Contribution of Kinematical and Thermal Full-field Measurements for Mechanical Properties Identification: Application to High Cycle Fatigue of Steels

The purpose of this work is to extend the use of unconventional tests and full field measurements (kinematical and thermal) to the identification of the effect of a wide plastic pre-strain range on the high cycle fatigue properties of a dual-phase steel. An unconventional specimen is designed. The geometry of this specimen permits a constant gradient of pre-strain to be obtained after a monotonic tensile test. Then, a self-heating test under cyclic loading is carried out on the pre-strained specimen. During this cyclic test, the thermal field is measured using an infrared camera. Finally, a suitable numerical strategy is proposed to identify a given thermal source model taking into account the influence of plastic pre-strain. The results show that, with the unconventional test and the procedure developed in this work, the influence of a plastic pre-strain range on fatigue properties can be identified by using only one specimen when, for a classical fatigue campaign, a great number of specimens is required.     

The gradient and heavy ball with friction dynamical systems: the quasiconvex case

We consider the gradient system $\dot x(t)+\nabla\phi(x(t))=0$ and the so-called heavy ball with friction dynamical system $\ddot x(t) +\lambda\dot x(t)+\nabla\phi(x(t))=0$ , as well as an implicit discrete (proximal) version of it, and study the asymptotic behavior of their solutions in the case of a smooth and quasiconvex objective function Φ. Minimization properties of trajectories are obtained under various additional assumptions. We finally show a minimizing property of the heavy ball method which is not shared by the gradient method: the genericity of the convergence of each trajectory, at least when Φ is a Morse function, towards local minimum of Φ.     

α,α-Difluorophosphonohydroxamic Acid Derivatives among the Best Antibacterial Fosmidomycin Analogues

Three α,α-difluorophosphonate derivatives of fosmidomycin were synthesized from diethyl 1,1-difluorobut-3-enylphosphonate and were evaluated on Escherichia coli. Two of them are among the best 1-deoxy-d-xylulose 5-phosphate reductoisomerase inhibitors, with IC₅₀ in the nM range, much better than fosmidomycin, the reference compound. They also showed an enhanced antimicrobial activity against E. coli on Petri dishes in comparison with the corresponding phosphates and the non-fluorinated phosphonate.     

Thermal and Structural Behavior of Palm Oil. Influence of Cooling Rate on Fat Crystallization

Summary: The effects of scanning rates (q = −0.5 °C/min to −50 °C/min) on the formation of the different phases occurring at low temperature of a palm oil are investigated by means of calorimetry and optical analysis. It is demonstrated that the cooling rates changed the polymorphism of triacylglycerols (TAGs). The centrifugation is used to separate the two fractions (olein and stearin) of palm oil. We show whereas the rate of centrifugation the separation is not effective. We obtained two fractions, a liquid fraction and a solid fraction which contains some liquid TAGs. It is observed that the solid fraction of palm oil is more sensitive to the effects of the cooling rates. By changing the cooling rate q, it appears threshold behaviour for q = −3 °C/min dividing the data discussion in two parts: for slow cooling rate and for fast cooling rate. At slow cooling rates, TAGs had more time to interact. Contrary at fast cooling rate, TAGs have not the time to be reorganised in more stable conformation. Micrographs revealed that the types of crystals observed were spherolites but some variations in crystal size appeared with the variation of cooling rate.     

Atomic decomposition and interpolation for Hardy spaces of noncommutative martingales

We prove that atomic decomposition for the Hardy spaces h₁ and H₁ is valid for noncommutative martingales. We also establish that the conditioned Hardy spaces of noncommutative martingales hp and bmo form interpolation scales with respect to both complex and real interpolations.     

Evaluation of preconcentration methods in the analysis of synthetic musks in whole‐water samples

According to the European Water Framework Directive, environmental assessment of organic compounds should be made in whole‐water samples, but due to their hydrophobicity and strong attraction to organic content these compounds can be found bound to suspended particle matter or in the dissolved fraction. In this work, the extraction of musk compounds was studied in whole‐water samples exhibiting different amounts of dissolved organic carbon and suspended particulate matter using polyethersulfone preconcentration technique. Matrix effects in estuarine and wastewater (both influent and effluent) were evaluated for filtered and unfiltered samples. For unfiltered samples, estuarine water exhibited matrix effects <20%, while for effluent it was up to 48% and for influent ranged from 85 to 99%. To compensate matrix effects and determine total concentrations in unfiltered samples, different quantification approaches were tested: the use of deuterated analogues and standard additions. Standard additions provided the best results for unfiltered samples. Finally, filtered and unfiltered samples were analyzed using both polyethersulfone preconcentration and membrane‐assisted solvent extraction and results showed a good agreement between the two methods. In both cases unfiltered samples provided concentrations 1.5–2.6 times higher than filtered samples.     

Fast data preprocessing for chromatographic fingerprints of tomato cell wall polysaccharides using chemometric methods

The variability in the chemistry of cell wall polysaccharides in pericarp tissue of red-ripe tomato fruit (Solanum lycopersicon Mill.) was characterized by chemical methods and enzymatic degradations coupled to high performance anion exchange chromatography (HPAEC) and mass spectrometry analysis. Large fruited line, Levovil (LEV) carrying introgressed chromosome fragments from a cherry tomato line Cervil (CER) on chromosomes 4 (LC4), 9 (LC9), or on chromosomes 1, 2, 4 and 9 (LCX) and containing quantitative trait loci (QTLs) for texture traits, was studied. In order to differentiate cell wall polysaccharide modifications in the tomato fruit collection by multivariate analysis, chromatograms were corrected for baseline drift and shift of the component elution time using an approach derived from image analysis and mathematical morphology. The baseline was first corrected by using a "moving window" approach while the peak-matching method developed was based upon location of peaks as local maxima within a window of a definite size. The fast chromatographic data preprocessing proposed was a prerequisite for the different chemometric treatments, such as variance and principal component analysis applied herein to the analysis. Applied to the tomato collection, the combined enzymatic degradations and HPAEC analyses revealed that the firm LCX and CER genotypes showed a higher proportion of glucuronoxylans and pectic arabinan side chains while the mealy LC9 genotype demonstrated the highest content of pectic galactan side chains. QTLs on tomato chromosomes 1, 2, 4 and 9 contain important genes controlling glucuronoxylan and pectic neutral side chains biosynthesis and/or metabolism.