排序方式: 共有210条查询结果,搜索用时 62 毫秒
21.
Dr. Jingjun Hao Prof. Arnold L. Rheingold Marzieh Kavand Dr. Kipp J. van Schooten Prof. Christoph Boehme Dr. Marçal Capdevila‐Cortada Prof. Juan J. Novoa Eva Wöss Prof. Günther Knör Prof. Joel S. Miller 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(35):12312-12315
The reaction of 2,3,5,6‐tetracyanopyridine (TCNPy) and Cr(C6H6)2 forms diamagnetic σ‐[TCNPy]22? possessing a 1.572(3) Å intrafragment sp3–sp3 bond. This is in contrast to the structurally related 1,2,4,5‐tetracyanobenzene and 1,2,4,5‐tetracyanopyrazine that form π‐dimer dianions possessing long, multicenter bonds. 相似文献
22.
Mansoureh Mohammadi Marzieh Kamankesh Zahra Hadian Amir Mohammad Mortazavian Abdorreza Mohammadi 《Chromatographia》2017,80(1):119-126
Microwave-assisted extraction and dispersive liquid–liquid microextraction followed by gas chromatography–mass spectrometry as a sensitive and efficient method was applied to extract and determine four biogenic amines (BAs) in Iranian Lighvan cheese samples. Carrez solutions were used for the sedimentation of proteins. Effective factors on the performance of microextraction were studied and optimized. The proposed method showed good linear ranges from 5 to 500 ng mL?1, with the coefficients of determination higher than 0.9929. Average recoveries were between 97 and 103%. Limits of detection for all analyzed BAs ranged from 5.9 to 14.0 ng g?1, and limits of quantitation ranged between 19.7 and 46.2 ng g?1. Compared with previous methods, the proposed method is simple, fast, accurate, and precise and gives low detection limits for investigating trace amounts of BAs in Iranian Lighvan cheese samples. The levels of four BAs were determined in five Lighvan cheese samples. Cadaverine was found as prevailing amine in the cheese samples. Putrescine, tyramine, and histamine were present at the second, third, and fourth highest levels, respectively. 相似文献
23.
Nahid Shahabadi Soheila Kashanian Marzieh Khosravi Maryam Mahdavi 《Transition Metal Chemistry》2010,35(6):699-705
The water-soluble Ni(II) complex, [Ni(bipy)2(phen-dione)](OAc)2·2H2O (bipy = 2,2′-bipyridine and phen-dione = 1,10-phenanthroline-5,6-dione) has been synthesized and characterized by physico-chemical
and spectroscopic methods. The binding interactions of this complex with calf thymus DNA (CT-DNA) were investigated using
fluorimetry, spectrophotometry, circular dichroism and viscosimetry. In fluorimetric studies, the enthalpy and entropy of
the reaction between the complex and CT-DNA showed that the reaction is exothermic (ΔH = −123.9 kJ mol−1; ΔS = −323.5 J mol−1 K−1). The competitive binding studies showed that the complex could not release methylene blue completely. The complex showed
absorption hyperchromism in its UV–Vis spectrum with DNA. The calculated binding constant, K
b obtained from UV–Vis absorption studies was 2 × 105 M−1. Moreover, the complex induced detectable changes in the CD spectrum of CT-DNA, as well as changes in its viscosity. The
results suggest that this nickel(II) complex interact with CT-DNA via a groove-binding mode. 相似文献
24.
Alireza Khorsandi Saeed Ghavami Sabouri Somaieh Fathi Marzieh Asadnia-Jahromi 《Optics & Laser Technology》2011,43(5):956-959
We have reported a modified V-shaped external cavity, which is constructed around a commercial diode laser operating at a center wavelength of λ=785 nm by adding a new coated glass plate with about 50% reflectivity to the cavity. This allows simultaneous dual-wavelengths operation in the vicinity of Δνmin=0.18 THz to Δνmax=0.22 THz, which can be used as laser source for terahertz generation either for semiconductor devices or nonlinear schemes. 相似文献
25.
Marzieh Riahinezhad Niousha Kazemi Neil McManus Alexander Penlidis 《Journal of polymer science. Part A, Polymer chemistry》2013,51(22):4819-4827
Reactivity ratios for the important acrylamide (AAm)/acrylic acid (AAc) copolymerization system exhibit considerable scatter in previously published literature, and therefore, there is a need for more definitive values for these reactivity ratios. An appropriate methodology, based on the error‐in‐variables‐model (EVM) framework along with a direct numerical integration procedure, is applied in order to determine reliable reactivity ratios. The reliability of the results is confirmed with extensive and independent replication. Furthermore, via an EVM‐based criterion for the design of experiments using mechanistic models, optimal feed compositions are calculated, and from these optimal reactivity ratios are estimated for the first time (rAAm = 1.33 and rAAc = 0.23) based on information from the full conversion range. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4819–4827 相似文献
26.
In this paper, for the first time, an inorganic–organic hybrid material based on ZnO nanoparticles was anchored to a composite made from polythiophene and hexagonally ordered silica (ZnO/PT/SBA-15) for use in solid-phase fibre microextraction (SPME) of medicinal plants. A homemade SPME apparatus was used for the extraction of volatile components of Ziziphora tenuior L. A simplex method was used for optimisation of five different parameters affecting the efficiency of the extraction. The main constituents extracted by ZnO/PT/SBA-15 and PDMS fibres and hydrodistillation (HD) methods, respectively, included pulegone (51.25%, 53.64% and 56.68%), limonene (6.73%, 6.58% and 8.3%), caryophyllene oxide (5.33%, 4.31% and 4.53%) and 1,8-cineole (4.21%, 3.31% and 3.18%). In comparison with the HD method, the proposed technique could equally monitor almost all the components of the sample, in an easier way, in a shorter time and requiring a much lower amount of the sample. 相似文献
27.
