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71.
72.
A new crystalline octahedral hexaaqua Ni(II) bis(o-tolylazo-citrazinate)hexahydrate complex was synthesized. The analytical data proved the formation of 1:2 stoichiometry. An X-ray structure investigation has been carried out. The triclinic space group is p and the unit cell parameters are a = 585.5 pm, b = 993 pm, c = 1139.4 pm, α = 101.6°, β = 97.4°, γ = 102.4°. Evaluation of intensity data revealed the structure with an R-value of 0.03 (2316 observed independent reflections). The compound consists of hexaaqua nickel(2+) ions, univalent anions of the carboxylic acid and six additional water molecules per 相似文献
73.
M. S. Masoud S. A. Abou El-Enein H. A. Motaweh A. E. Ali 《Journal of Thermal Analysis and Calorimetry》2004,75(1):51-61
CrIII, MnII and UO2
II amino alcohol complexes were prepared and analyzed. The IR spectra proved that the ligation occurs via oxygen and nitrogen atoms. The nujol mull electronic absorption spectra joined with the room temperature magnetic moment values proved that the complexes are of Oh geometry. The thermal behaviour of the complexes was studied by DTA and TG techniques. The mechanism of the decomposition was suggested. The thermodynamic parameters of the decomposition were evaluated and discussed. The entropy of activation changes, S*, showed that the transition states are more ordered than the reacting complexes. The D.C. electrical conductivity measurements of Cr- and Mn-amino alcohol complexes are of semiconductor behaviour. Empirical equations were deduced for the conduction of the investigated complexes.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
74.
Rashidi M Shahabadi N Nabavizadeh SM 《Dalton transactions (Cambridge, England : 2003)》2004,(4):619-622
The complexes [Pt[(CH2)4](NN)], 1a (NN = 2,2'-bipyridine) and 1b (NN = 1,10-phenanthroline) react with 2,3-epoxypropylphenyl ether in the presence of CO2 to give tris-chelate platina(IV)cyclopentane complexes characterized by 1H and 13C NMR spectroscopy as [Pt[(CH2)4](CH2CHCH2OPhOCO2)(NN)], 2. The reactions proceed by the SN2 mechanism and the rates were independent of concentration of CO2. It is demonstrated that for 1a, the reaction proceeds 2.32 times faster than the similar reaction in which the dimethyl analog, [PtMe2(2,2'-bipyridine)], is used. The analog tris-chelate complex [Pt[(CH2)4](CH2CHPhOCO2)(phen)], 3a, was similarly synthesized. 相似文献
75.
Mohammad-Hossein Sorouraddin Masoud Saadati Ayyoub Aghaei 《Monatshefte für Chemie / Chemical Monthly》2011,63(9):439-445
Abstract
A selective optode based on immobilization of 5-(p-dimethylaminobenzylidene)rhodanine on a triacetylcellulose membrane was developed for quantitative determination of Au(III). The determination procedure was performed using a simple light-emitting diode (LED)-based device as a new effort to overcome low reproducibility and repeatability problems which usually accompany optode-based determinations. The results obtained were compared with those of conventional spectrophotometric methods. The response characteristics of the sensor including dynamic range, reproducibility, response time, and lifetime are discussed in detail. This sensor was used for the determination of Au(III) in ore and electroplating liquid effluent samples with satisfactory results in comparison with flame atomic absorption spectroscopy as standard method. Under the optimum conditions, the calibration plot was linear in the concentration range of 0.3–6.0 μg cm−3. The relative standard deviations for five replicate determinations of 1.0 μg cm−3 Au(III) and the corresponding limits of detection were 1.76% and 0.12 μg cm−3, respectively. 相似文献76.
Masoud Darbandi Ehsan Roohi Vahab Mokarizadeh 《Numerical Methods for Partial Differential Equations》2008,24(2):583-604
The main objective of the current work is to introduce a new conceptual linearization strategy to improve the performance of a primitive shock‐capturing pressure‐based finite‐volume method. To avoid a spurious oscillatory solution in the chosen collocated grids, both the primitive and extended methods utilize two convecting and convected momentum expressions at each cell face. The expressions are obtained via a physical‐based discretization of two inclusive statements, which are constructed via a novel incorporation of the continuity and momentum governing equations. These two expressions in turn provide a strong coupling among the Euler conservative statements. Contrary to the primitive work, the linearization in the current work respects the definitions and essence of physics behind deriving the Euler governing equations. The accuracy and efficiency of the new formulation are then investigated by solving the shock tube as a problem with moving normal and expansion waves and the converging‐diverging nozzle as a problem with strong stationary normal shock. The results show that there is good improvement in performance of the primitive pressure‐based shock‐capturing method while its superior accuracy is not deteriorated at all. © 2007 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2008 相似文献
77.
Mohsen Nikpour Hossein Eshtiagh-Hosseini Masoud Mirzaei Amir Aghaei Kaju Soroush Zarinabadi 《中国化学快报》2010,21(4):501-505
<正>A unique ionic hybrid material[C_6H_(12)N_5O]_3[(PO_4)W__(12)O_(36)]·5H_2O has been synthesized from the reaction of((1H-tetrazole-5- yl)methyl)morpholine andα-H_3[(PO_4)W_(12)O_(36)]·21H_2O.It has successfully been characterized by elemental analysis,IR and ~1H NMR spectroscopies,TGA and single-crystal X-ray diffraction method.The title compound is constructed from the three [C_6H_(12)N_5O]~+ cations andα-Keggin[(PO_4)W_(12)O_(36)]~(3-) polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like(2D/∞)[(PO_4)W_(12)O_(36)]~(3-)) which forming via van der Waals interactions along the x axis. 相似文献
78.
Mahmoud Mirzaei Azita Nouri Masoud Giahi Masoumeh Meskinfam 《Monatshefte für Chemie / Chemical Monthly》2010,80(1):305-307
Abstract
The electronic structure of a boron nitride nanocone with 240° disclination, and some properties that derive from this structure, were studied by density-functional theory calculations. In the considered model there are only hexagonal rings, with the apex and mouth of the nanocone saturated by hydrogen atoms. The model was optimized, and then the nuclear quadrupole resonance parameters were calculated at the sites of 11B and 14N nuclei. The results revealed that the nuclei in the boron nitride nanocone are divided into layers with similar electronic properties. The nuclei at the apex and mouth are very important for the electronic behavior of the nanocone, with 11B playing the major role. 相似文献79.
Nano-sized Cu6Sn5 alloy powders were prepared by a co-precipitation reductive route using a hydrothermal method at 80 °C. The nano-size and morphology of the synthesized Cu6Sn5 alloy powders were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The obtained morphologies, chemical compositions are comparatively discussed. A variety of synthesis parameters, such as time, capping agent and sort of reductant, has an effect on the morphology of the obtained materials, and will be particularly highlighted. 相似文献
80.
S. Masoud Hosseini A. R. Moghadassi Dale E. Henneke 《Journal of Thermal Analysis and Calorimetry》2010,99(3):873-877
Immobilization of lead contamination in soils by precipitation of non-assimilable for plants Pb-phosphate was considered. Glassy fertilizer of controlled release rate of the nutrients for plants as a source of phosphate anions was applied. Thermal analysis methods (TG/DTG/DTA) were used for the identification of components of Pb-precipitate, which being in statu nascendi have nonstoichiometric composition and disordered crystallographic structure difficult to identify by XRD method. Application of TA methods permits to demonstrate the negative role of Pb complexing citric acid solution simulating the natural soil conditions, which inhibits the Pb-phosphate of pyromorphite type formation. 相似文献