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101.
A new chemical vapor deposition (CVD) method, called ionization CVD, was developed, to produce non-agglomerated nanoparticles in which reactant gases are charged. A sonic-jet corona discharger was used as an ionizer in the developed nanoparticle generator. For a tetraethylorthosilicate (TEOS)/O2 chemical system, SiO2 nanoparticles were prepared. All particles formed by the ionization CVD were charged unipolarly. SEM micrographs of particles showed that the repulsive Coulombic force between charged particles reduces their coagulation rate and produces non-agglomerated nanoparticles that have a relatively high number concentration and small size. An external field was used to collect the charged particles onto Si wafers. These collected samples indicated that the deposition of charged particles could be controlled by the external electric field. Particle concentration measurement with a condensation nucleus counter at various TEOS concentrations suggested the particle formation mechanism in the ionization CVD was an ion-induced nucleation. 相似文献
102.
Keiichiro Adachi Yumiko Hirose Yoichi Ishida 《Journal of Polymer Science.Polymer Physics》1975,13(8):1491-1499
The dielectric constant of solutions of poly(γ-benzyl-L -glutamate) (PBLG) in dichloromethane shows a jump near 195°K, irrespective of frequency. Therefore, the discontinuity is not a dispersion phenomenon but a phase transition in the thermodynamic sense. The transition temperature is independent of the concentration in the range from 0.01 to 10% by weight, but it increases linearly with the logarithm of the molecular weight of PBLG. The height of the jump depends strongly on frequency, concentration, and molecular weight. The viscosity also changes abruptly at 195°K. These results suggest that the PBLG molecule forms a cluster like a liquid crystal or is in a random coil state below the transition point. 相似文献
103.
Yuji Yaegashi Seiji Adachi Takahiro Wada Satoshi Takano H. Yamauchi 《Physica C: Superconductivity and its Applications》1992,190(4):433-436
Yb(Ba1−xSrx)2Cu4O8 (0.1x0.3) superconductors of the YBa2Cu4O8(“124”) structure were successfully synthesized using an O2-hot-isostaticc-pressing (HIP) technique. The samples were characterized with respect to the crystal structure and superconducting properties. The lattice parameters of the samples decreased as the substitution of Sr for Ba proceeded. The superconducting transition temperatures of all the Yb-“124” samples were more or less the same, being around 80 K. 相似文献
104.
M. Adachi A. Muroi T. Matsuzaki H. Taketani 《Zeitschrift für Physik A Hadrons and Nuclei》1980,295(3):251-258
Low-lying states below 500 keV excitation in112In have been investigated via the112Cd(p, nγ) reaction. New levels have been established atE x=206.5keV and 456.1 keV from the measuredγ-ray excitation functions,γ?γ coincidences and the precision measurements of the (p, n) threshold energy of the ground state and of the 206.5 keV state of112In. Spins and parities of the 206.5 keV state (2+) and the 456.1 keV state (3+) and multipolarities and mixing ratios of the deexcitationγ-rays have been determined from the angular distributions and linear polarizations of the deexcitation γ-rays as well as the excitation functions of the residual levels. Possible configurations of the newly-found levels are discussed. Half-lives of two states have been remeasured:T 1/2=15.2±0.1 min for the ground state andT 1/2=20.9±0.1 min for the 156.4 keV (4+) state. The ground stateQ-value for the112Cd(p, n)112 In reaction has been measured to be ?3.376±0.006 MeV. 相似文献
105.
A convenient synthesis of 1,4-benzodiazepines starting from secondary-2-aminobenzhydrols, which are easily obtained from secondary anilines and benzaldehydes, is described. 7-Nitro-1-methyl-1,4-benzodiazepine 1d can be formed from 5-nitro-2-methylaminomethylacylaminobenzo-phenone 10b and c by using ammonium carbonate instead of ammonia, which gives only the Smiles-rearranged product 11 . 相似文献
106.