Explicit constructions and properties of generalized shift-invariant systems in $L^{2}(\mathbb {R})$
Ole Christensen Marzieh Hasannasab Jakob Lemvig 《Advances in Computational Mathematics》2017,43(2):443-472
Generalized shift-invariant (GSI) systems, originally introduced by Hernández et al. and Ron and Shen, provide a common frame work for analysis of Gabor systems, wavelet systems, wave packet systems, and other types of structured function systems. In this paper we analyze three important aspects of such systems. First, in contrast to the known cases of Gabor frames and wavelet frames, we show that for a GSI system forming a frame, the Calderón sum is not necessarily bounded by the lower frame bound. We identify a technical condition implying that the Calderón sum is bounded by the lower frame bound and show that under a weak assumption the condition is equivalent with the local integrability condition introduced by Hernández et al. Second, we provide explicit and general constructions of frames and dual pairs of frames having the GSI-structure. In particular, the setup applies to wave packet systems and in contrast to the constructions in the literature, these constructions are not based on characteristic functions in the Fourier domain. Third, our results provide insight into the local integrability condition (LIC). 相似文献
28.
Tahereh Naderi Joloudar Ali Akbar Saboury Marzieh Dehghan Shasaltaneh Seifollah Bahramikia Mohammad Ali Ebrahimi Atiyeh Ghasemi 《Journal of the Iranian Chemical Society》2017,14(11):2407-2416
A key feature in more than twenty amyloid-related diseases is the aggregation of intra-and/or extracellular misfolded proteins as amyloid fibrils. Therefore, preventing or reversing amyloid aggregation by using of small molecules is considered as useful approaches to the treatment of these diseases. We have evaluated the ability of safranal and crocin, to inhibit amyloid self-assembly of hen egg white lysozyme (HEWL), as an in vitro model system. Structural properties of HEWL in the presence of these compounds were investigated individually using thioflavin T, anilinonaphthalene-8-sulfonic acid fluorescence assays, far-UV circular dichroism and scanning electron microscopy as well as docking method. Our results showed that incubation of HEWL with either crocin or safranal at various concentrations leads a significant inhibition in the rate of amyloid formation. Docking analysis revealed crocin and safranal interact with the central hydrophobic region of lysozyme through van der Waals interaction. Hydroxyl group in crocin through hydrogen bonds connected to the several hydrophilic amino acids of lysozyme, while in safranal there are just one aldehyde group that through hydrogen bonds connected to aspartic acid in lysozyme. It can be concluded that both hydrophobic and hydrophilic groups contribute to lower lysozyme fibril accumulation. 相似文献
29.
Marzieh Foroughpour Saeid Davatolhagh Abdol-Hamid Tabatabaeifar 《The European Physical Journal B - Condensed Matter and Complex Systems》2013,86(3):1-7
The transition metal pnictides ABX2 have been recently proposed as half-metallic fully compensated ferrimagnets, also briefly referred to as half-metallic “antiferromagnets” [N. Long, M.Ogura, H. Akai, J. Phys.: Condens. Matter 21, 064241 (2009)]. In this work we carry out a systematic study of the more promising cases of the transition metal nitrides MnCoN2 and NiCrN2 on the basis of density functional theory in the framework of full-potential linearized augmented plane wave method. The electronic structures and the magnetic properties of the above hypothetical compounds in Zinc-blende-type, NaCl-type, and Wurtzite-type structure are calculated within generalized gradient approximation. The results reveal that, although these compounds are metallic in their bulk equilibrium in all three structures, they exhibit antiferromagnetic half-metallicity under negative stress or volume expansion in a limited range of lattice parameters, which is significantly larger than the equilibrium values. This suggests that a situation in which half-metallicity may arise, is when these compounds are coated on semiconducting layers of larger lattice constant. 相似文献
30.
More than 70% of the world's nickel reserves are found in laterite ores. In this research, a laterite ore sample, containing Ni, Co, and Fe, was employed to study the recovery of nickel and cobalt. Thus, the effect of calcination, acid concentration, percent solids, and stirring rate on nickel and cobalt recoveries from an iron-rich laterite sample was investigated. Optimization with response surface methodology and kinetic studies were performed. The calcination of the sample prior to leaching at 500°C for 2 h provided condition for better nickel and cobalt dissolutions. At optimal conditions, the concentration of sulfuric acid, solid-to-liquid ratio, stirring speed, temperature, and time test were equal to 5 M, 0.1, 370 rpm, 90°C, and 2 h, respectively. The highest recoveries of nickel and cobalt were 65.9% and 63.1%, respectively. Solids content had a negative effect on Ni and Co recovery, whereas acid concentration was positively affected. Addition of 10% (w/v) NaCl in the presence of 5 M acid concentration, 60°C, 370 rpm, and leaching time of 2 h increased the nickel and cobalt recoveries, 15.3% and 21.4%, respectively. The high dependence of process on temperature indicates chemical control; the activation energies Ea = 59.54 and Ea = 45.74 kJ/mol, respectively, for nickel and cobalt, were also consistent with this conclusion. 相似文献