general the best LOQs were obtained for the modified Schenck's method. Modified QuEChERS method provides 21-72% better LOQs than the original method.