Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters. 相似文献
To clarify the primary process of photosynthesis, a series of model compounds, in which an octaethylporphyrin and a benzoquinone ring are connected with different lengths of a polymethylene chain, were synthesized and their photophysical properties were investigated. 相似文献
The general properties of the order parameter for a dipolar spinor Bose-Einstein condensate are discussed based on symmetries of interactions. An initially spin-polarized dipolar condensate is shown to dynamically generate a nonsingular vortex via spin-orbit interactions--a phenomenon reminiscent of the Einstein-de Haas effect in ferromagnets. 相似文献
Subpicosecond vacuum ultraviolet (VUV) pulses at the wavelength of 126 nm have been generated in rare gases as a result of the 7th harmonic radiation of a subpicosecond Ti:Sapphire laser oscillating at 882 nm. The VUV harmonic intensity was optimized in Xe at the pressure of 1.2 Torr. The behavior of the harmonic emission was qualitatively reproduced by the classical nonlinear optics. The increase of the harmonic intensity was limited by multiphoton ionization of Xe. 相似文献
We show that quasi-Nambu-Goldstone (NG) modes, which play prominent roles in high energy physics but have been elusive experimentally, can be realized with atomic Bose-Einstein condensates. The quasi-NG modes emerge when the symmetry of a ground state is larger than that of the Hamiltonian. When they appear, the conventional vacuum manifold should be enlarged. Consequently, topological defects that are stable within the conventional vacuum manifold become unstable and decay by emitting the quasi-NG modes. Contrary to conventional wisdom, however, we show that the topological defects are stabilized by quantum fluctuations that make the quasi-NG modes massive, thereby suppressing their emission. 相似文献
Surface structural changes of a hydrogenated diamond-like carbon (DLC) film exposed to a hyperthermal atomic oxygen beam were investigated by Rutherford backscattering spectroscopy (RBS), synchrotron radiation photoelectron spectroscopy (SR-PES), and near-edge X-ray absorption fine structure (NEXAFS). It was confirmed that the DLC surface was oxidized and etched by high-energy collisions of atomic oxygen. RBS and real-time mass-loss data showed a linear relationship between etching and atomic oxygen fluence. SR-PES data suggested that the oxide layer was restricted to the topmost surface of the DLC film. NEXAFS data were interpreted to mean that the sp2 structure at the DLC surface was selectively etched by collisions with hyperthermal atomic oxygen, and an sp3-rich region remained at the topmost DLC surface. The formation of an sp3-rich layer at the DLC surface led to surface roughening and a reduced erosion yield relative to the pristine DLC surface. 相似文献
Abstract The Frank elastic constants K1, K2, K3 are calculated in the mean field approximation by assuming that the intermolecular force is the sum of hard rod repulsion (length L and width D) and Maier-Saupe's type attraction. The main conclusions are as follows. (1) the inequlaities K3? K1 > K2 necessarily hold. (2) All the K'is are nearly proportional to the square of the orientational order parameter S. (3) In thermotropic system, K1/S2, K1/K and K2/K(K: mean elastic constant) increase slowly and K3/K, K3/K1 decreases with L/D, whereas K/kTc is nearly constant for L/D = 3 ~ 5. These tendecies agree fairly well with the observations on liquid crystals with almost rigid structure. (4) In the lyotorpic system in which L/D ? 1, K1/3 = K2 = cLkT/3πD2 and k1/K3 = 4D/5cL are obtained (c: packing fraction). The estimate for PBLG solution nearly agrees with recent experimental data. 相似文献
Substances containing ethynylpyrenes linked to either one or four benzocrown ethers were synthesized, and their absorption and fluorescence spectroscopic responses to metal ions were assessed. Addition of metal perchlorates to solutions of these substances promotes short wavelength shifts in their absorption and fluorescence maxima and increases in their fluorescence intensities. The magnitudes of the fluorescence intensity increases are dependent on the ring size and number of the crown ether and the nature of the metal cation. Association constants for complex formation were calculated using fluorescence intensity versus concentration data. Analysis using Job's plots showed that the substances containing one benzocrown ether moiety form 1:1 complexes with metal ions. Results of experiments employing repeated addition and removal of Mg(ClO4)2 demonstrate that the ON‐OFF fluorescence response can be repeated at least three times. Results of molecular orbital calculations show that complexation with metal ions lowers the energies of both the π and π* levels of the ethynylpyrene moiety and that in some cases the vacant orbital on the metal becomes the LUMO of the complex. An explanation of the spectroscopic changes promoted by metal ions is proposed in terms of electrostatic repulsion and structural regulation. 相似文献
The anion exchange reaction is fundamental to the adsorption and desorption of a specific species from a solution phase to an extracting phase, and it is widely used for separation and waste fluid treatment in industrial fields. However, the details of the anion exchange reaction are poorly understood. Quantitative thermodynamic analysis needs a precise solution condition before and after the exchange reaction. Identification of species adsorbed on the anion exchanger is also necessary because there are multiple species in the solution phase in general. Cobalt is a base metal that is widely used in modern society. One of the authors determined the distribution of cobalt-chloro complexes in hydrochloric acid solutions. It is necessary to know what species are adsorbed on anion exchangers for the thermodynamic analysis of the anion exchange reaction. The comparison in structures between the species in the solution phase and adsorbed on anion exchangers reveals what species are adsorbed. Therefore, the determination of the structures of cobalt-chloro complexes in the solution phase is the next step for quantitative analysis. X-ray absorption spectroscopy (XAS) was used for the structure analysis. Factor analysis can decompose extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) spectra consisting of multiple species into individual spectra of single species using the distribution determined using UV-Vis absorption spectra. Fitting EXAFS theoretical models to the decomposed individual spectra determined the structures of three cobalt-chloro complexes: an octahedron of [CoII(H2O)6]2+, a distorted octahedron of [CoII(H2O)5Cl]+, and a tetrahedron of [CoIICl4]2?. The XANES spectra showed us that the Cl ligand in [CoII(H2O)5Cl]+ was attracted to the center atom of CoII by an electrostatic force, and the bonding system between Cl ligands and CoII in [CoIICl4]2? involved covalency.
We perform an information-theoretical analysis of quantum measurement processes and obtain the global information balance in quantum measurements, in the form of a closed chain equation for quantum mutual entropies. Our balance provides a tight and general entropic information-disturbance trade-off, and explains the physical mechanism underlying it. Finally, the single-outcome case, that is, the case of measurements with posts election, is briefly discussed. 相似文献