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61.
A new crystalline octahedral hexaaqua Ni(II) bis(o-tolylazo-citrazinate)hexahydrate complex was synthesized. The analytical data proved the formation of 1:2 stoichiometry. An X-ray structure investigation has been carried out. The triclinic space group is p and the unit cell parameters are a = 585.5 pm, b = 993 pm, c = 1139.4 pm, α = 101.6°, β = 97.4°, γ = 102.4°. Evaluation of intensity data revealed the structure with an R-value of 0.03 (2316 observed independent reflections). The compound consists of hexaaqua nickel(2+) ions, univalent anions of the carboxylic acid and six additional water molecules per 相似文献
62.
Summary The reaction of nickel(II) salts with 2-picolyl- and 2,6-lutidyl-phenylketone benzoylhydrazone and theirp-nitro- andp-methoxy-derivatives were carried out and the compounds characterized on the basis of analytical and spectral data. 相似文献
63.
M. S. Masoud S. A. Abou El-Enein H. A. Motaweh A. E. Ali 《Journal of Thermal Analysis and Calorimetry》2004,75(1):51-61
CrIII, MnII and UO2
II amino alcohol complexes were prepared and analyzed. The IR spectra proved that the ligation occurs via oxygen and nitrogen atoms. The nujol mull electronic absorption spectra joined with the room temperature magnetic moment values proved that the complexes are of Oh geometry. The thermal behaviour of the complexes was studied by DTA and TG techniques. The mechanism of the decomposition was suggested. The thermodynamic parameters of the decomposition were evaluated and discussed. The entropy of activation changes, S*, showed that the transition states are more ordered than the reacting complexes. The D.C. electrical conductivity measurements of Cr- and Mn-amino alcohol complexes are of semiconductor behaviour. Empirical equations were deduced for the conduction of the investigated complexes.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
64.
Mohamadzadeh M Mohamadzadeh H Brammer M Sestak K Luftig RB 《Journal of immune based therapies and vaccines》2004,2(1):8
Dendritic cells (DC) are known to present exogenous protein Ag effectively to T cells. In this study we sought to identify
the proteases that DC employ during antigen processing. The murine epidermal-derived DC line Xs52, when pulsed with PPD, optimally
activated the PPD-reactive Th1 clone LNC.2F1 as well as the Th2 clone LNC.4k1, and this activation was completely blocked
by chloroquine pretreatment. These results validate the capacity of XS52 DC to digest PPD into immunogenic peptides inducing
antigen specific T cell immune responses. XS52 DC, as well as splenic DC and DCs derived from bone marrow degraded standard
substrates for cathepsins B, C, D/E, H, J, and L, tryptase, and chymases, indicating that DC express a variety of protease
activities. Treatment of XS52 DC with pepstatin A, an inhibitor of aspartic acid proteases, completely abrogated their capacity
to present native PPD, but not trypsin-digested PPD fragments to Th1 and Th2 cell clones. Pepstatin A also inhibited cathepsin
D/E activity selectively among the XS52 DC-associated protease activities. On the other hand, inhibitors of serine proteases
(dichloroisocoumarin, DCI) or of cystein proteases (E-64) did not impair XS52 DC presentation of PPD, nor did they inhibit
cathepsin D/E activity. Finally, all tested DC populations (XS52 DC, splenic DC, and bone marrow-derived DC) constitutively
expressed cathepsin D mRNA. These results suggest that DC primarily employ cathepsin D (and perhaps E) to digest PPD into
antigenic peptides. 相似文献
65.
Rashidi M Shahabadi N Nabavizadeh SM 《Dalton transactions (Cambridge, England : 2003)》2004,(4):619-622
The complexes [Pt[(CH2)4](NN)], 1a (NN = 2,2'-bipyridine) and 1b (NN = 1,10-phenanthroline) react with 2,3-epoxypropylphenyl ether in the presence of CO2 to give tris-chelate platina(IV)cyclopentane complexes characterized by 1H and 13C NMR spectroscopy as [Pt[(CH2)4](CH2CHCH2OPhOCO2)(NN)], 2. The reactions proceed by the SN2 mechanism and the rates were independent of concentration of CO2. It is demonstrated that for 1a, the reaction proceeds 2.32 times faster than the similar reaction in which the dimethyl analog, [PtMe2(2,2'-bipyridine)], is used. The analog tris-chelate complex [Pt[(CH2)4](CH2CHPhOCO2)(phen)], 3a, was similarly synthesized. 相似文献
66.
