全文获取类型
收费全文 | 1456篇 |
免费 | 31篇 |
国内免费 | 12篇 |
专业分类
化学 | 935篇 |
晶体学 | 19篇 |
力学 | 10篇 |
数学 | 135篇 |
物理学 | 400篇 |
出版年
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 23篇 |
2018年 | 8篇 |
2017年 | 15篇 |
2016年 | 21篇 |
2015年 | 16篇 |
2014年 | 32篇 |
2013年 | 66篇 |
2012年 | 75篇 |
2011年 | 95篇 |
2010年 | 38篇 |
2009年 | 48篇 |
2008年 | 82篇 |
2007年 | 83篇 |
2006年 | 86篇 |
2005年 | 88篇 |
2004年 | 84篇 |
2003年 | 68篇 |
2002年 | 52篇 |
2001年 | 38篇 |
2000年 | 32篇 |
1999年 | 18篇 |
1998年 | 19篇 |
1997年 | 21篇 |
1996年 | 24篇 |
1995年 | 9篇 |
1994年 | 16篇 |
1993年 | 15篇 |
1992年 | 15篇 |
1991年 | 18篇 |
1990年 | 15篇 |
1989年 | 17篇 |
1988年 | 17篇 |
1987年 | 8篇 |
1986年 | 13篇 |
1985年 | 23篇 |
1984年 | 26篇 |
1983年 | 11篇 |
1982年 | 17篇 |
1981年 | 19篇 |
1980年 | 15篇 |
1979年 | 11篇 |
1978年 | 12篇 |
1976年 | 8篇 |
1975年 | 16篇 |
1974年 | 5篇 |
1973年 | 8篇 |
1972年 | 5篇 |
1968年 | 4篇 |
排序方式: 共有1499条查询结果,搜索用时 15 毫秒
71.
72.
73.
Yoko M. NAKAO Takashi MIYAWAKI Shinji YASUNO Kazuhiro NAKAO Sachiko TANAKA Midori IDA Masakazu HIRATA Masato KASAHARA Kiminori HOSODA Kenji UESHIMA Kazuwa NAKAO 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2012,88(8):454-461
Objective: To investigate the significance of intra-abdominal fat area (IAFA) on new onset of individual components of the metabolic syndrome: high blood pressure, dyslipidemia, or hyperglycemia. Methods: We conducted a longitudinal study using checkup data of a hospital from 1994 to 2010. Of 25,255 subjects, we examined 1,380 Japanese, who underwent computed tomography to measure IAFA and had no metabolic syndrome components at baseline. Results: During 3.6 years of the mean follow-up period, one of metabolic syndrome components occurred in 752 subjects. Of three components, high blood pressure was more prevalent. The multiple Cox regression analysis disclosed that IAFA is significantly associated with onset of metabolic syndrome components (HR: 1.05 per 10 cm2, 95%CI: 1.03–1.07). This finding was independent of BMI, and significant even in non-obese individuals with body mass index <25 kg/m2. Conclusions: MERLOT study demonstrates that IAFA is an independent predictor for new onset of individual components of the metabolic syndrome, even in non-obese healthy Japanese. 相似文献
74.
Kentaro Iwasaki Kazunori Umishita Shojun Hino Koichi Kikuchi Yohji Achiba 《Molecular Crystals and Liquid Crystals》2013,570(1):623-628
Abstract Ultraviolet photoelectron spectra of potassium dosed higher fullerenes are measured with a synchrotron radiation light source. Potassium dosing to higher fullerenes brings a new structure between the spectral onset of pristine fullerenes and the Fermi level. As the spectral edge of the new structure does not cross the Fermi level, potassium dosed higher fullerenes are not metallic but semiconductive. When the potassium is excessively dosed to the fullerenes, the lower binding energy structures above 5 eV become faint. In contrast to this phenomenon, four distinct structures appear between 5 and 14 eV. 相似文献
75.
76.
Dr. Yohei Hattori Tatsuya Maejima Yumi Sawae Jun-ichiro Kitai Prof. Masakazu Morimoto Dr. Ryojun Toyoda Prof. Hiroshi Nishihara Prof. Satoshi Yokojima Dr. Shinichiro Nakamura Prof. Kingo Uchida 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(50):11441-11450
The cyclization reaction of diarylethenes having an azulene ring occurs only via higher excited states. Novel diarylethenes having an azulene ring with a strong donor or acceptor were synthesized and examined in these reactions. A derivative having an electron-donating 1,3-benzodithiol-2-ylidenemethyl group at the 1-position of the azulene ring showed photochromism, whereas neither a derivative having a π-conjugated electron-donating group at the 3-position of the azulene ring nor derivatives having a π-conjugated electron-withdrawing group at the 1- or 3-position of the azulene ring showed any photochromism. The photoreactivities of these compounds were explained by calculating forces and bond orders on the excited states using density functional theory (DFT) and time-dependent (TD)-DFT. 相似文献
77.
Fujiko Iwasaki Hideyuki Nishiyama Noriko Manabe Masanori Yasui Noboru Matsumura 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):429-430
Abstract Novel metal-carbene complexes (4) with a metallapentalene framework have been obtained from hypervalent diazadiselenathiapentalenes (3) by treating with Pt(PPh3)4, Pd(PPh3)4 and RhCl(PPh3)3. X-Ray investigations revealed that the central hypervalent sulfur atom in 3 was substituted by a metal atom to form M-Se bonds in the resultant metallapentalene framework. 相似文献
78.
Fujiko Iwasaki Seui Kakuma Satoshi Yoshida Shin Murata Masanori Yasui 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):515-516
Abstract The deformation electron-density distributions of 6a-thia-1,3,4,6-tetraazapentalene derivatives (I, II) and bis(phenylthio)dibenzothiophene (III) were investigated by the X-ray diffraction method. For I and II, a structure around the hypervalent S-N bonds is a trigonal bipyramid with equatorial sp2 hybrid of S-C bond and lone-pair electrons and apical polarized S-N bonds. In 111 lone-pair electron densities are observed perpendicular to the thiophene ring and the C-S-C sulfide planes. 相似文献
79.
80.