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261.
Eripine, a new indole alkaloid, was isolated from the leaves of Hunteria umbellata. The spectral data of the alkaloid, of eripinic acid and the O-acetyl and 19, 20-dihydro derivatives of the alkaloid led to the structure II. Heating of II gave a mixture (ratio 3,5:1) of the known alkaloid erinine (I) and its stereoisomer, isoerinine (VII), which is not found in nature. The same mixture was obtained on heating either erinine or isoerinine. 相似文献
262.
Toshikatsu Koga Kenji Shimokawa Ikuo Inagawa Mutsuo Morita 《Theoretical chemistry accounts》1982,62(1):39-53
The method of momentum density for interatomic interactions is used to investigate the pictures and roles of the polarization and floating functions in momentum (p-) space. Referring to the previous results from the minimal LCAO (Finkelstein-Horowitz) momentum density, we quantitatively discuss the effect of these functions for the bonding process in the ground state of H
2
+
system. The essence of the polarization and floating effects is found to be a modulation of the oscillation in the two-center part of the momentum density. The polarization function introduces a term with a phase and the floating function enlarges the period of the oscillation. An increased migration of the density from the one-center to the two-center part is also important. As a result, both the functions contribute to emphasize the contraction and expansion of momentum density observed previously. However, the floating function disturbs the density distribution in high momentum region, reflecting the destruction of cusps in position (r-) space. We point out an error in the pioneer work of Duncanson. 相似文献
263.
Tomoya Ito Koji Suda Takuya Kumamoto Waka Nakanishi Toshiko Watanabe Tsutomu Ishikawa Hiroko Seki Masatoshi Kawahata Kentaro Yamaguchi Yasumitsu Ogura Kazuo T. Suzuki 《Molecular diversity》2010,14(1):131-145
The role of o-bisguanidinobenzenes (BGBs) as new Brønsted base ligands for arsenic and phosphoric acids was examined. In solution state, complexation was evaluated by Job’s plot in 1H NMR experiment, indicating a 1:1 complex formation, whereas in solid state crystalline structures of complexes obtained were addressed by X-ray crystallographic analysis and/or solid state 13C NMR experiment, in which 1:2 complexes between the BGB and the acid components were normally formed. Based on these results, Merrifield and Hypogel® resin-anchored BGBs were designed and prepared as the corresponding polymer-supported host ligands. Evaluation of their coordination ability with metal salts (ZnCl2 and CoCl2) and arsenic acid in aqueous media by ICP-MS showed that the latter Hypogel® resin-anchored BGBs acted as effective immobilized base ligands. 相似文献
264.
Sanada H Kondo Y Matsuzaka S Morita K Hu CY Ohno Y Ohno H 《Physical review letters》2006,96(6):067602
We demonstrate local manipulation and detection of nuclear spin coherence in semiconductor quantum wells by an optical pump-probe technique combined with pulse rf NMR. The Larmor precession of photoexcited electron spins is monitored by time-resolved Kerr rotation (TRKR) as a measure of nuclear magnetic field. Under the irradiation of resonant pulsed rf magnetic fields, Rabi oscillations of nuclear spins are traced by TRKR signals. The intrinsic coherence time evaluated by a spin-echo technique reveals the dependence on the orientation of the magnetic field with respect to the crystalline axis as expected by the nearest neighbor dipole-dipole interaction. 相似文献
265.
Surface-enhanced infrared absorption spectroscopy (SEIRAS) combined with cyclic voltammetry or chronoamperometry has been utilized to examine kinetic and mechanistic aspects of the electrocatalytic oxidation of formic acid on a polycrystalline Pt surface at the molecular scale. Formate is adsorbed on the electrode in a bridge configuration in parallel to the adsorption of linear and bridge CO produced by dehydration of formic acid. A solution-exchange experiment using isotope-labeled formic acids (H(12)COOH and H(13)COOH) reveals that formic acid is oxidized to CO(2) via adsorbed formate and the decomposition (oxidation) of formate to CO(2) is the rate-determining step of the reaction. The adsorption/oxidation of CO and the oxidation/reduction of the electrode surface strongly affect the formic acid oxidation by blocking active sites for formate adsorption and also by retarding the decomposition of adsorbed formate. The interplay of the involved processes also affects the kinetics and complicates the cyclic voltammograms of formic acid oxidation. The complex voltammetric behavior is comprehensively explained at the molecular scale by taking all these effects into account. 相似文献
266.
Novel thermo-gelling aqueous solution systems are developed with a polyrotaxane, consisting of methylated alpha-cyclodextrin and polyethylene glycol, based on the slide-ring properties of the macrocycles along the linear chain. 相似文献
267.
Morita K Sankaran NB Huang W Seino T Sato Y Nishizawa S Teramae N 《Chemical communications (Cambridge, England)》2006,(22):2376-2378
An abasic site-containing DNA combined with lumiflavin allows amperometric determination of single nucleotide polymorphism through hydrogen bond-mediated nucleobase recognition in water by using abasic sites as a molecular recognition field. 相似文献
268.
For Komatu–Loewner equation on a standard slit domain, we randomize the Jordan arc in a manner similar to that of Schramm (2000) to find the SDEs satisfied by the induced motion on and the slit motion . The diffusion coefficient and drift coefficient of such SDEs are homogeneous functions.Next with solutions of such SDEs, we study the corresponding stochastic Komatu–Loewner evolution, denoted as . We introduce a function measuring the discrepancy of a standard slit domain from relative to BMD. We show that enjoys a locality property. 相似文献
269.
Yoshihisa Morita 《Journal of Applied Analysis & Computation》2012,2(1):57-71
We are dealing with a two-component system of reaction-diffusion equations with conservation of a mass in a bounded domain subject to the Neumann or the periodic boundary conditions. We consider the case that the conserved system is transformed into a phase-field type system. Then the stationary problem is reduced to that of a scalar reaction-diffusion equation with a nonlocal term. We study the linearized eigenvalue problem of an equilibrium solution to the system, and compare the eigenvalues with ones of the linearized problem arising from the scalar nonlocal equation in terms of the Rayleigh quotient. The main theorem tells that the number of negative eigenvalues of those problems coincide. Hence, a stability result for nonconstant solutions of the scalar nonlocal reaction-diffusion equation is applicable to the system. 相似文献
270.
A combinatorial proof for the relation between the exponential function and the logarithmic function
Aequationes mathematicae - Two combinatorial identities are considered. These identities imply that $$\exp $$ and $$\log $$ are mutually inverse to one another even in the case where the variable... 相似文献