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排序方式: 共有206条查询结果,搜索用时 0 毫秒
181.
Ki Hong Park Masa-Aki Kakimoto Yoshio Imai 《Journal of polymer science. Part A, Polymer chemistry》1995,33(7):1031-1037
Novel aromatic polyamides, having inherent viscosities of 0.76-2.31 dL/g, were synthesized by the low temperature solution polycondensation of a new highly phenylated diamine monomer having an imidazolinone group, 1,3-bis(4-aminophenyl)-4,5-diphenylimidazoline-2-one (TPIDA), with various aromatic diacid chlorides. All the polymers were amorphous, and most of the polyamides were readily soluble in organic solvents such as N-methyl–2-pyrrolidone, N,N-dimethylacetamide (DMAc), and m-cresol. Flexible and tough films could be prepared from the DMAc solutions of these soluble aromatic polyamides. The glass transition temperatures and 10% weight loss temperatures under nitrogen of the polyamides were in the range of 275–315°C and 430–505°C, respectively. © 1995 John Wiley & Sons, Inc. 相似文献
182.
Yoshio Imai N. N. Maldar Masa-Aki Kakimoto 《Journal of polymer science. Part A, Polymer chemistry》1985,23(6):1797-1803
New soluble aromatic polyamides with inherent viscosities of 1.0–1.7 dL/g were prepared by the low temperature solution polycondensation of 2,5-bis(4-aminophenyl)—3,4-diphenylthiophene, bis(4-aminophenyl) ether, and aromatic diacid chlorides in N,N-dimethylacetamide. The polyamides and copolyamides are generally soluble in amide-type solvents. They have glass transition temperatures in the range of 280–325°C and showed no weight loss below 390°C on thermogravimetry curves in both air and nitrogen atmospheres. 相似文献
183.
Nagumo S Ono M Kakimoto Y Furukawa T Hisano T Mizukami M Kawahara N Akita H 《The Journal of organic chemistry》2002,67(19):6618-6622
The novel lactonizations of methyl 4-aryl-5-tosyloxypentanoate 1 and 4-aryl-5-tosyloxyhexanoate 3 concomitant with a phenyl rearrangement are reported. The lactonizations were promoted by silica gel or heating in various solvents. By examining the effects of substituents of the aromatic ring on the reactivity, it was found that the reaction proceeded via a phenonium ion. This finding was supported by the stereochemical results for the lactonization of optical active 1. Silica gel-promoted lactonization of 1 gave only gamma-lactone 2, whereas that of 3 afforded gamma-lactone 4 and delta-lactone 5. These lactonizations proved to be kinetically controlled. On the other hand, when 3c was heated in CH(3)NO(2) at 70 degrees C, the highly selective formation of 4c was observed. Further detailed experiments confirmed that the thermal lactonization in CH(3)NO(2) was thermodynamically controlled. 相似文献
184.
Mitsuhiro Yamashita Masa-Aki Kakimoto Yoshio Imai 《Journal of polymer science. Part A, Polymer chemistry》1993,31(6):1513-1518
A new triphenylphosphine-type monomer, bis(4-aminophenyl) phenylphosphine, was synthesized starting from p-bromoaniline and dichlorophenylphosphine. The aromatic polyamides (aramids) containing triphenyphosphine unit in the polymer backbone was prepared by the polycondensation of this diamine with various aromatic diacid chlorides using a low-temperature solution method in N,N-dimethylacetamide (DMAc). The aramids having inherent viscosities of 0.4–0.7 dL/g were obtained in quantitative yields. The polymers were amorphous and soluble in various organic solvents such as DMAc, N-methylpyrrolidone, dimethyl sulfoxide, pyridine, and m-cresol. Transparent, tough, and flexible films were obtained by casting from the DMAc solutions. The glass transition temperatures of the aramids were in the range of 265–310°C, and the 10% weight loss temperatures were above 400°C in air. © 1993 John Wiley & Sons, Inc. 相似文献
185.
Stephen J. Grunzinger Teruaki Hayakawa Masa‐Aki Kakimoto 《Journal of polymer science. Part A, Polymer chemistry》2008,46(14):4785-4793
Hyperbranched poly(ether sulfone) was prepared in the presence of an oligomeric linear poly(ether sulfone) to generate multiblock hyperbranched‐linear (LxHB) copolymers. The LxHB copolymers were prepared in a two‐step, one‐pot synthesis by first polymerizing AB monomer to generate a linear block of a desired molecular weight followed by addition of the AB2 monomer in a large excess (19:1, AB2:AB) to generate the hyperbranched block. NMR integration analysis indicates that AB2:AB ratio is independent of the reaction time. Because the molecular weight still increases with reaction time, these results suggest that polymer growth continues after consumption of monomer by condensation into a multiblock architecture. The LxHB poly(ether sulfone)s have better thermal stability (10% mass loss > 343 vs. 317 °C) and lower Tg (200 vs. > 250 °C) than the hyperbranched homopolymer, higher Tg than the linear homopolymer (<154 °C), while little difference in the solubility character was observed between the two polymers. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4785–4793, 2008 相似文献
186.
