Prediction of the acid value,peroxide value and the percentage of some fatty acids in edible oils during long heating time by chemometrics analysis of FTIR-ATR spectra

Edible oils are used in the preparation of foods as a part of their recipe or for frying. So to ensure of food safety, checking the quality of the oils before and after usage is an important subject in food control laboratories. In this study, edible oils from four different sources (canola, corn, sunflower and frying) were heated for 36 h at 170 °C and sampling was done every 6 h. The free fatty acid, peroxide value and the content of some fatty acids (C16:0, C18:0, C18:1, C18:2, C18:3) of the oil samples were determined by standard methods. Then, the ATR-FTIR spectra of the samples were collected. The partial least squares (PLS) regression combined with genetic algorithm was performed on the spectroscopic data to obtain the appropriate predictive models for the simultaneous estimation of acid value, peroxide value and the percentage of five kinds of fatty acids. The effect of some preprocessing methods on these models was also investigated. Preprocessing of data by orthogonal signal correction (OSC) resulted in the best predictive models for all oil properties. The correlation coefficients of calibration set (>0.99) and validation set (>0.86 and in most case >0.94) of the OSC–PLS model suggested suitable predictive modeling for all studied parameters in the oil samples. This method could be suggested as a rapid, economical and environmental friendly technique for simultaneous determination of seven noted parameters in the edible oils.     

Solid phase extraction and graphite furnace atomic absorption spectrometric determination of ultra trace amounts of bismuth in water samples

A simple and reliable method for the selective extraction and determination of bismuth in water as well as alloy samples using octadecyl bonded silica cartridge modified with cyanex 301 and graphite furnace atomic absorption spectrometry is described. Extraction efficiency and influence of sample matrix, optimum amount of extraction ligand, type and least amount of proper eluent and flow rates were evaluated. The limit of detection of the proposed method is 0.01 ng ml(-1). The influence of potential interfering cations in water samples on the recovery of bismuth was investigated. The method was successfully applied to the extraction and determination of bismuth in natural water and alloy samples.     

Electrochemical sensing of <Emphasis Type="SmallCaps">D</Emphasis>-penicillamine on modified glassy carbon electrode by using a nanocomposite of gold nanoparticles and reduced graphene oxide

A new electrochemical sensor was developed for determination of D-penicillamine using glassy carbon electrode which had been modified by gold nanoparticles–reduced graphene oxide nanocomposite (AuNPs/RGO/GCE) in aqueous solution. Cyclic voltammetry, transmission electron microscopy and electrochemical impedance spectroscopy were used for characterization of the modified electrode. The results indicated that the kinetic of oxidation reaction of D-penicillamine at the surface of the electrode was controlled by both diffusion and adsorption processes. In 0.1 mol L^?1 phosphate buffer (pH 2.0), the oxidation current increased linearly with concentration of D-penicillamine with a linear range of 5.0 × 10^?6 to 1.1 × 10^?4 mol L^?1 and regression coefficient of R ² = 0.9972. Theoretical detection limit, defined based on 3σ of the blank signal (n = 9) divided by the slope of the linear regression equation, was 3.9 × 10^?6 mol L^?1 D-penicillamine using differential pulse voltammetry. The developed method was successfully applied to the determination of D-penicillamine in pharmaceutical formulation and blood serum samples.     

Unsteady Natural Convection Within a Porous Enclosure of Sinusoidal Corrugated Side Walls

Numerically investigation of free convection within a porous cavity with differential heating has been performed using modified corrugated side walls. Sinusoidal hot left and cold right walls are assumed to receive sudden differentially heating where top and bottom walls are insulated. Air is considered as working fluid and is quiescent, initially. Numerical experiments reveal 3 distinct stages of developing pattern including initial stage, oscillatory intermediate, and finally steady-state condition. Implicit Finite Volume Method with TDMA solver is used to solve the governing equations. This study has been performed for the Rayleigh numbers ranging from 100 to 10,000. Outcomes have been reported in terms of isotherms, streamline, velocity and temperature plots and average Nusselt number for various Ra, corrugation frequency, and corrugation amplitude (CA). The effects of sudden differential heating and its resultant transient behavior on fluid flow and heat transfer characteristics have been shown for the range of governing parameters. The present results show that the transient phenomena are enormously influenced by the variation of the Rayleigh Number with CA and frequency.     

Characterization of Tetracyanopyridine (TCNPy)‐Based Magnets: V[TCNPy]2⋅z (CH2Cl2) (Tc=111 K) and V[TCNPy]3⋅z (CH2Cl2) (Tc=90 K)

The reaction of 2,3,5,6‐tetracyanopyridine (TCNPy) with V(CO)₆ in CH₂Cl₂ forms new organic‐based magnets of V[TCNPy]_x?z (CH₂Cl₂) (x=2, 3) composition. Analysis of the IR spectra suggests that the TCNPy is reduced and coordinated to V^II sites through the nitriles. V[TCNPy]_x order as ferrimagnets with 111 and 90 K T_c values for V[TCNPy]₂ and V[TCNPy]₃, respectively. Their respective remanent magnetizations and coercive fields are 1260 and 250 emuOe mol^?1 and 9 and 6 Oe at 5 K, and they exhibit some spin‐glass behavior.     

Noetherian rings with almost injective simple modules

We characterize right Noetherian rings over which all simple modules are almost injective. It is proved that R is such a ring, if and only if, the complements of semisimple submodules of every R-module M are direct summands of M, if and only if, R is a finite direct sum of right ideals I_r, where I_r is either a Noetherian V-module with zero socle, or a simple module, or an injective module of length 2. A commutative Noetherian ring for which all simple modules are almost injective is precisely a finite direct product of rings R_i, where R_i is either a field or a quasi-Frobenius ring of length 2. We show that for commutative rings whose all simple modules are almost injective, the properties of Kasch, (semi)perfect, semilocal, quasi-Frobenius, Artinian, and Noetherian coincide.     

Plasmonically enhanced optical transmission through a metalized nanostructured photonic crystal fiber taper

A subwavelength holey plasmonic structure was proposed by adiabatically tapering a photonic crystal fiber (PCF) and subsequently metalizing the cleaved end facet. By coupling a white light into the PCF side, we experimentally observed an enhanced optical transmission in the spectral domain through the plasmonic structure at the tapered end. We further showed numerically that the proposed device renders a focused directional beam, due to its Fresnel-zone-like configuration and the plasmonic lensing effects.     

2,6‐Dicarboxypyridinium Fluorochromate: A Mild and Efficient Reagent for Oxidative Deprotection of Oximes,Phenylhydrazones, and Semicarbazones to Their Corresponding Carbonyl Compounds under Solvent‐Free Conditions

2,6‐Dicarboxypyridinium fluorochromate as a new, rapid, and efficient reagent was prepared and used for the oxidative deprotection of oximes, phenylhydrazones, and semicarbazones to their carbonyl analogues under solvent‐free conditions at room temperature.