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Nozawa D Okubo T Chaki S Okuyama S Nakazato A 《Chemical & pharmaceutical bulletin》2007,55(8):1232-1239
In the present study, conducted to explore potent and small molecular melanocortin-4 (MC4) receptor ligands, we found that tripeptide 3a, containing a D-Phe-Arg-2-Nal (Nal; naphthylalanine) sequence, exhibited a moderate affinity for the MC4 receptor. Structural optimization led to the identification of a compound with a high affinity for the MC4 receptor, namely, tripeptide 3e, which showed a 70-fold higher affinity for the MC4 receptor than the lead compound 3a. Moreover, in an effort to further reduce the peptidic characters of tripeptide 3e, we found that dipeptide 3g exhibited a relatively high affinity for the MC4 receptor. Furthermore, in these analogues, the substituted position (1' vs. 2') of the naphthyl ring of Nal residue at position 7 was found to be important for the differentiation of agonist and antagonist activity. The synthesis and structure-activity relationships of the arginine analogues as MC4 receptor ligands were described in this paper. 相似文献
234.
Alkyl chain tethered bis-squaraines bind to Ca2+ ions through the participation of the negatively charged oxygen of the central cyclobutene moiety to form folded H-type aggregates. The initially formed Ca2+ complex is preorganized to facilitate cooperative allosteric binding of Ca2+, resulting in the formation of extended supramolecular arrays. The electronic absorption, IR, and ESI-MS studies support the formation of metallo supramolecular architectures of the folded H-type dimers of the bis-squaraines. 相似文献
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Electrogenerated Chemiluminescence of Donor–Acceptor Molecules with Thermally Activated Delayed Fluorescence 下载免费PDF全文
Dr. Ryoichi Ishimatsu Dr. Shigeyuki Matsunami Takashi Kasahara Prof. Jun Mizuno Dr. Tomohiko Edura Prof. Chihaya Adachi Prof. Koji Nakano Prof. Toshihiko Imato 《Angewandte Chemie (International ed. in English)》2014,53(27):6993-6996
The electrochemistry and electrogenerated chemiluminescence (ECL) of four kinds of electron donor–acceptor molecules exhibiting thermally activated delayed fluorescence (TADF) is presented. TADF molecules can harvest light energy from the lowest triplet state by spin up‐conversion to the lowest singlet state because of small energy gap between these states. Intense green to red ECL is emitted from the TADF molecules by applying a square‐wave voltage. Remarkably, it is shown that the efficiency of ECL from one of the TADF molecule could reach about 50 %, which is comparable to its photoluminescence quantum yield. 相似文献
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