全文获取类型
收费全文 | 508篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
化学 | 441篇 |
晶体学 | 6篇 |
力学 | 1篇 |
数学 | 21篇 |
物理学 | 62篇 |
出版年
2023年 | 2篇 |
2021年 | 4篇 |
2020年 | 22篇 |
2019年 | 14篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 17篇 |
2015年 | 13篇 |
2014年 | 13篇 |
2013年 | 23篇 |
2012年 | 34篇 |
2011年 | 21篇 |
2010年 | 12篇 |
2009年 | 17篇 |
2008年 | 30篇 |
2007年 | 34篇 |
2006年 | 25篇 |
2005年 | 24篇 |
2004年 | 28篇 |
2003年 | 30篇 |
2002年 | 20篇 |
2001年 | 18篇 |
2000年 | 20篇 |
1999年 | 5篇 |
1997年 | 5篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1991年 | 4篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 8篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 7篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1968年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有531条查询结果,搜索用时 31 毫秒
81.
82.
Kento Okoshi Anubhav Saxena Masanobu Naito Goro Suzaki Masatoshi Tokita Junji Watanabe Michiya Fujiki 《Liquid crystals》2004,31(2):279-283
A smectic A-cholesteric phase transition for a rigid-rod helical polymer, poly[n-decyl-(S)-2-methylbutylsilane] (PD2MBS), with a narrow molecular weight distribution, has been observed for the first time. Polarizing optical microscopy showed that the fan-shaped texture of the smectic A phase turned into the characteristic planar texture of the cholesteric phase upon heating. The positive CD band, which corresponds to the reflection band of the cholesteric phase, gradually decreased in intensity within a range 30°C below the transition temperature on cooling, while the peak maximum shifted towards shorter wavelengths. It was concluded that the system has a very wide temperature region over which the cholesteric-smectic A phase transition occurs and in which the cholesteric pitch varies with temperature. 相似文献
83.
The influence of cell density of cells cryopreserved inside a collagen matrix at various cooling rates was investigated. Human fibroblasts were three-dimensionally cultured for 2 days in a collagen sponge (20 mm in diameter and 1 mm in thickness) as an extracellular matrix to imitate biological tissue (artificial tissue). Different cell densities for the artificial tissue were used, from 10(5) to 10(7) cells/cm(3). Four artificial tissues were first stacked in a test chamber, frozen at a cooling rate of 0.3 to 50 degrees C/min in a solution of Dulbecco's Modified Eagle Medium, 20% fetal bovine serum and 10% dimethylsulfoxide, kept frozen below -185 degrees C for 2 hours, and then finally thawed. Membrane integrity of fibroblasts using a trypan blue exclusion assay was evaluated as an index for post-thaw cellular viability. Results show that with increasing cell density, the post-thaw membrane integrity decreased. Therefore, in the cryopreservation of biological tissue, it seems high cell density is one factor which causes a decline in viability. 相似文献
84.
Highly Chemoselective and Versatile Method for Direct Conversion of Carboxylic Acids to Ketones Utilizing Zinc Ate Complexes 下载免费PDF全文
Various carboxylic acids were directly transformed into the corresponding ketones by utilizing organozinc ate complexes, which provide high chemoselectivity without any overreaction to the undesired tertiary carbinol, owing to formation of a stable tetrahedral zincioketal intermediate. This method offers good overall atom/step/pot economy and operational simplicity. 相似文献
85.
Nakayama Masanobu Nishimura Norimitsu Kondo Yuki Takeda Hayami Kasuga Toshihiro 《Journal of Solid State Electrochemistry》2017,21(4):1137-1143
Journal of Solid State Electrochemistry - We demonstrate the Laplace transform (LT) impedance technique for measuring electrochemical lithiation and delithiation in the two-phase system of spinel... 相似文献
86.
Hashizume M Nagasawa Y Suzuki T Kawashima S Kamitakahara M 《Colloids and surfaces. B, Biointerfaces》2011,84(2):545-549
Preparation of colloidal hydroxyapatite (HAp) particles under body fluid conditions was investigated with focusing on the effect of preparative conditions on crystallinity of the resulting particles. Tris(hydroxymethyl)aminomethane was added to 1.5SBF (a solution having 1.5 times higher ion concentrations than those of a simulated body fluid, SBF) to increase the solution pH, which resulted in induction of homogeneous nucleation of HAp in the solution. Colloidal HAp particles having diameters about 300 nm were obtained. When the reaction was proceeded at 70°C and the sample was dried by heating, it was effective to obtain HAp particles having high crystallinity. Experimental results support that remaining water in the sample contributed to increase HAp crystallinity. 相似文献
87.
We present our recent studies on magnetic field effects (MFEs) observed in reactions of heavy atom-centered radicals such as Si-,P-, Ge-, and Sn-radicals with a ns-laser photolysis technique under magnetic fields of 0–10 T. Although the MFES of heavy atom-centered radicals are much smaller than those of C-radicals due to the spin-orbit interaction of heavy atoms, we have found appreciable MFEs in many reactions of such heavy atom-centered radicals. Comparing the MFES of C-radicals with those of heavy atom-centered ones, we have explained the MFEs of heavy atom-centered radicals in terms of the Δg and relaxation mechanisms. We have found that the separation between the MFES due to the Δg mechanism and those due to the relaxation one is possible with the enhancement of spin relaxation by the addition of a paramagnetic ion. We have also tried to enrich magnetic isotopes of heavy atoms with the magnetic isotope effect (MIE), using the reactions which show fairly large MFES. Recently, we have succeeded in enriching 73Ge. This is the heaviest isotope which has so far been enriched with the MIE from samples of natural abundance. 相似文献
88.
Microstructural and chemical changes in a NiO-YSZ electrocatalytic electrode were studied. The microstructural changes in the NiO-YSZ electrocatalytic electrode after the cell operation was compared with the electrode quenched under the applied voltage to suppress the oxidation process. The reversible reduction of NiO into Ni and the formation of intergranular Ni layers at the NiO/YSZ interface were investigated. It was shown that in a compositional range of the NiO-YSZ electrodes from 1/3 to 2/3 the value of the ambipolar conductivity increased with increasing voltage applied to the electrochemical cell. The observed reversible increase in the value of ambipolar conductivity of the electrocatalytic electrode is described in frames of the model of reversible reduction of NiO into Ni under the conditions of cell operation. 相似文献
89.
Let {Xt} be a Gaussian ARMA process with spectral density fθ(λ), where θ is an unknown parameter. The problem considered is that of testing a simple hypothesis H:θ = θ0 against the alternative A:θ ≠ θ0. For this problem we propose a class of tests
, which contains the likelihood ratio (LR), Wald (W), modified Wald (MW) and Rao (R) tests as special cases. Then we derive the χ2 type asymptotic expansion of the distribution of T
up to order n−1, where n is the sample size. Also we derive the χ2 type asymptotic expansion of the distribution of T under the sequence of alternatives An: θ = θ0 + /√n, ε > 0. Then we compare the local powers of the LR, W, MW, and R tests on the basis of their asymptotic expansions. 相似文献
90.
Hiroshi Nozaki Masanobu Saeki Mitsuko Onoda Yoshito Onoda 《Journal of solid state chemistry》1983,46(1):132-137
The phase relations of the ternary system V1?xTixS1.57 are presented on the basis of X-ray diffractometry. The site distribution of Ti and V atoms in the structure is clarified through an NMR absorption study at room temperature. The phase relations and the site distribution of Ti and V, which appear to be closely related to each other, are discussed in terms of the metal-metal interaction of the face-shared octahedra in the metal-deficient distorted NiAs structure. 相似文献