An electrically conductive metallocycle: densely packed molecular hexagons with π-stacked radicals

Electrical conduction among metallocycles has been unexplored because of the difficulty in creating electronic transport pathways. In this work, we present an electrocrystallization strategy for synthesizing an intrinsically electron-conductive metallocycle, [Ni₆(NDI-Hpz)₆(dma)₁₂(NO₃)₆]·5DMA·nH₂O (PMC-hexagon) (NDI-Hpz = N,N′-di(1H-pyrazol-4-yl)-1,4,5,8-naphthalenetetracarboxdiimide). The hexagonal metallocycle units are assembled into a densely packed ABCABC… sequence (like the fcc geometry) to construct one-dimensional (1D) helical π-stacked columns and 1D pore channels, which were maintained under the liberation of H₂O molecules. The NDI cores were partially reduced to form radicals as charge carriers, resulting in a room-temperature conductivity of (1.2–2.1) × 10⁻⁴ S cm⁻¹ (pressed pellet), which is superior to that of most NDI-based conductors including metal–organic frameworks and organic crystals. These findings open up the use of metallocycles as building blocks for fabricating conductive porous molecular materials.

Intrinsically electron-conductive metallocycle was synthesized. π-Radicals play a key role in constructing π-stacked columns among molecular hexagons and achieving high electrical conductivity over 10⁻⁴ S cm⁻¹ in polycrystalline pellet.     

High-speed 1.55 μm InGaAs/InGaAsP multi-quantum well λ/4-shifted DFB lasers

The high-speed modulation properties of 1.5 μm multiquantum-well λ/4-shifted DFB lasers are filly reviewed. In particular, the dependence of intrinsic dynamic properties, such as relaxation oscillation frequency, nonlinear damping phenomenon, and spectral chirping under 10 Gbit/s direct modulation, on the number of quantum wells is systematically investigated and compared with those of bulk lasers. The results indicate that the dependence of the above three factors on the number of wells is clearly explained by the linear gain saturation of the quantum-well lasers and that the optimum number of wells should be more than ten in order to increase the modulation bandwidth.     

Random walk properties of lattices and correlation factors for diffusion via the vacancy mechanism in crystals

Random walk properties and correlation factors for diffusion via the vacancy mechanism are calculated and compared for various three-dimensional lattices. By applying the theory of random walks on an imperfect lattice, the correlation factor for impurity diffusion is calculated rigorously for the five jump frequency model in the fee lattice.Presented at the Symposium on Random Walks, Gaithersburg, MD, June 1982.     

Laser cleaning of glass

The pulse lasers, YAG-, CO₂-, and N₂-lasers, are examined for use in the cleaning of glass. Cleaning is found to be due to the evaporation and sputtering of stains on the glass by the heat energy of the laser light. Only the N₂ laser can be used for the cleaning of the exit surface of the glass (the opposite side to the laser). A laser with a high peak power of about 10⁶J/s and short-pulse duration below 100 ns is found to be necessary in practice.     

Examination of Changes in 6-minute Walk Distance and Related Factors in Patients with Perioperative Peripheral Arterial Disease

Objective: This study aimed to clarify the effects of pre- and postoperative physical function on the 6-minute walking distance (6MWD) in patients with peripheral arterial disease (PAD). Method: Forty-two elderly patients with PAD who were hospitalized for revascularization and able to walk independently were included in the study. The 6MWD, ankle brachial index (ABI), weight-bearing index (WBI), gait, and intermittent claudication distance (ICD) were measured before and after the surgery, and skeletal muscle index was measured only before surgery. Analyses were performed by comparing the pre- and postoperative values of each factor using a paired t-test. In addition, multiple regression analysis was performed with 6MWD as the dependent variable before and after surgery. Results: Postoperatively, pain disappeared in 22 patients, and ABI, ICD, 6MWD, and stride length improved significantly. ICD and stride length were extracted as factors related to 6MWD before and after surgery, and ABI, WBI, and stride length were extracted as factors related to 6MWD after surgery. Conclusion: The improvement of intermittent claudication associated with revascularization suggests a stronger influence of functional aspects on postoperative 6MWD.     

Maximum number of connectable laser diode optical switch (LDSW) systems

The maximum number of connectable laser diode optical switches (LDSWs) was studied through the baseband signal-to-noise ratio calculation. For an NRZ 100 Mbits^–1 PCM-IM signal, 60 stages of LDSWs can be connected with a 6-nm optical bandpass filter inserted after the last stage at an input signal level of –30 dB m and an internal gain of 16 dB. A PCM-IM signal of 10 Gbits^–1 can be transmitted through 130 stages of LDSWs at an internal gain of 8 dB and an input signal level of –20 dB m.     

Optimum design of a distributed Bragg-reflector laser with optical loss in the corrugated waveguide

The distributed Bragg-reflector (DBR) laser with optical loss in the corrugated waveguide is analyzed by using the coupling mode theory. The threshold gain and the mode selectivity are given as a function of the optical loss, the coupling coefficient and the pumped length. These results show that the DBR laser has an optimum condition by considering the threshold gain and the mode selectivity.