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991.
A lower sputtering gas pressure during the sputtering process tends to result in the deposition of denser Co-Cr films, but also increases compressive internal stresses when a mixture of Ar and Kr is used as the sputtering gas. The internal stresses have been reduced with an increase in the ratio of Kr in the gas mixture. 相似文献
992.
The adsorption of Si on polycrystalline tungsten surfaces was studied for the first time by means of thermal desorption. Instead of the main peak of Si (), the isotope () contained naturally (~3%) was monitored by mass spectrometry. This method can reduce the contribution from CO to the mass signal of Si. Two desorption peaks were observed at 1480 and 1820 K. The activation energies for the desorption were estimated to be about 90 and 110 kcal/mol, respectively. 相似文献
993.
We studied the structures and the phase transition of Pb/Ge(1 1 1) surface by using the reflection high-energy positron diffraction. The surface structures at 60 K and 293 K have the 3 × 3 and √3 × √3 periodicities, respectively. The rocking curves measured at both temperatures are nearly the same. This indicates that the equilibrium positions of the surface atoms do not change according to the phase transition. From the analysis of the rocking curve based on the dynamical diffraction theory, we found that at both temperatures the surface structures are composed of the so-called one-up and two-down model. The 3 × 3-√3 × √3 phase transition for the Pb/Ge(1 1 1) surface is interpreted in terms of order-disorder transition. 相似文献
994.
We consider a relation between the conformal factor in the stationary axisymmetric (SAS) Einstein-Maxwell field equations and a central extension of a formal loop group which is described by a group 2-cocycle on the formal loop group. The corresponding 2-cocycle on the Lie algebra of the formal loop group is the one which describes an affine Lie algebra. As a result, we see that the space of formal solutions with conformal factors is a homogeneous space of a central extension of the Hauser group. 相似文献
995.
H. Bhang S. Ajimura K. Aoki A. Banu T. Fukuda O. Hashimoto J. I. Hwang S. Kameoka B. H. Kang E. H. Kim J. H. Kim M. Kim T. Maruta Y. Miura Y. Miyake T. Nagae M. Nakamura S. N. Nakamura H. Noumi S. Okada Y. Okayasu H. Outa H. Park P. K. Saha Y. Sato M. Sekimoto S. Shin T. Takahashi H. Tamura K. Tanida A. Toyota K. Tsukada T. Watanabe H. J. Yim 《The European Physical Journal A - Hadrons and Nuclei》2007,33(3):259-263
Recent exclusive coincidence measurements of non-mesonic weak decays (NMWD) reported for the ratio of the partial decay width
of neutron-induced-to-proton-induced NMWD, Γn/Γp , values of 0.45±0.11±0.03 and 0.51±0.13±0.04 for 5lam and 12
Λ
C , respectively. These observations agree well with the improved theoretical Γn/Γp ratios which are in the range of 0.3-0.7. It appears that the long-standing discrepancy between the experimental and theoretical
values of Γn/Γp has finally been solved. However, when compared to the results of intra-nuclear cascade (INC) calculations, the observed
numbers of both single nucleons and coincident nucleon pairs are strongly quenched. The quenching of the proton yield observed
previously has been interpreted as an increase of the Γn/Γp ratio. On the other hand, significant contributions from the two-nucleon-induced three-body process ΛNN → nNN are predicted. Indeed, the angular correlation of the emitted nucleon pairs in the NMWD of 12
Λ
C showed not only decay events in back-to-back kinematics, but also events with non-back-to-back kinematics. In this paper
we show that the difficulties to extract the correct Γn/Γp ratio from the proton spectra is related to the three-body weak-interaction process which strongly quenches the nucleon yields. 相似文献
996.
Hideyuki Hashimoto Masatoshi Hasegawa Kazuyuki Horie Takashi Yamashita Hideharu Ushiki Itaru Mita 《Journal of Polymer Science.Polymer Physics》1993,31(9):1187-1196
Photoluminescence behavior (polarization, lifetime) related to liquid-crystal (LC) formation was examined for the thermotropic liquid-crystalline polyesters poly [(ethylene terephthalate)-co-(p-oxybenzoate)] (PET40/OBA60) (OBA content: 60 mol %) and poly [(ethylene 2,6-naphthalene dicarboxylate)-co-(p-oxybenzoate)] (PEN50/OBA50) (OBA:50 mol %). The Growth of liquid-crystalline (LC) phases of PET40/OBA60 proceeded during annealing. even at low temperature (e.g., 138°C) and were promoted by an increase in annealing temperatures Ta in the experimental temperature range 138–260°C. The concentration dependence of fluorescence spectra of PET40/OBA60 in solution suggested that the fluorescences at 325 and 395 nm can be attributed to monomer and ground-state dimer, respectively. The increase in dimer fluorescence intensity and the decrease in the fluorescence anisotropy ratio r from 0.06 to –0.14 were observed with growth of LC phases. These effects are explained by an increase in the ground-state dimer population and a slight change in the dimer configuration, respectively. PEN50/OBA50 showed monomer fluorescence at 395 nm due to naphthalenedicarboxylate segments and excimer fluorescence at 430 nm. The r value for the excimer fluorescence decreased from zero to about ?0.14 with growth of the LC phase. Such an extraordinary phenomena, in comparison with the usual excimer fluorescences which occurs through energy migration, could be interpreted as the result of formation of high-concentration excimer sites induced by chain orientation in LC domains. © 1993 John Wiley & Sons, Inc. 相似文献
997.
Ferroelectric liquid-crystalline polymers and copolymers were synthesized from acrylate polymers with side chains consisting of a flexible spacer unit, a mesogenic unit and an optically active substituent. In the chiral smectic C (S*c) phases typical fan-shaped textures with equidistant lines (caused by the helical structures) were observed. It was found that the helical pitch increased with increasing polymer molecular weight. The helical pitch also increased in copolymers containing mixtures of right- and left-handed chiral side chains. 相似文献
998.
The leaf extract of the Borneo Kopsia, K. tenuis, provided several new indoles with a novel hexacyclic carbon skeleton, incorporating a cyclopropyl moiety. Two of these, displayed appreciable in vitro cytotoxicity against B16 melanoma cells, as well as the circumvention of drug-resistance in drug-resistant KB cells. The structures of tenuisines A-C were revised from a dimeric to a monomeric structure, based on new LSIMS data, and in conjunction with the preparation of the methyl iodide salt of tenuisine A. 相似文献
999.
Y Tsuda Y Okada M Tanaka N Shigematsu Y Hori T Goto M Hashimoto 《Chemical & pharmaceutical bulletin》1991,39(3):607-611
The structure of WS1279, isolated from Streptomyces sp. as an immunoactive lipopeptide, has been deduced on the basis of chemical and physical evidence as S-[2,3-bis(palmitoyloxy)propyl]-N alpha-palmitoyl-Cys-Asn-Ser-Gly-Gly-Ser- OH. This was confirmed by synthesis. 相似文献
1000.
Capillary electrophoresis of small anions in complex samples with a hollow fiber sampling inlet end.
A hollow fiber sampling inlet end of capillary electrophoresis (CE) for small ions in complex samples is described. A short piece of hollow fiber, which only permits small ions to pass through its wall, was directly connected to one end of a capillary. Small ions in complex samples were injected into the capillary through the hollow fiber by an electrokinetic method. The experimental results of CE for standard anion mixture solutions, river water, and milk samples show that the hollow fiber sampling inlet end is a simple and useful method for the CE of complex samples. Furthermore, it has been shown that the method can be used to study small anion changes during the milk storing process. 相似文献