Hyperfine quantum beat of short-lived beta-emitter8Li polarized by the tilted foil technique

To disclose the basic mechanisms of nuclear polarization creation realized by the tilted foil technique, hyperfine quantum beats of the nuclear polarization of the short-lived beta-emitter⁸Li(I =2⁺,T _1/2=840 ms) were measured as a function of the distance between two tilted foils. From the observed beats of the⁸Li nuclear polarization, it was found that the Fermi-contact interaction of the⁸Li nucleus with the ground 1s-electron in LiIII plays a main role in the final stage of polarization transfer from polarized orbital electrons to the⁸Li nucleus.     

Quadrupole moment of41Sc by use of new nuclear quadrupole resonance detection

Quadrupole effects in -NMR spectra of⁴¹Sc(I =7/2^–,T _1/2=0.596 s) implanted in a TiO₂ single crystal were detected by use of a modified -NMR technique. Using the field gradient in the crystal determined by the pulsed-Fourier-transformed NMR of⁴⁵Sc in TiO₂, the quadrupole moment of⁴¹Sc has been determined as |Q(⁴¹Sc; 7/2^–)|=166±8 mb.     

Nuclear spin dependence of polarization enhancement by multi-tilted foils studied by short-lived beta-emitters8B and12B

In order to study the basic mechanism of polarization enhancement realized by the multitilted foil technique, nuclear polarization of short-lived beta-emitter⁸B(T_1/2=769 ms,I =2⁺) was induced. Utilizing up to ten tilted foils, the polarization enhancement was measured as a function of the foil numbers. The observed enhancement for⁸B was combined with the previous results for¹²B(I =1⁺,T _1/2=20 ms) which has the same atomic configurations but different nuclear spin. Analyzing these results in the framework of the classical vector model, the essential features of the enhancement depending on the nuclear spin was disclosed.     

A theorem on the average number of subfaces in arrangements and oriented matroids

It is known that for simple arrangements in thed-dimensional Euclidean spaceR ^d The average number ofj-dimensional subfaces of ak-dimensional face is less than . In this paper, we show that this is also true for all arrangements inR ^d and for all oriented matroids, and we give combinatorial proofs.     

Total synthesis and absolute stereochemistry of pentenocin B, a novel interleukin-1 beta converting enzyme inhibitor

Four possible diastereomers of pentenocin B were synthesized in a stereocontrolled manner, and the first total synthesis of a natural enantiomer of (+)-pentenocin B unequivocally established the absolute stereochemistry to be 4S,5R,6R.     

Effect of encaged aromatic guests on the shape and connectivity of molecular cavity in crystalline polystyrene evaluated by molecular simulations

The delta form of crystalline syndiotactic polystyrene is a clathrate molecular compound in which various aromatic molecules are encaged. We have investigated the size, shape, and connectivity of the molecular cavity in the crystal using a molecular dynamics simulation. The effects of the guest species on the cavity structure were investigated in detail. In order to systematically vary the guest structure, various aromatic guests, e.g., benzene, toluene, p-xylene, m-xylene, o and mesitylene were examined. The interstitial spaces between the guests and the polymer chains were analyzed by cluster analysis of the free volumes. The individual cavity volumes into which the guests are clathrated were also evaluated. It was found that the guest molecules can greatly affect not only the cavity size and shape but also the connectivity of the cavities. The transport of small molecules in the crystal is discussed in connection with the cavity structure.     

Synthetic approach toward antibiotic tunicamycins — VI total synthesis of tunicamycins

Tunicamycins and their eight analogs have been synthesized by condensation of a N-acetyl-D-glucosamine derivative and an anomeric chloride of tunicaminyl uracil, followed by deprotections and N-acylation.     

Phenolic constituents of licorice. III. Structures of glicoricone and licofuranone, and inhibitory effects of licorice constituents on monoamine oxidase

Two new phenolic compounds, glicoricone (3) and licofuranone (4), were isolated from a species of licorice brought from the northwestern region of China, and their structures were assigned. Among the twelve licorice constituents examined for the inhibition of monoamine oxidase (MAO), six compounds, 3, 4, genistein (6), licopyranocoumarin (7), licocoumarone (14) and glycyrrhisoflavone (15), inhibited the enzyme with the IC50 (concentration required for 50% inhibition of the enzyme activity) values of 6.0 x 10(-5)-1.4 x 10(-4) M. Glycyrrhizin (1) also inhibited MAO with the IC50 value of 1.6 x 10(-4) M.