Mohammad-Hossein Sorouraddin Masoud Saadati Ayyoub Aghaei 《Monatshefte für Chemie / Chemical Monthly》2011,63(9):439-445
Abstract
A selective optode based on immobilization of 5-(p-dimethylaminobenzylidene)rhodanine on a triacetylcellulose membrane was developed for quantitative determination of Au(III). The determination procedure was performed using a simple light-emitting diode (LED)-based device as a new effort to overcome low reproducibility and repeatability problems which usually accompany optode-based determinations. The results obtained were compared with those of conventional spectrophotometric methods. The response characteristics of the sensor including dynamic range, reproducibility, response time, and lifetime are discussed in detail. This sensor was used for the determination of Au(III) in ore and electroplating liquid effluent samples with satisfactory results in comparison with flame atomic absorption spectroscopy as standard method. Under the optimum conditions, the calibration plot was linear in the concentration range of 0.3–6.0 μg cm−3. The relative standard deviations for five replicate determinations of 1.0 μg cm−3 Au(III) and the corresponding limits of detection were 1.76% and 0.12 μg cm−3, respectively. 相似文献67.
Masoud Khalkhali 《代数通讯》2013,41(14):5861-5874
68.
Masoud Darbandi Ehsan Roohi Vahab Mokarizadeh 《Numerical Methods for Partial Differential Equations》2008,24(2):583-604
The main objective of the current work is to introduce a new conceptual linearization strategy to improve the performance of a primitive shock‐capturing pressure‐based finite‐volume method. To avoid a spurious oscillatory solution in the chosen collocated grids, both the primitive and extended methods utilize two convecting and convected momentum expressions at each cell face. The expressions are obtained via a physical‐based discretization of two inclusive statements, which are constructed via a novel incorporation of the continuity and momentum governing equations. These two expressions in turn provide a strong coupling among the Euler conservative statements. Contrary to the primitive work, the linearization in the current work respects the definitions and essence of physics behind deriving the Euler governing equations. The accuracy and efficiency of the new formulation are then investigated by solving the shock tube as a problem with moving normal and expansion waves and the converging‐diverging nozzle as a problem with strong stationary normal shock. The results show that there is good improvement in performance of the primitive pressure‐based shock‐capturing method while its superior accuracy is not deteriorated at all. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2008 相似文献
69.
合成了纳米尺度氧化石墨烯(NGO)层,用作碳催化剂高效催化苄醇与芳香醛的氧化反应.对于醇氧化反应,当80℃时H2O2存在下,NGOs(20 wt%)可高效催化醇选择性生成醛,其反应速率和产率取决于醇上取代基的性质.对于4-硝基苄醇,反应24 h后,只有10%可转换为相应羧酸.相反,4-甲氧基苄醇和二苯基甲醇分别反应仅9和3h则可完全转化为对应的羧酸和酮.NGO碳催化剂上芳香醛氧化速率高于醇氧化速率.对于所有的醛,采用7 wt% NGO作催化剂,在70℃反应2-3 h后,就可完全转化为相应羧酸.我们讨论了NGO催化剂结构对苄醇和芳香醛氧化反应影响的可能机理. 相似文献
70.
Mohsen Nikpour Hossein Eshtiagh-Hosseini Masoud Mirzaei Amir Aghaei Kaju Soroush Zarinabadi 《中国化学快报》2010,21(4):501-505
<正>A unique ionic hybrid material[C_6H_(12)N_5O]_3[(PO_4)W__(12)O_(36)]·5H_2O has been synthesized from the reaction of((1H-tetrazole-5- yl)methyl)morpholine andα-H_3[(PO_4)W_(12)O_(36)]·21H_2O.It has successfully been characterized by elemental analysis,IR and ~1H NMR spectroscopies,TGA and single-crystal X-ray diffraction method.The title compound is constructed from the three [C_6H_(12)N_5O]~+ cations andα-Keggin[(PO_4)W_(12)O_(36)]~(3-) polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like(2D/∞)[(PO_4)W_(12)O_(36)]~(3-)) which forming via van der Waals interactions along the x axis. 相似文献