全文获取类型
收费全文 | 3437篇 |
免费 | 74篇 |
国内免费 | 7篇 |
专业分类
化学 | 2356篇 |
晶体学 | 42篇 |
力学 | 68篇 |
数学 | 356篇 |
物理学 | 696篇 |
出版年
2022年 | 40篇 |
2021年 | 37篇 |
2020年 | 50篇 |
2019年 | 40篇 |
2018年 | 26篇 |
2017年 | 27篇 |
2016年 | 47篇 |
2015年 | 52篇 |
2014年 | 71篇 |
2013年 | 163篇 |
2012年 | 148篇 |
2011年 | 201篇 |
2010年 | 119篇 |
2009年 | 83篇 |
2008年 | 181篇 |
2007年 | 199篇 |
2006年 | 196篇 |
2005年 | 194篇 |
2004年 | 177篇 |
2003年 | 134篇 |
2002年 | 131篇 |
2001年 | 62篇 |
2000年 | 47篇 |
1999年 | 37篇 |
1998年 | 35篇 |
1997年 | 43篇 |
1996年 | 41篇 |
1995年 | 39篇 |
1994年 | 52篇 |
1993年 | 58篇 |
1992年 | 33篇 |
1991年 | 42篇 |
1990年 | 37篇 |
1989年 | 29篇 |
1988年 | 30篇 |
1987年 | 21篇 |
1986年 | 23篇 |
1985年 | 31篇 |
1984年 | 46篇 |
1983年 | 29篇 |
1982年 | 49篇 |
1981年 | 37篇 |
1980年 | 29篇 |
1979年 | 35篇 |
1978年 | 36篇 |
1977年 | 29篇 |
1976年 | 38篇 |
1975年 | 28篇 |
1974年 | 30篇 |
1973年 | 23篇 |
排序方式: 共有3518条查询结果,搜索用时 15 毫秒
121.
A comparison between various recommended reference standards of diffuse reflectance in the IR is presented. It is shown that at a wavelength of 10.6 μm sulfur is the most Lambertian of the tested samples, although its powdery consistence makes it less suitable for use as a standard. Flame sprayed aluminum, with or without gold coating, also approaches a Lambertian surface and is suitable for use as a standard for BRDF measurements at 10.6 μm. Results for the BRDF of sulfur, gold-coated sandpaper, a commercial diffuse gold surface (by Labsphere) and flame sprayed aluminum are presented. 相似文献
122.
Mary E. Gbur 《Monatshefte für Mathematik》1976,81(2):95-107
C. Hightower found two infinite sequences of gaps in the Markov spectrum, (
n
,
n
) and (
n
,
n
) with
n
and
n
both Markov elements, converging to
. This paper exhibits Markov elements
n
*
and
n
*
such that, for alln 1, (
n
*
,
n
) and (
n
n
*
) are gaps in the Markov spectrum. Other results include showing that, for alln 1,
n
is completely isolated, while the other endpoints of the gaps are limit points in the Markov spectrum. 相似文献
123.
124.
125.
Conventional design of radiation detectors uses sintered ceramic insulating modules. The major drawback of these ceramic components
is their inherent brittleness. Ion chambers, in which these ceramic spacers are replaced by metallic components with plasma
spray coated alumina, have been developed in our Research Centre. These components act as thin spacers that have good mechanical
strength as well as high electrical insulation and replace alumina insulators with the same dimensions. As a result, the design
of the beam loss monitor ion chamber for CAT could be simplified by coating the outer surface of the HT electrode with alumina.
One of the chambers developed for isotope calibrator for brachytherapy gamma sources has its outer aluminium electrode (60
mm dia × 220 mm long) coated with 250 μ thick alumina (97%) + titania (3%).
In view of potential applications in neutron-sensitive ion chambers used in reactor control instrumentation, studies were
carried out on alumina 100 μ to 500 μ thick coatings on copper, aluminium and SS components. The electrical insulation varied
from 108 ohms to 1012 ohms for coating thicknesses above 200 μ. The porosity in the coating resulted in some fall in electrical insulation due
to moisture absorption. An improvement could be achieved by providing the ceramic surface with moisture-repellent silicone
oil coating. Irradiation at Apsara reactor core location showed that the coating on aluminium was found to be unaffected after
exposure to 1017 nvt fluence. 相似文献
126.
