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51.
Mathieu Albini Catherine Taillier Vincent Dalla Jérôme Blanchet Jacques Rouden 《Tetrahedron letters》2014
A dramatic improvement of our previous methodology based on a Suzuki–Miyaura cross-coupling to access 3,3′-disubstituted H8-BINOLs using microwave heating is reported herein. These new conditions represent a large gain in term of atom-economy, reaction time, catalyst loading, and excess of reagents employed. 相似文献
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In this note, we study non-linear gauge theories for principal bundles, where the structure group is replaced by a Lie groupoid. We follow the approach of Moerdijk–Mr?un and establish its relation with the existing physics literature. In particular, we derive a new formula for the gauge transformation which closely resembles and generalizes the classical formulas found in Yang Mills gauge theories. 相似文献
54.
Toward the Rational Design of Galactosylated Glycoclusters That Target Pseudomonas aeruginosa Lectin A (LecA): Influence of Linker Arms That Lead to Low‐Nanomolar Multivalent Ligands 下载免费PDF全文
Dr. Shuai Wang Lucie Dupin Mathieu Noël Cindy J. Carroux Dr. Louis Renaud Dr. Thomas Géhin Albert Meyer Dr. Eliane Souteyrand Dr. Jean‐Jacques Vasseur Dr. Gérard Vergoten Dr. Yann Chevolot Dr. François Morvan Dr. Sébastien Vidal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(33):11785-11794
Anti‐infectious strategies against pathogen infections can be achieved through antiadhesive strategies by using multivalent ligands of bacterial virulence factors. LecA and LecB are lectins of Pseudomonas aeruginosa implicated in biofilm formation. A series of 27 LecA‐targeting glycoclusters have been synthesized. Nine aromatic galactose aglycons were investigated with three different linker arms that connect the central mannopyranoside core. A low‐nanomolar (Kd=19 nm , microarray) ligand with a tyrosine‐based linker arm could be identified in a structure–activity relationship study. Molecular modeling of the glycoclusters bound to the lectin tetramer was also used to rationalize the binding properties observed. 相似文献
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V. Mathieu A. H. Mueller D. N. Triantafyllopoulos 《The European Physical Journal C - Particles and Fields》2014,74(5):1-15
We give a detailed derivation of the Boltzmann equation, and in particular its collision integral, in classical field theory. We first carry this out in a scalar theory with both cubic and quartic interactions and subsequently in a Yang–Mills theory. Our method does not rely on a doubling of the fields, rather it is based on a diagrammatic approach representing the classical solution to the problem. 相似文献
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George S Cui Z Razavet M Pickett CJ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(17):4037-4046
This paper describes the kinetics and intimate mechanisms associated with cyanation of [2Fe3S] assemblies to give species structurally related to the subsite of all-iron hydrogenase. Stopped-flow FTIR spectroscopy has enabled the quantitation of the dynamics of five well-defined steps that experimentally illustrate the role of bridging carbonyls in the assembly of the dicyanide species, how on-off sulfur ligation can have a dramatic effect on cyanation kinetics and how the [2Fe3S] core stabilises bridging carbonyl species. 相似文献
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Razavet M Borg SJ George SJ Best SP Fairhurst SA Pickett CJ 《Chemical communications (Cambridge, England)》2002,(7):700-701
Iron(I) in biology?: one-electron oxidation of an (Fe(I)-Fe(I)) carbonyl cyanide precursor bearing a proximal thioether group leads to an (Fe(I)-Fe(II)) bridging carbonyl transient with spectral features similar to the di-iron sub-site of the CO inhibited paramagnetic centre of all-iron hydrogenase. 相似文献
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