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21.
Abdolkarim Zare Alireza Hasaninejad Mohammad Hassan Beyzavi Ahmad Reza Moosavi-Zare Ali Khalafi-Nezhad Mehrnoosh Roshankar 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1702-1712
KF/Al 2 O 3 efficiently catalyzes the microwave-assisted Michael addition of sulfonamides to α,β-unsaturated esters under solvent-free conditions to afford N-alkyl derivatives of sulfonamides as biologically interesting compounds in high yields and in short reaction times. In this reaction, N,N-dialkylsulfonamides are also produced, but in very low yields. 相似文献
22.
Davood Nori-Shargh Hossein Aghabozorgh Karim Zare Mohammad Reza Talei Bavil Olyai Saeed Jameh-Bozorghi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):341-351
Molecular structures, metallotropic and prototropic shifts of cyclopentadienyl(trimethyl)silane ( 1 ), cyclopentadienyl(trimethyl)germane ( 2 ), and cyclopentadienyl(trimethyl)stannane ( 3 ) were investigated using ab initio molecular orbital and the Becke, Lee, Yang, and Parr density functional (B3LYP) methods. The results show that the most stable structure of compounds 1-3 has the (CH 3 ) 3 M fragment in the allylic position. The energy barrier of metallotropic shifts in compound 1 is higher than in 2 , and in compound 2 higher than in 3 , in good agreement with experimental data. The cyclopentadienyl rings in compounds 1-3 are found to be planar but this result contradicts the reported experimental data. 相似文献
23.
A facile and convenient protocol was developed for the synthesis of diindolylmethanes in short reaction time and high yields using newly synthesized complex as an efficient recyclable heterogeneous catalyst. All synthesized compounds were characterized by IR, NMR spectra and elemental analysis. 相似文献
24.
Gholamreza Ebrahimzadeh Rajaei Hosein Aghaie Karim Zare Mehran Aghaie 《Research on Chemical Intermediates》2013,39(8):3579-3594
Fine powder of Typha latifolia L. root was used for adsorption of copper and zinc ions from buffered and nonbuffered aqueous solutions. The adsorption reached equilibrium in 60 min. During this time, more than 90 % of the adsorption process was completed. The effect of initial pH, initial concentration of metal ion, and contact time was investigated in a batch system at room temperature. The optimum adsorption performance was observed at pH 5.00 and 4.25 for nonbuffered solutions of Cu(II) and Zn(II), respectively, while for buffered solutions it occurred at pH 6.00. The total metal uptake decreased on application of ammonium acetate buffer, from 37.35 to 17.00 mg g?1 and 28.80 to 9.90 mg g?1 for Cu(II) and Zn(II) solutions, respectively, with 100 mg L?1 initial concentration. The pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich models were used to describe the adsorption kinetics. The experimental data followed the pseudo-second-order kinetic model. The biosorption equilibrium was well described by Langmuir and Freundlich isotherm models. 相似文献
25.
Russian Journal of Organic Chemistry - Tannic acid‐functionalized silica‐coated Fe3O4 nanoparticles (Fe3O4@SiO2@tannic acid) were synthesized and characterized by transmission electron... 相似文献
26.
Salek Farhad Babaie Meisam Ghodsi Ali Hosseini Seyed Vahid Zare Ali 《Journal of Thermal Analysis and Calorimetry》2021,145(3):817-828
Journal of Thermal Analysis and Calorimetry - Number of hybrid vehicles has increased around the world significantly. Automotive industry is utilizing the hybridization of the powertrain system to... 相似文献
27.
T. Mousanejad M. Khosravi S. M. Tabatabaii A. R. Khataee K. Zare 《Research on Chemical Intermediates》2014,40(2):711-722
The results of degradation efficiency of 2-sec-butyl-4,6-dinitrophenol (DNBP) in a batch system by various advanced oxidation processes revealed the order of TiO2/UV/O3 > TiO2/O3 > UV/O3 > O3 > UV/TiO2. All processes followed pseudo-first order kinetics. The influence of operational parameters such as initial pH, initial concentration of DNBP, ozone and catalyst dosage on the TiO2/UV/O3 process, which was the most significant investigated method. The ozone dosage was found to have the noticeable impact on the process; however, initial pH and TiO2 dosage were less effective. The mineralization of 40 mg/L of DNBP and petrochemical wastewater under the obtained optimal conditions was monitored by total organic carbon and chemical oxygen demand, respectively. The results demonstrated that the TiO2/UV/O3 process was a very effective method for degradation and mineralization of DNBP in aqueous solutions and industrial wastewater. The degradation intermediates were identified by GC–MS. 相似文献
28.
Kohzadian Alireza Filian Hossein Kordrostami Zahra Zare Abdolkarim Ghorbani-Choghamarani Arash 《Research on Chemical Intermediates》2020,46(3):1941-1953
Research on Chemical Intermediates - In this paper, a rapid, easy and very efficient method for the synthesis of bis(pyrazolyl)methanes has been reported in the presence of nickel–guanidine... 相似文献
29.
Ab initio calculations are carried out to determine γΠ (true), the first-order contribution to the spin-rotation constant, γΠ, for the X2Π ground states of OH, HF+, and HCl+ and their deuterated analogs. These calculations demonstrate that the contribution of this term to the experimentally determined value of γΠ is small, as has been previously conjectured. Furthermore, it is found in the cases under study that the Van Vleck approximation to γΠ (true) significantly overestimates its importance, and a more realistic approximation is presented. 相似文献
30.