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161.
Ultraviolet and infrared conical emissions were observed during the filamentation in air of powerful femtosecond laser pulses produced by a portable terawatt laser system. The broadband spectrum was measured from 200 nm up to 14 microm and covered the complete optical transmission window of the atmosphere. The angularly resolved spectrum showed some X-wave structure across the frequency range analyzed. However, we demonstrated that the strong conical emission observed in the mid- and far-infrared is mainly owing to the four-wave mixing between the pump pulse and its blueshifted conical emission. 相似文献
162.
Comparison of loudspeakers is a major concern during design or product selection. There are several standards for the measurement of loudspeaker characteristics, but none of them provides hints for a rigorous comparison between devices. In this study, different ways of evaluating acoustical dissimilarity between loudspeakers were compared. Several methods of signal analysis were used, and for each method a metric evaluating the dissimilarity between two signals was defined. The correlation between the different dissimilarity evaluations over a significant panel of loudspeakers led to identified classes of measurements. A specific aspect of this work is that measurements were performed in a standard listening environment, rather than in an anechoic or reverberant one. It allowed the use of the recorded signals for a simple listening test, providing a perceptual metric which was compared to the acoustical ones. It also allowed the introduction of auditory models in the computation of some acoustical metrics, so defining a new class of measurements which gave results close to the perceptual ones. 相似文献
163.
Hossain MA Hu Z Haverkort MW Burnus T Chang CF Klein S Denlinger JD Lin HJ Chen CT Mathieu R Kaneko Y Tokura Y Satow S Yoshida Y Takagi H Tanaka A Elfimov IS Sawatzky GA Tjeng LH Damascelli A 《Physical review letters》2008,101(1):016404
Sr3(Ru(1-x)Mnx)2O7, in which 4d-Ru is substituted by the more localized 3d-Mn, is studied by x-ray dichroism and spin-resolved density functional theory. We find that Mn impurities do not exhibit the same 4+ valence of Ru, but act as 3+ acceptors; the extra eg electron occupies the in-plane 3d(x2-y2) orbital instead of the expected out-of-plane 3d(3z2-r2). We propose that the 3d-4d interplay, via the ligand oxygen orbitals, is responsible for this crystal-field level inversion and the material's transition to an antiferromagnetic, possibly orbitally ordered, low-temperature state. 相似文献
164.
165.
We study reduction of generalized complex structures. More precisely, we investigate the following question. Let J be a generalized complex structure on a manifold M, which admits an action of a Lie group G preserving J. Assume that M0 is a G-invariant smooth submanifold and the G-action on M0 is proper and free so that MG?M0/G is a smooth manifold. Under what condition does J descend to a generalized complex structure on MG? We describe a sufficient condition for the reduction to hold, which includes the Marsden–Weinstein reduction of symplectic manifolds and the reduction of the complex structures in Kähler manifolds as special cases. As an application, we study reduction of generalized Kähler manifolds. 相似文献
166.
Bouteiller Hugo Pasturel Mathieu Lemoine Pierric 《Journal of chemical crystallography》2021,51(3):311-316
Journal of Chemical Crystallography - The manganese(II) chloride tetrahydrate MnCl2·4H2O (α-form) crystallizes in the space group P21/n with a?=?6.1918(4) Å,... 相似文献
167.
Wenbin Guo Dr. Nathalie Daro Dr. Sébastien Pillet Dr. Mathieu Marchivie Dr. El-Eulmi Bendeif Dr. Elodie Tailleur Dr. Kittipong Chainok Dominique Denux Dr. Guillaume Chastanet Prof. Philippe Guionneau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(57):12927-12930
The current craze for research around the spin crossover phenomenon can be justified to some extent by the mechanical properties due to the decrease of volume associated with the transition of the metal ion from the HS state to the LS state. As demonstrated here, the molecular complex [Fe(PM-pBrA)2(NCS)2] exhibits, on the contrary, an increase of the unit-cell volume from HS to LS. This counter-intuitive and unprecedented behavior that concerns both the thermal and the photoexcited spin conversions is revealed by a combination of single-crystal and powder X-ray diffraction complemented by magnetic measurements. Interestingly, this abnormal volume change appears concomitant with the wide rotation of a phenyl ring which induces a drastic modification, though reversible, of the structural packing within the crystal. In addition, the light-induced HS state obtained through the Light-Induced Excited Spin-State Trapping shows a remarkably high relaxation temperature, namely T(LIESST), of 109 K, one of the highest so far reported. The above set of quite unusual characteristics opens up new fields of possibilities within the development of spin crossover materials. 相似文献
168.
Xinghui Qi Dr. Sébastien Pillet Dr. Coen de Graaf Michał Magott Dr. El-Eulmi Bendeif Dr. Philippe Guionneau Dr. Mathieu Rouzières Dr. Valérie Marvaud Dr. Olaf Stefańczyk Dr. Dawid Pinkowicz Dr. Corine Mathonière 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(8):3141-3145
The photoinduced properties of the octacoordinated complex K4MoIV(CN)8⋅2 H2O were studied by theoretical calculations, crystallography, and optical and magnetic measurements. The crystal structure recorded at 10 K after blue light irradiation reveals an heptacoordinated Mo(CN)7 species originating from the light-induced cleavage of one Mo−CN bond, concomitant with the photoinduced formation of a paramagnetic signal. When this complex is heated to 70 K, it returns to its original diamagnetic ground state, demonstrating full reversibility. The photomagnetic properties show a partial conversion into a triplet state possessing significant magnetic anisotropy, which is in agreement with theoretical studies. Inspired by these results, we isolated the new compound [K(crypt-222)]3[MoIV(CN)7]⋅3 CH3CN using a photochemical pathway, confirming that photodissociation leads to a stable heptacyanomolybdate(IV) species in solution. 相似文献
169.
In this paper we provide a novel strategy to prove the validity of Hartree?s theory for the ground state energy of bosonic quantum systems in the mean-field regime. For the known case of trapped Bose gases, this can be shown using the strong quantum de Finetti theorem, which gives the structure of infinite hierarchies of k-particles density matrices. Here we deal with the case where some particles are allowed to escape to infinity, leading to a lack of compactness. Our approach is based on two ingredients: (1) a weak version of the quantum de Finetti theorem, and (2) geometric techniques for many-body systems. Our strategy does not rely on any special property of the interaction between the particles. In particular, our results cover those of Benguria–Lieb and Lieb–Yau for, respectively, bosonic atoms and boson stars. 相似文献
170.
Journal of Global Optimization - A highly influential ingredient of many techniques designed to exploit sparsity in numerical optimization is the so-called chordal extension of a graph... 相似文献