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51.
Localized state conduction through a variable-range hopping mechanism in the low-temperature region (~180–270 K) and thermally activated phonon-assisted tunneling in the higher-temperature region (~270–320 K) has been observed in a polycrystalline Sb35Se65 sample. 相似文献
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So far only few materials have been investigated for their application in fast opto-electronic switching. These materials are Si, GaAs and InP. The difficulty in obtaining a high resistivity specimen of group IV elemental semiconductors puts constraints on their high power handling capability. Most of the group III–V compounds have the possibility of showing up of Gunn effect at high fields, which has undesirable effect in high voltage switching. We have, therefore, investigated a mixed II–VI compound CdS0.5Se0.5 for its potential use as an opto-electronic switch. 相似文献
55.
Fourier-transformed interferometric techniques have been utilized to obtain new data for the far-infrared spectrum of isotactic polystyrene. The region in which rotational and translational crystalline bands are observed has been investigated and 21 absorptions associated with infrared active crystal lattice modes have been observed in the 7–400 cm?1 region. Possible assignments of these bands have been attempted, and a comparison with the previously reported data for polypropylene has been made. 相似文献
56.
Abhishek Verma Swati Nagpal Praveen K. Pandey P. K. Bhatnagar P. C. Mathur 《Journal of nanoparticle research》2007,9(6):1125-1131
Quantum Dots of CdS
x
Se1−x
embedded in borosilicate glass matrix have been grown using Double-Step annealing method. Optical characterization of the
quantum dots has been done through the combinative analysis of optical absorption and photoluminescence spectroscopy at room
temperature. Decreasing trend of photoluminescence intensity with aging has been observed and is attributed to trap elimination.
The changes in particle size, size distribution, number of quantum dots, volume fraction, trap related phenomenon and Gibbs
free energy of quantum dots, has been explained on the basis of the diffusion-controlled growth process, which continues with
passage of time. For a typical case, it was found that after 24 months of aging, the average radii increased from 3.05 to
3.12 nm with the increase in number of quantum dots by 190% and the size-dispersion decreased from 10.8% to 9.9%. For this
sample, the initial size range of the quantum dots was 2.85 to 3.18 nm. After that no significant change was found in these
parameters for the next 12 months. This shows that the system attains almost a stable nature after 24 months of aging. It
was also observed that the size-dispersion in quantum dots reduces with the increase in annealing duration, but at the cost
of quantum confinement effect. Therefore, a trade off optimization has to be done between the size-dispersion and the quantum
confinement. 相似文献
57.
Sneha Karmarkar P. V. Khadikar Vijay K. Agrawal Keshav C. Mathur Manorama Mandloi Shobha Joshi 《Journal of Chemical Sciences》2000,112(1):43-49
Proton-ligand formation constants of salicylhydroxamic acids (SHA) and their nuclear substituted derivatives have been estimated
topologically using the normalized Wiener index, referred to as mean square Wiener index (Wms). Regression analysis of the
data indicates that Wms can be used successfully for estimating and monitoring proton-ligand formation constants. 相似文献
58.
Low‐temperature sol–gel transformation of methyl silicon precursors to silica‐based hybrid materials
Veena Dhayal Rakesh Bohra Meena Nagar Ajay Kaushik Sanjay Mathur Sven Barth 《应用有机金属化学》2008,22(11):629-636
Six new methyl silicon (IV) precursors of the type [MeSi{ON?C(R)Ar}3] [when R = Me, Ar = 2‐C5H4N ( 1 ), 2‐C4H3O ( 2 ) or 2‐C4H3S ( 3 ); and when R = H, Ar = 2‐C5H4N ( 4 ), 2‐C4H3O ( 5 ) or 2‐C4H3S ( 6 )] were prepared and structurally characterized by various spectroscopic techniques. Molecular weight measurements and FAB (Fast Atomic Bombardment) mass spectral studies indicated their monomeric nature. 1H and 13C{1H} NMR spectral studies suggested the oximate ligands to be monodentate in solution, which was confirmed by 29Si{1H} NMR signals in the region expected for tetra‐coordinated methylsilicon (IV) derivatives. Thermogravimetric analysis of 1 revealed the complex to be thermally labile, decomposing to a hybrid material of definite composition. Two representative compounds ( 2 and 4 ) were studied as single source molecular precursor for low‐temperature transformation to silica‐based hybrid materials using sol–gel technique. Formation of homogenous methyl‐bonded silica materials (MeSiO3/2) at low sintering temperature was observed. The thermogravimetric analysis of the methylsilica material indicated that silicon‐methyl bond is thermally stable up to a temperature of 400 °C. Reaction of 2 and Al(OPri)3 in equimolar ratio in anhydrous toluene yielded a brown‐colored viscous liquid of the composition [MeSi{ON?C(CH3)C4H3O}3.Al(OPri)3]. Spectroscopic techniques 1H, 13C{1H}, 27Al{1H} and 29Si{1H} NMR spectra of the viscous product indicated the presence of tetracoordination around both silicon and aluminum atoms. On hydrolysis it yielded methylated aluminosilicate material with high specific surface area (464 m2/g). Scanning electron micrography confirmed a regular porous structure with porosity in the nanometric range. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
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Pradeep Mathur Raj Kumar Joshi Amrendra K. Singh 《Journal of organometallic chemistry》2010,695(24):2687-2694
A facile, one pot, high yield synthesis of α,β-vinylester (1-14) and alkoxy substituted γ-lactones (15-28) has been achieved by the photochemical reaction of terminal acetylene (ferrocenyl phenyl trimethylsillyl, hexyl and cyclohexyl) with alcohol (methanol, ethanol and isopropanol) and carbon monoxide in presence of iron pentacarbonyl as a catalyst. The selectivity of the compounds depends on the time of photolysis of the reaction as well as the solvent used. A stable reaction intermediate ferrole was isolated, and further photolysis with alcohols, resulted in the formation of α,β-vinylester. All the compounds were fully characterised by spectroscopic methods and the molecular structures of compounds 1, 16, 17 and 20 were established crystallographically. 相似文献