Kinematics of the motorcar body side deformation process during front-to-side vehicle collision and the emergence of a hazard to car occupants

The kinematics of the process of deformation of the motorcar body side in the culminating phase of a front-to-side vehicle collision has been examined as a possible basis for analyzing and modeling the process of emergence of a hazard to car occupants during a road accident. The course of such accidents has a complex nature and their models are necessarily based on the approximation of non-linear elastoplastic characteristics of impact processes, especially during the transition from the compression phase to the restitution phase of the deformation process. For such characteristics to be obtained, a lot of experimental tests have to be carried out. This paper addresses the short-duration processes with a high degree of complexity.

A front-to-side motorcar collision model has been prepared, which made it possible to analyze the process of deformation of the car body side and the emergence of a hazard and injuries to car occupants. The results of calculation of the deformation rate and range in various car body zones, velocity of the test dummy placed on driver’s seat and velocity of possible dummy’s impact against the car body side being deformed may be taken as a basis for designing effective occupant protection systems. The kinematics of the phase of vehicle contact and deformation process was modeled with taking into account results of experimental tests, including the curves characterizing the largely non-linear processes that are decisive for the deformation of the car body side. The deformation processes analyzed on these grounds showed at the same time the range of penetration of the deformed body part into the car interior, which causes a hazard to vehicle occupants. The calculation results have shown e.g. that the car body side is deformed to a depth of 0.2 m as quickly as within 0.02–0.03 s. At such a car body side deformation range, the car body part being deformed hits occupant’s body in his/her hips and pelvis area with a velocity of about 6 m/s.

     

The effect of gamma irradiation on the structural properties of olivine

Journal of Radioanalytical and Nuclear Chemistry - Gamma irradiation studies of (Mg0.905Fe0.095)2SiO4 olivine were performed using X-ray fluorescence method, X-ray diffraction, Raman and...     

Complete metric approximation property for q-Araki–Woods algebras

By adapting an ultraproduct technique of Junge and Zeng, we prove that radial completely bounded multipliers on q-Gaussian algebras transfer to q-Araki–Woods algebras. As a consequence, we establish the $w^{?}$-complete metric approximation property for all q-Araki–Woods algebras. We apply the latter result to show that the canonical ultraweakly dense C^?-subalgebras of q-Araki–Woods algebras are always QWEP.     

Arzelà-Ascoli theorem via the Wallman compactification

In the paper, we recall the Wallman compactification of a Tychonoff space T (denoted by Wall(T)) and the contribution made by Gillman and Jerison. Motivated by the Gelfand-Naimark theorem, we investigate the homeomorphism between C^b(T), the space of continuous and bounded functions on T , and C(Wall(T)), the space of continuous functions on the Wallman compactification of T. Along the way, we attempt to justify the advantages of the Wallman compactification over other manifestations of the Stone-?ech compactification. The main result of the paper is a new form of the Arzelà-Ascoli theorem, which introduces the concept of equicontinuity along ω-ultrafilters.     

The evolution of the molecular relaxation parameters described by the Cole–Cole model at the isotropic-nematic phase transition*

This paper presents the dielectric properties of the isotropic liquid and nematic phase at the phase transition. One strong molecular relaxation is observed in both phases. It is interpreted as related to the relaxation around a short molecular axis, due to the fact that molecules possess a strong longitudinal dipole moment. In the isotropic liquid the relaxation is described by the Debye model, while after entering the nematic phase (at cooling) relaxation becomes described by the Cole–Cole model. The distribution parameter of the Cole–Cole model changes from 0.05 (10 degrees above the temperature of the Iso-N transition) to 0.09 (exactly at the phase transition Iso-N), and finally, it reaches 0.35 (10 degrees below the Iso-N transition). Additionally, we observe that ion contribution to the dielectric response is not influenced by the phase transition. All relaxation parameters are discussed within the context of the phase transition phenomena.     

Quantum Tunneling Mediated Interfacial Synthesis of a Benzofuran Derivative

Reaction pathways involving quantum tunneling of protons are fundamental to chemistry and biology. They are responsible for essential aspects of interstellar synthesis, the degradation and isomerization of compounds, enzymatic activity, and protein dynamics. On‐surface conditions have been demonstrated to open alternative routes for organic synthesis, often with intricate transformations not accessible in solution. Here, we investigate a hydroalkoxylation reaction of a molecular species adsorbed on a Ag(111) surface by scanning tunneling microscopy complemented by X‐ray electron spectroscopy and density functional theory. The closure of the furan ring proceeds at low temperature (down to 150 K) and without detectable side reactions. We unravel a proton‐tunneling‐mediated pathway theoretically and confirm experimentally its dominant contribution through the kinetic isotope effect with the deuterated derivative.     

Polyethylene green composites modified with post agricultural waste filler: thermo-mechanical and damping properties

The aim of the study was to determine thermo-mechanical properties and applicability of sunflower husk waste as a filler for ultra low density polyethylene composites. The post agricultural waste filler was milled and chemically treated with (3-aminopropyl)triethoxysilane (3-APS). The amount of filler used was 5, 10 and 20 wt%. The mechanical and thermal properties of the composites containing unmodified and modified natural fillers were determined in the course of static tensile test, rebound resilience by Schob method, and dynamic mechanic thermal analysis. The influence of filler loading and chemical modification of the filler on the morphology of natural composites was evaluated by SEM analysis.