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951.
Majid M. Heravi Khadijeh Bakhtiari Tina Benmorad Fatemeh F. Bamoharram Hossein A. Oskooie Maryam H. Tehrani 《Monatshefte für Chemie / Chemical Monthly》2007,138(5):449-452
Summary. The nitration of aromatic compounds was carried out in the presence of divanadium-substituted molybdophosphoric acid, H5PMo10V2O40, as catalyst and a mixture of nitric acid and acetic anhydride as nitrating agent. In the presence of this heteropolyacid
the ortho- and para-nitro compounds were obtained in good to excellent yields under mild reaction conditions. 相似文献
952.
Issa Yavari Zinatossadat Hossaini Maryam Sabbaghan Majid Ghazanfarpour-Darjani 《Tetrahedron》2007,63(38):9423-9428
The reaction of ethyl propiolate with triphenylphosphine (Ph3P) in the presence of N-alkylisatins led to ethyl 2,2,2-triphenyl-2,5-dihydro-1,2-λ5-oxaphosphole-4-carboxylate-spiro-1-alkyl-1,3-dihydro-2H-indol-2-ones in good yield. The reaction of dialkyl acetylenedicarboxylates with Ph3P in the presence of N-alkylisatins led to dialkyl 2,2,2-triphenyl-2,5-dihydro-1,2-λ5-oxaphosphole-3,4-dicarboxylate-spiro-1-alkyl-1,3-dihydro-2H-indol-2-ones and alkyl 4-(alkoxy)-5-oxo-2,5-dihydro-3-furancarboxylate-spiro-1-alkyl-1,3-dihydro-2H-indol-2-ones. 相似文献
953.
Akbar Heydari Roohollah Kazem Shiroodi Hossein Hamadi Maryam Esfandyari Mehrdad Pourayoubi 《Tetrahedron letters》2007,48(33):5865-5868
The commercially available heteropoly acid H3PW12O40 (0.5 mol %) is a very efficient and environmentally benign catalyst for N-tert-butoxycarbonylation of amines (primary, secondary) with di-tert-butyl dicarbonate at room temperature in short reaction times (<10 min). No competitive side products such as isocyanates, ureas, N,N-di-tert-butoxycarbonyls, O-Boc and oxazolidinones were observed. Chiral α-amino alcohols and esters afforded the corresponding N-Boc derivatives chemoselectively in excellent yields. 相似文献
954.
Akbar Heydari Samad Khaksar Maryam Esfandyari Mahmoud Tajbakhsh 《Tetrahedron letters》2007,48(7):1135-1138
A simple and convenient procedure for direct reductive amination of aldehydes and ketones with sodium borohydride is described. The reaction has been carried out in methanol in the presence of a catalytic amount of H3PW12O40 (0.5 mol %). α,β-Unsaturated aldehydes and ketones can be easily converted into the corresponding allyl alcohols by reaction with H3PW12O40 (0.5 mol %)/NaBH4. 相似文献
955.
Dabbagh HA Teimouri A Chermahini AN Shahraki M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(2):449-459
We present a detailed analysis of the structural, infrared spectra and visible spectra of a series of azo dyes preparation of salicylic acid and 2,4-dihydroxy benzoic acid derivatives as the coupling component. The preparation of these azo dyes with salicylic acid and 2,4-dihydroxy benzoic acid derivatives (salicylic acid, methyl salicylate, ethyl salicylate, butyl salicylate, methyl 2,4-dihydroxy benzoate, ethyl 2,4-dihydroxy benzoate, salicylaldehyde, salicylamide, 2,4-dihydroxy benzamide, salicylaldoxime) have been investigated theoretically by performing HF and DFT levels of theory using the standard 6-31G* basis set. The optimized geometries and calculated vibrational frequencies are evaluated via comparison with experimental values. The vibrational spectral data obtained from solid phase FT-IR spectra are assigned modes based on the results of the theoretical calculations. The observed spectra are found to be in good agreement with the calculations. 相似文献
956.