K. Kakimoto L. Liu H. Miyazawa S. Nakano D. Kashiwagi X. J. Chen Y. Kangawa 《Crystal Research and Technology》2007,42(12):1185-1189
Heat and mass transfer during crystal growth of bulk Si and nitrides by using numerical analysis was studied. A three‐dimensional analysis was carried out to investigate temperature distribution and solid‐liquid interface shape of silicon for large‐scale integrated circuits and photovoltaic silicon. The analysis enables prediction of the solid‐liquid interface shape of silicon crystals. The result shows that the interface shape became bevel like structure in the case without crystal rotation. We also carried out analysis of nitrogen transfer in gallium melt during crystal growth of gallium nitride using liquid‐phase epitaxy. The result shows that the growth rate at the center was smaller than that at the center. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
187.
Preparation of SnO2 Monolithic Gel by Sol-Gel Method 总被引:2,自引:0,他引:2
Haruhisa Shiomi Chisato Kakimoto Atsushi Nakahira Shinichi Takeda 《Journal of Sol-Gel Science and Technology》2000,19(1-3):759-763
The effects of aging of a wet gel at room temperature and a use of a drying control chemical additive (DCCA) were investigated on the prevention of cracking of the gel during drying. N,N-Dimethylformamide (DMF) having low surface tension was used as a DCCA in this study. Before drying, the aged wet gel was immersed in DMF for several days to replace the pore liquid in the wet gel with DMF.The longer the aging and DMF immersing times became, a fewer cracks generated during drying. Especially, the immersion in DMF for over 8 days made it possible to obtain the SnO2 gel monolith without cracking from the wet gel aged for short time (1 day). However, the wet gel aged for long time without immersing in DMF could not be dried without cracking. Therefore, the replacement of the pore liquid in the wet gel with DMF having low surface tension is thought to be more effective on avoiding a crack generation than aging. From a pore size distribution measurement by N2 gas adsorption, it was found that the pore size and the breadth of the pore size distribution of the dried gel became larger and narrower respectively with increasing DMF immersing time. DMF is thought to be capable of forming strong hydrogen bonding to hydroxyl groups remaining on the surface of the wet gel and providing a shielding cage around the reactants (Sn–OH), thus further condensation reaction is probably suppressed. Consequently, a large pore distribution is developed in the gel, which reduces the magnitude of capillary stress induced during drying. 相似文献
188.
High frequency dielectric response in a branched phthalocyanine 总被引:1,自引:0,他引:1
Guo M Yan X Kwon Y Hayakawa T Kakimoto MA Goodson T 《Journal of the American Chemical Society》2006,128(46):14820-14821
We describe the dielectric effects in a novel branched phthalocyanine system. The synthesis and characterization of the hyperbranched structure are provided. The dielectric constant was approximately 45 over many decades of frequency, and the dispersion was small up to 1 MHz. The losses experienced in this novel material were very small (close to 0.001) at high frequency. The mechanism of this novel effect in the branched structure involves a delocalized polaronic state which takes advantage of the strong intramolecular interactions in the system. 相似文献
189.
Photosensitized isomerization of 1,2-dichloroethylene with 15- and 18-membered-ring crowned benzophenones (1a and 1b) as triplet sensitizers resulted in the cation-dependent increase in the Z/E isomer ratios up to ca. 10 by addition of alkali and alkaline earth metal ions in comparison with the metal-free reactions (Z/E = 1.5-2.1). The highest Z/E values were attained for 1a with Li+ (2.9) and Mg2+ (5.3), and for 1b with Na+ (8.2) and Ca2+ (9.8), respectively, among each family of alkali and alkaline earth metal ions. It was found that the cation recognized sensitization brought about the change of the inherent triplet energy ET as well as the PhiE/Phiz ratio to raise the Z/E isomer ratio of 1,2-dichloroethylene. 相似文献
190.
Munirathina Padmanaban Masa-Aki Kakimoto Yoshio Imai 《Journal of polymer science. Part A, Polymer chemistry》1990,28(11):2997-3005
A new class of polymers containing a photosensitive disilane unit in the polymer main chain with inherent viscosities between 0.1 and 0.59 dL/g was prepared by the melt polycondensation of 1,2-bis (diethylamino) tetramethyldisilane and various bisphenols. The polymers were characterized by UV, IR, 1H-NMR, and elemental analysis. Poly(oxyaryleneoxydisilane)s were soluble in a variety of common organic solvents and have a wide range of glass transition temperatures varying between ?65 and 135°C, depending on the arylene structure. Most of the polymers were stable up to 350°C in both air and nitrogen atmospheres. The inherent viscosity of the polymer containing the 1,6-napthalene unit decreased drastically upon UV light irradiation, indicating its photodegradation. 相似文献