Dr. Daiki Umeyama Dr. Linn Leppert Bridget A. Connor Dr. Mary Anne Manumpil Prof. Jeffrey B. Neaton Prof. Hemamala I. Karunadasa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(43):19249-19256
Replacing the Pb−X octahedral building unit of AIPbX3 perovskites (X=halide) with a pair of edge-sharing Pb−X octahedra affords the expanded perovskite analogs: AIIPb2X6. We report seven members of this new family of materials. In 3D hybrid perovskites, orbitals from the organic molecules do not participate in the band edges. In contrast, the more spacious inorganic sublattice of the expanded analogs accommodates larger pyrazinium-based cations with low-lying π* orbitals that form the conduction band, substantially decreasing the band gap of the expanded lattice. The molecular nature of the conduction band allows us to electronically dope the materials by reducing the organic molecules. By synthesizing derivatives with AII=pyridinium and ammonium, we can isolate the contributions of the pyrazinium-based orbitals in the band gap transition of AIIPb2X6. The organic-molecule-based conduction band and the inorganic-ion-based valence band provide an unusual electronic platform with localized states for electrons and more disperse bands for holes upon optical or thermal excitation. 相似文献
127.
Debanjan Chakraborty Shyamapada Nandi Rahul Maity Dr. Radha Kishan Motkuri Dr. Kee Sung Han Sean Collins Dr. Paul Humble Dr. James C. Hayes Prof. Tom K. Woo Dr. Ramanathan Vaidhyanathan Dr. Praveen K. Thallapally 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(55):12544-12548
Molecular confinement plays a significant effect on trapped gas and solvent molecules. A fundamental understanding of gas adsorption within the porous confinement provides information necessary to design a material with improved selectivity. In this regard, metal–organic framework (MOF) adsorbents are ideal candidate materials to study confinement effects for weakly interacting gas molecules, such as noble gases. Among the noble gases, xenon (Xe) has practical applications in the medical, automotive and aerospace industries. In this Communication, we report an ultra-microporous nickel-isonicotinate MOF with exceptional Xe uptake and selectivity compared to all benchmark MOF and porous organic cage materials. The selectivity arises because of the near perfect fit of the atomic Xe inside the porous confinement. Notably, at low partial pressure, the Ni–MOF interacts very strongly with Xe compared to the closely related Krypton gas (Kr) and more polarizable CO2. Further 129Xe NMR suggests a broad isotropic chemical shift due to the reduced motion as a result of confinement. 相似文献
128.
Torsion balances have good immunity to tilt and low rotational stiffness. However precise control of the position of the suspended torsion ‘bob’ is difficult in the presence of ground vibrations and tilt and this is a limiting factor in applications where Casimir forces or putative non-Newtonian short-range forces are being measured. We describe how the desirable characteristics of torsion balances can be reproduced in a rigid body that is suspended using applied forces rather than a torsion fibre. The suspension system can then provide a more precise control of the degrees of freedom of the suspended body. We apply these ideas to a superconducting levitated torsion balance, developed by the authors, and a generic electrostatic suspension. We present results of preliminary experiments that provide support for our analyses. 相似文献
129.
The perturbation function of a Cd probe atom bound in a hydrogen-decorated vacancy complex in Pt is found to exhibit dynamical
relaxation at 294 K, as measured by the technique of perturbed γ-γ angular correlations. Based on other characteristics of
the complex, a model is proposed for the structure of the complex. In the undecorated state, it consists of a probe atom at
the center of a tetrahedron of vacancies in the fcc structure. In the decorated state at low temperature, the probe atom returns
to one of the four vacant lattice sites. The relaxation at room temperature is attributed to motion of the probe atom in a
cage formed by the four vacant sites. 相似文献
130.
C. B. Collins 《Communications in Mathematical Physics》1972,27(1):37-43
The technique of phase plane analysis, which was used in a previous paper [4] to study the behaviour of a class of perfect-fluid anisotropic cosmological models, is applied to some simple anisotropic models that contain a uniform magnetic field. A formal correspondence is established between these magnetic models (of Bianchi type I) and certain perfect fluid models (of Bianchi type II), and new exact solutions are consequently discovered. 相似文献