The rate constant for the reaction CH3O2 + NO2 → (products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and at total pressures between 53 and 580 Torr, k3 = (9.2 ± 0.4) × 108 liter/mole sec so that the rate of formation of the probable primary product peroxymethyl nitrate (CH3O2NO2) may be significant in urban atmospheres. 相似文献
107.
Intrinsic spectral and kinetic parameters have been measured for the ethylperoxy radical, which was formed in the gas phase by the flash photolysis of azoethane in the presence of an adequate excess of oxygen. Absolute values of the extinction coefficient ?(λ) were derived from complementary measurements of the yield of nitrogen and the absorbance of an equivalent concentration of ethylperoxy radicals. The absorption spectrum is broad, structureless and comparatively weak; ?(236) = 1.02 × 103 liter mole?1 cm?1 at the maximum, and the oscillator strength is 3.4 × 10?2. This spectrum resembles the spectrum of the methylperoxy radical closely in form, but it is less intense; the ratio of the values of oscillator strength is 0.5. The bimolecular reactions of mutual interaction of ethylperoxy radicals are not exclusively terminating, and ethoxy and hydroperoxy radicals are formed in kinetically significant quantities. A computer program was designed to simulate the rise and fall of the concentration of each radical species, and to perform the related kinetic analysis. This program predicted that a second-order plot of the decline of the absorbance of the ethylperoxy radical during the dark period would not show a significant departure from linearity, a conclusion which was confirmed by experiment. Accordingly, the gradient of each such plot yielded a value of k'/?(λ), where k' is the apparent value of the rate constant for the collective reactions of mutual interaction. This rate constant was evaluated from the product of corresponding values of k'/?(λ) and ?(λ); individual values are independent of the wavelength of measurement, and the mean value is k' = (6.6 ± 0.5) × 107 liter mole?1 sec?1. Further kinetic analysis yielded the corresponding absolute value: k = (6.0 ± 0.6) × 107 liter mole?1 sec?1. This value fits the pattern of a relationship between rate constant and structure shown by the methylperoxy, isopropylperoxy, and tert-butylperoxy radicals. Adequate sensitivity for the characterization of the spectrum of the ethylperoxy radical was achieved by the use of a pulsed xenon arc as the monitoring light source in conjunction with a dual beam detection system with twin cells and balanced photomultipliers, and the apparatus is described in detail. 相似文献
108.
Yao K Imai Y Shi L Dong A Adachi Y Nishikubo K Abe E Tateyama H 《Journal of colloid and interface science》2005,285(1):259-266
A novel strategy for the synthesis of layered organosilica is demonstrated. The ionic interaction between the anionic group of a surfactant (sodium dodecyl sulfate) and the cationic organic group of an organosilane (3-aminopropyltrimethoxysilane, ATMS) under acidic conditions was utilized to create a layered organosilica at room temperature. The inorganic part of the organosilica layer was an Si-O hexagonal sheet, and organofunctional groups were alternately arranged on both sides of the sheet. The layered structure of the ATMS organosilica was retained after the removal of the surfactant with chloride anion. The properties of the layered ATMS organosilica were investigated. The layered ATMS-Cl organosilica is stable and possesses a definite layer structure in water or ethanol. Various kinds of anions can be intercalated in the interlayer space of the layered ATMS organosilicas and the layer was expanded dependent on the intercalated anions. The structure of the layered ATMS organosilica was well retained during the intercalation processes. 相似文献
109.
Yasuhiro Takeuchi Norihiko Adachi 《Journal of Mathematical Analysis and Applications》1981,79(1):141-162
This paper presents sufficient conditions for the existence of a nonnegative and stable equilibrium point of a dynamical system of Volterra type, (1) , for every q = (q1,…, qn)T?Rn. Results of a nonlinear complementarity problem are applied to obtain the conditions. System (1) has a nonnegative and stable equilibrium point if (i) f(x) = (f1(x),…,fn(x))T is a continuous and differentiable M-function and it satisfies a certain surjectivity property, or (ii), f(x) is continuous and strongly monotone on R+0n. 相似文献
110.
Buckling of torispherical shells under internal pressure 总被引:1,自引:0,他引:1