全文获取类型
收费全文 | 1361篇 |
免费 | 30篇 |
国内免费 | 3篇 |
专业分类
化学 | 1039篇 |
晶体学 | 18篇 |
力学 | 29篇 |
数学 | 62篇 |
物理学 | 246篇 |
出版年
2023年 | 5篇 |
2021年 | 8篇 |
2020年 | 11篇 |
2019年 | 18篇 |
2018年 | 13篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 20篇 |
2014年 | 25篇 |
2013年 | 55篇 |
2012年 | 50篇 |
2011年 | 63篇 |
2010年 | 36篇 |
2009年 | 38篇 |
2008年 | 75篇 |
2007年 | 76篇 |
2006年 | 88篇 |
2005年 | 69篇 |
2004年 | 84篇 |
2003年 | 77篇 |
2002年 | 58篇 |
2001年 | 23篇 |
2000年 | 22篇 |
1999年 | 18篇 |
1998年 | 17篇 |
1997年 | 25篇 |
1996年 | 18篇 |
1995年 | 10篇 |
1994年 | 18篇 |
1993年 | 15篇 |
1992年 | 8篇 |
1991年 | 16篇 |
1990年 | 10篇 |
1989年 | 14篇 |
1988年 | 12篇 |
1986年 | 13篇 |
1985年 | 29篇 |
1984年 | 29篇 |
1983年 | 5篇 |
1982年 | 19篇 |
1981年 | 29篇 |
1980年 | 14篇 |
1979年 | 16篇 |
1978年 | 24篇 |
1977年 | 17篇 |
1976年 | 13篇 |
1975年 | 7篇 |
1974年 | 9篇 |
1972年 | 7篇 |
1971年 | 7篇 |
排序方式: 共有1394条查询结果,搜索用时 0 毫秒
41.
Takashi Uemura Nobuyuki Okuda Hiroya Kirmura Yasuko Okuda Yoshinobu Ueba Tuguru Shirakawa 《先进技术聚合物》1997,8(7):437-442
Electroluminescent(EL) devices have been fabricated using four different polymers with different glass transition temperatures (Tg) dispersed with N,N′-bis-(3-methylphenyl)-N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine (TPD) as a hole transport layer and tris(8-hydroxyquinoline) aluminum (Alq3) as an emitting layer. It was found that the higher the Tg of the polymer, the longer the lifetime of the device. From observations of TPD-doped polymer films with optical microscope and atomic force microscope, dispersing TPD in the polymers was found to suppress the crystallization that causes the roughness of the film surface. It was also observed that the higher the Tg of the host polymers, the more difficult TPD crystallization was. The property of the EL device with polyethersulfone (PES) dispersed with TPD was also investigated. The lifetime of EL device with the TPD doped PES film was improved more than five times at a current density below 10 mA/cm2 compared with the device with a conventional TPD hole transport layer. © 1997 John Wiley & Sons, Ltd. 相似文献
42.
4,4'-Dihydroxytriphenylmethanes were synthesized using Br?nsted acid or Lewis acid in yields of 24-86% as target compounds for developing antiviral agents. Most of the 4,4'-dihydroxytriphenylmethanes showed significant activity against herpes simplex virus type 1 (anti-HSV-1 activity) in a plaque reduction assay. Higher cytotoxicity was observed generally in halogenated 4,4'-dihydroxytriphenylmethanes (2a-d) than in non-halogenated derivatives. The non-halogenated derivative, 4,4',4"-trihydroxy-3"-methoxytriphenylmethane (3), showed remarkable antiviral activity with an EC(50) value of 1.8 microg/ml. 相似文献
43.
44.
Inada Y Nishibayashi Y Hidai M Uemura S 《Journal of the American Chemical Society》2002,124(51):15172-15173
A novel cationic methanethiolate-bridged diruthenium complex [Cp*RuCl(mu2-SMe)2RuCp*(OH2)]OTf (1e) has been disclosed to promote the catalytic propargylic substitution reaction of propargylic alcohols bearing not only terminal alkyne group but also internal alkyne group with thiols. It is noteworthy that neutral thiolate-bridged diruthenium complexes (1a-1c), which were known to promote the propargylic substitution reactions of propargylic alcohols bearing a terminal alkyne group with various heteroatom- and carbon-centered nucleophiles, did not work at all. The catalytic reaction described here provides a general and environmentally friendly preparative method for propargylic sulfides, which are quite useful intermediates in organic synthesis, directly from the corresponding propargylic alcohols and thiols. 相似文献
45.