Seyed Hadi Peighambardoust Maryam Jafarzadeh-Moghaddam Mirian Pateiro Jos M. Lorenzo Rubn Domínguez 《Molecules (Basel, Switzerland)》2021,26(5)
The objective of this study was to characterize the properties of pectin extracted from sugar beet pulp using subcritical water (SWE) as compared to conventional extraction (CE). The research involved advanced modeling using response surface methodology and optimization of operational parameters. The optimal conditions for maximum yield of pectin for SWE and CE methods were determined by the central composite design. The optimum conditions of CE were the temperature of 90 °C, time of 240 min, pH of 1, and pectin recovery yield of 20.8%. The optimal SWE conditions were liquid-to-solid (L/S) ratio of 30% (v/w) at temperature of 130 °C for 20 min, which resulted in a comparable yield of 20.7%. The effect of obtained pectins on viscoamylograph pasting and DSC thermal parameters of corn starch was evaluated. The contents of galacturonic acid, degree of methylation, acetylation, and ferulic acid content were higher in the pectin extracted by SWE, while the molecular weight was lower. Similar chemical groups were characterized by FTIR in both SWE and CE pectins. Color attributes of both pectins were similar. Solutions of pectins at lower concentrations displayed nearly Newtonian behavior. The addition of both pectins to corn starch decreased pasting and DSC gelatinization parameters, but increased ΔH. The results offered a promising scalable approach to convert the beet waste to pectin as a value-added product using SWE with improved pectin properties. 相似文献
957.
Maryam Mirzakhani 《Journal of the American Mathematical Society》2007,20(1):1-23
In this paper, we establish a relationship between the Weil- Petersson volume of the moduli space of hyperbolic Riemann surfaces with geodesic boundary components of lengths , and the intersection numbers of tautological classes on the moduli space of stable curves. As a result, by using the recursive formula for obtained in the author's Simple geodesics and Weil-Petersson volumes of moduli spaces of bordered Riemann surfaces, preprint, 2003, we derive a new proof of the Virasoro constraints for a point. This result is equivalent to the Witten-Kontsevich formula.
958.
Hojati Seyedeh Fatemeh Amiri Amirhassan Fardi Elham Mahamed Maryam 《Research on Chemical Intermediates》2022,48(4):1347-1363
Research on Chemical Intermediates - Two new magnetic nanocomposites containing aniline–pyrrole copolymer-coated magnetic carbon nano-tubes (poly(Ani-co-Py)@CNT-Fe3O4) were synthesized and... 相似文献
959.
Dr. Saeedeh Sarabadani Tafreshi Mahkameh Ranjbar Dr. Narges Taghizade Dr. S. F. K. S. Panahi Dr. Maryam Jamaati Prof. Nora H. de Leeuw 《Chemphyschem》2022,23(6):e202100781
As promising materials for the reduction of greenhouse gases, transition-metal carbides, which are highly active in the hydrogenation of CO2, are mainly considered. In this regard, the reaction mechanism of CO2 hydrogenation to useful products on the Nb-terminated NbC (111) surface is investigated by applying density functional theory calculations. The computational results display that the formation of CH4, CH3OH, and CO are more favored than other compounds, where CH4 is the dominant product. In addition, the findings from reaction energies reveal that the preferred mechanism for CO2 hydrogenation is thorough HCOOH*, where the largest exothermic reaction energy releases during the HCOOH* dissociation reaction (2.004 eV). The preferred mechanism of CO2 hydrogenation towards CH4 production is CO2*→t,c-COOH*→HCOOH*→HCO*→CH2O*→CH2OH*→CH2*→CH3*→CH4*, where CO2*→t,c-COOH*→HCOOH*→HCO*→CH2O*→CH2OH*→CH3OH* and CO2*→t,c-COOH*→CO* are also found as the favored mechanisms for CH3OH and CO productions thermodynamically, respectively. During the mentioned mechanisms, the hydrogenation of CH2O* to CH2OH* has the largest endothermic reaction energy of 1.344 eV. 相似文献
960.
The reactions of 4‐amino‐5‐methyl‐2H‐1,2,4‐triazole‐3(4H)‐thione (AMTT, L1 ) with 2‐thiophen carbaldehyde, salicylaldehyde and 2‐nitrobenzaldehyde in methanol led to the corresponding Schiff‐bases ( L1a‐c ). The reaction of L1 with [(PPh3)2Cu]NO3 in ethanol gave the ionic complex [(PPh3)2Cu(L1)]NO3·EtOH ( 2 ) All compounds were characterized by infrared spectroscopy, elemental analyses as well as by X‐ray diffraction studies. Crystal data for L1a at 20 °C: space group P21/n with a = 439.6(2), b = 2074.0(9), c = 1112.8(4) pm, β = 93.51(3)°, Z = 4, R1 = 0.0406, L1b at ?80 °C: space group P21/n with a = 1268.9(2), b = 739.3(1), c = 1272.5(1) pm, β = 117.97(1)°, Z = 4, R1 = 0.0361, L1c at ?80 °C: space group P21/n with a = 847.8(1), b = 1502.9(2), c = 981.5(2) pm, β = 110.34(1)°, Z = 4, R1 = 0.0376 and for 2 at ?80 °C: space group with a = 1247.8(1), b = 1270.3(1), c = 1387.5(1) pm, α = 84.32(1)°, β = 84.71(1)°, γ = 63.12(1)°, Z = 2, R1 = 0.0539. 相似文献