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411.
Abstract
Vortex levitation can achieve non-contact handling by blowing air into a vortex cup through a tangential nozzle to generate a swirling flow. In this paper, we focused on the relationship between the sucking pressure and the flow dynamics when gap distance from the cup to a work piece changes. Then simultaneous measurement of a pressure and a flow field in the cup was performed. As a result, the mean pressure changes and the pressure fluctuation inside the cup enhances with increasing gap height. Especially, periodic pressure perturbation is observed with wide gap height and it synchronizes with an eccentric rotation of the swirling flow. It is also found that the rotation axis of swirling flow steadily inclines against the central axis of the cup for appropriate gap height. 相似文献412.
Koki Fujimura Dr. Yoshihiro Ueda Dr. Yousuke Yamaoka Prof. Kiyosei Takasu Prof. Takeo Kawabata 《Angewandte Chemie (International ed. in English)》2023,62(30):e202303078
A method for rotaxane synthesis by enlargement of the size of the terminal phenol group of the axle component by aromatic bromination has been developed. This method may be regarded as an end-capping strategy involving the swelling of the phenol group at the axle terminal. The advantages of the present strategy include: ready availability of axle components with a variety of swelling precursors, wide product scope (19 examples given including a [3]rotaxane), mild conditions for the swelling process, rich potential for the derivatization of the brominated rotaxanes, and possible release of the axle component by degradative dethreading of the thermally stable brominated rotaxanes under the basic conditions. 相似文献
413.
Binary blends of poly(vinyl chloride) (PVC) and chitin-graft-poly(2-methyl-2-oxazoline) showed miscibility in the blend fraction range of the latter lower than ca. 10 wt.-%. The glass transition temperature of PVC, which was determined by differential scanning calorimetry, changed to lower temperatures with increasing modified chitin contents up to 10 wt.-%. Segmental interaction between PVC and the graft copolymer was confirmed by the carbonyl stretching band shift in the FT-IR analysis. 相似文献
414.
Akinori Takasu Terumi Niwa Hisashi Itou Yoshihito Inai Tadamichi Hirabayashi 《Macromolecular rapid communications》2000,21(11):764-769
A new procedure for chemical modification of poly(vinyl alcohol) (PVA) was established by a glycosidation reaction of hydroxyl groups in PVA with triacetylated sugar oxazoline 1 . 1H and 13C NMR analyses indicated that triacetylated N‐acetyl‐D‐glucosamine (GlcNAc) was introduced onto a PVA backbone selectively via a β‐O‐glycoside linkage. Deacetylation of triacetylated GlcNAc‐substituted PVA 2 resulted in GlcNAc‐substituted PVA 3 in good yield. These modified PVAs 2 and 3 exhibited solubilities and thermal properties different from the original PVA. 相似文献
415.
As a new class of biopolymer-based hybrid materials, the present paper describes the binary blends of a modified chitin and poly(vinyl alcohol) (PVA) which are miscible in the whole range of compositions. The blend films were prepared by the solvent cast method from a homogeneous aqueous solution of PVA and a chitin derivative having poly(2-methyl-2-oxazoline) side chains. Miscibility between PVA and poly(2-methyl-2-oxazoline) homopolymer was also revealed. Differential scanning calorimetry and FT-IR analyses were used to investigate the blends. 相似文献
416.