Tetsuya Okuyama Masaru Nakayama Yoshitsugu Tomokiyo Omer Van Der Biest 《Microscopy and microanalysis》2002,8(1):11-15
Lattice strains around a platelet oxygen precipitate in Si wafer is studied by energy filtering convergent-beam electron diffraction (CBED) and calculations based on the finite element method (FEM). Local lattice strains are measured from CBD patterns obtained with a probe size less than 2 nm in a specimen thicker than 450 nm. Strains measured are compressive along a direction normal to a plate of the precipitation and tensile along a direction parallel to the plate. Two-dimensional stress fields near the precipitate are obtained with FEM computer analyses by fitting the measured strains. It appears that shear stresses are concentrated at the end of the precipitate edge and the maximum shear stress at an interface between the precipitate and the Si-matrix is 1.9 GPa. It is demonstrated that a combination of the energy filtering CBED and FEM is very useful for the study of local strains near interfaces in semiconductor devices, in particular for the study of stress fields that are too steep for application of the conventional CBED technique. 相似文献
46.
Umakoshi K Yamasaki T Fukuoka A Kawano H Ichikawa M Onishi M 《Inorganic chemistry》2002,41(16):4093-4095
Treatment of pyridine-2-thiol (pytH) with H(2) (60 atm) in the presence of 5-methylpyridine-2-thiolate (5-mpyt)-bridged dinuclear Pt(III), Pt(II), or Pd(II) complexes (1 mol %) in DMF at 150 degrees C for 72 h leads to the formation of pyridine in 3-51% yield. From the (1)H NMR study of the exchange reactions and of the products under D(2) pressure, it is suggested that the catalytic reaction involves bimetallic activation of the pyt ligand followed by the liberation of pyridine and H(2)S. 相似文献
47.
48.
Detailed studies have been conducted to determine the activity of palladium catalysts for the amination of five-membered heterocyclic halides and to determine the factors that control the scope of this reaction. Palladium-catalyzed aminations of the electron-rich furanyl, thiophenyl, and indolyl halides and of the related 2-halogenated thiazoles, benzimidazole, and benzoxazole have been shown to occur with a subset of amines. Various combinations of palladium precursors and P(t)Bu(3) were tested as catalysts for reaction of 3-bromothiophene with N-methylaniline, and the fastest reactions occurred with the Pd(I) dimer, [PdBr(P(t)Bu(3))](2). The fastest aminations of thiazoles, benzimidazoles, and benzoxazoles occurred with the combination of palladium trifluoroacetate and P(t)Bu(3) as catalyst. 相似文献
49.
Reaction pathways and kinetics of C2 (carbon-two) aldehyde, acetaldehyde (CH3CHO), and formic acid HCOOH or HOCHO, are studied in neutral and acidic subcritical water at 200-250 degrees C. Acetaldehyde is found to exhibit (i) the acid-catalyzed C-C bond formation between acetaldehyde and formic acid, which generates lactic acid (CH3CH(OH)COOH), (ii) the cross-disproportionation, where formic acid reduces acetaldehyde into ethanol, and (iii) the aldol condensation. The lactic acid formation is a green C-C bond formation, proceeding without any organic solvents or metal catalysts. The new C-C bond formation takes place between formic acid and aldehydes irrespective of the presence of alpha-hydrogens. The hydrothermal cross-disproportionation produces ethanol without base catalysts and proceeds even in acidic condition, in sharp contrast to the classical base-catalyzed Cannizzaro reaction. The rate constants of the reactions (i)-(iii) and the equilibrium constant of the lactic acid formation are determined in the temperature range of 200-250 degrees C and at HCl concentrations of 0.2-0.6 M (mol/dm(3)). The reaction pathways are controlled so that the lactic acid or ethanol yield may be maximized by tuning the reactant concentrations and the temperature. A high lactic acid yield of 68% is achieved when acetaldehyde and formic acid are mixed in hot water, respectively, at 0.01 and 2.0 M in the presence of 0.6 M HCl at 225 degrees C. The ethanol yield attained 75% by the disproportionation of acetaldehyde (0.3 M) and formic acid (2.0 M) at 225 degrees C in the absence of added HCl. 相似文献
50.
[reaction: see text] The reaction of heteroaromatic compounds with propargylic carboxylates in the presence of a catalytic amount of [RuCl(2)(CO)(3)](2) or PtCl(2) gives trienes in good yields. The key intermediate is an electrophilic (1-acetoxylvinyl)carbene complex generated from the activated propargylic acetates with transition metals. 相似文献