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991.
992.
Masaki Hanamura 《Inventiones Mathematicae》1988,93(2):383-403
Supported in part by the Educational Project for Japanese Mathematical Scientists 相似文献
993.
Aramaki Y Seto M Okawa T Oda T Kanzaki N Shiraishi M 《Chemical & pharmaceutical bulletin》2004,52(2):254-258
Quaternary ammonium benzocycloheptene compound 1 has previously been reported as a clinical candidate for an injectable CCR5 antagonist. In order to develop an orally active CCR5 antagonist, derivatives of tertiary amine benzocycloheptene 2, the chemical precursor to 1, were investigated. The benzocycloheptene ring was converted to benzothiepine and benzazepine rings and it was found that these changes could enhance the potency of tertiary amine derivatives. In particular, the 1-benzothiepine-1,1-dioxide 11b and the N-methyl-1-benzazepine 18 showed increased activity and good preliminary pharmacokinetic properties. The synthesis of 1-benzothiepine and 1-benzazepine derivatives and their activity are described. 相似文献
994.
Kawabata T Kato M Mizugaki T Ebitani K Kaneda K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,11(1):288-297
Montmorillonite-enwrapped copper and scandium catalysts (Cu(2+)- and Sc(3+)-monts) were easily prepared by treating Na(+)-mont with the aqueous solution of the copper nitrate and scandium triflate, respectively. The resulting Cu(2+)- and Sc(3+)-monts showed outstanding catalytic activities for a variety of carbon-carbon bond-forming reactions, such as the Michael reaction, the Sakurai-Hosomi allylation, and the Diels-Alder reaction, under solvent-free or aqueous conditions. The remarkable activity of the mont catalysts is attributable to the negatively charged silicate layers that are capable of stabilizing metal cations. Furthermore, these catalysts were reusable without any appreciable loss in activity and selectivity. The Cu(2+)-mont-catalyzed Michael reaction proceeds via a ternary complex in which both the 1,3-dicarbonyl compound and the enone are coordinated to a Lewis acid Cu(2+) center. 相似文献
995.
996.
We study the truncated microsupport SSk of sheaves on a real manifold. Applying our results to the case of , the complex of holomorphic solutions of a coherent -module , we show that SSk(F) is completely determined by the characteristic variety of . As an application, we obtain an extension theorem for the sections of Hj(F), j<d, defined on an open subset whose boundary is non-characteristic outside of a complex analytic subvariety of codimension d. We also give a characterization of the perversity for -constructible sheaves in terms of their truncated microsupports. 相似文献
997.
We measured the elastic response of single DNA molecules at various concentrations of the trivalent cation, spermidine. When added spermidine caused the DNA to collapse, the force-extension curves showed either plateaus or stick-release patterns depending on the concentration. The periodic stick-release response determines a characteristic length, which may reflect toroidal supercoiling. At high concentrations of spermidine, we observed the reelongation of single molecules of collapsed DNA. Thus condensation occurs between lower and upper critical concentrations, verifying that the transition is reentrant as theoretically predicted. 相似文献
998.
Yamada M Suzuki T Kanaori K Tajima K Sakamoto S Kodaki T Makino K 《Organic letters》2003,5(18):3173-3176
[reaction: see text] A gas mixture of NO and O(2) was bubbled into 2'-deoxyguanosine solution at neutral pH and 37 degrees C. A novel nitrated nucleoside was generated in the reaction mixture in addition to 8-nitroguanine, 8-nitroxanthine, 2'-deoxyxanthosine, xanthine, and guanine. The novel nucleoside was identified as N(2)-nitro-2'-deoxyguanosine by spectrometric data. 相似文献
999.
1000.
Hiroo Kagami Yoshinobu Kawano Toshiyuki Ikawa Naoko Nishi Tsuyoshi Toyoshima Takuji Hamamoto Yasutaka Hayasaka Yasuo Ikeda Masaki Yuhara Yoshiaki Tainosho 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(1):1
The Nd-isotopic data on sedimentary and metamorphic rocks of SW Japan Arc allow their discrimination into five different depleted mantle (Tdm) model age clusters, 2.6-2.45 Ga, 2.3-2.05 Ga, 1.9-1.55 Ga, 1.45-1.25 Ga, 1.2-0.85 Ga. The 2.6-2.45 Ga and 1.9-1.55 Ga model ages are also coincident with U-Pb inherited zircon ages of the above two epochs as well as the major magmatic activity in the Sino-Korean Craton (SKC). The 2.3-2.05 Ga model ages can be considered as the initial formation ages for the precursors of sedimentary rocks. The Nd-isotopic data suggest that the Hida Belt was most likely formed as a part of the SKC. The mantle underlying the Ryoke Belt had continental lithospheric signature during Triassic-Jurassic period. The 1.9-1.55 Ga model ages, especially 1.8 Ga~, can be associated with the formation of this belt. The source material for the sedimentary rocks occurring in the accretionary terrane of northeastern areas in the SW Japan Arc was probably in and around the SKC of the Ryoke Belt itself. The sedimentary rocks occurring in southwestern areas of the Arc were mainly composed of materials derived from a relatively younger source (1.45-0.85 Ga). 相似文献