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This study sets out to examine whether the demand for softwood lumber in the United States is responsive to various market factors including the price of softwood lumber, the price of other building materials, and the level of economic activity (e.g. housing starts). Concern in the analysis is focused on overcoming some of the methodological shortcomings found in previous studies of this issue. The results are conclusive. The quantity of softwood lumber demanded does respond to the various economic factors considered. Moreover, when the structural stability of the estimated relationships is investigated, the results suggest that the demand for softwood lumber regionally in the United States has remained unaltered over the sample period (1950–1985). 相似文献
74.
75.
Zhongren Wu Maria G Cappiello Boyd B Scott Yuri Bukhtiyarov Gerard M McGeehan 《BMC biochemistry》2008,9(1):19
Background
The renin-angiotensin-aldosterone system (RAS) cascade is a major target for the clinical management of hypertension. Although inhibitors of various components of this cascade have been developed successfully, development of renin inhibitors has proven to be problematic. The development of these inhibitors has been hindered by poor bioavailability and complex synthesis. However, despite the challenges of designing renin inhibitors, the enzyme remains a promising target for the development of novel treatments for hypertension. X-ray crystallographic data could greatly assist the design and development of these inhibitors. Here we describe the purification and characterization of recombinant human renin for x-ray crystallization studies. 相似文献76.
Keisuke Akita Youhi Morii Hisashi Nakamura Takuya Tezuka Kaoru Maruta 《Proceedings of the Combustion Institute》2021,38(2):2247-2255
Two-dimensional axisymmetric numerical simulation reproduced flames with repetitive extinction and ignition (FREI) in a micro flow reactor with a controlled temperature profile with a stoichiometric n-heptane/air mixture, which have been observed in the experiment. The ignition of hot flame occurred from consumption reactions of CO that was remained in the previous cycle of FREI. Between extinction and ignition locations of hot flames, several other heat release rate peaks related to cool and blue flames were observed for the first time. After the extinction of the hot flame, cool flame by the low-temperature oxidation of n-heptane appeared first and was stabilized in a low wall temperature region. In the downstream of the stable cool flame, a blue flame by the consumption reactions of cool flame products of CH2O and H2O2 appeared. After that, the hot flame ignition occurred from the remaining CO in the downstream of the blue flame. Then after the next hot flame ignition, the blue flame was swept away by the propagating hot flame. Soon before the hot flame merged with the stable cool flame, the hot flame propagation was intensified by the cool flame. After the hot flame merged with the stable cool flame, the hot flame reacted with the incoming fresh mixture of n-C7H16 and O2. 相似文献
77.
Hugo J. Bohórquez Chérif F. Matta Russell J. Boyd 《International journal of quantum chemistry》2010,110(13):2418-2425
The local single particle momentum is proposed as a localized‐electrons detector (LED) that provides a direct three‐dimensional representation of bonding interactions in molecules. It is given exclusively in terms of the electron density and its gradient. We show that the graphical representation of bonding interactions given by LED is consistent with the local curvatures of the electron density as given by the eigenvalues of the Hessian matrix, according to a local symmetry classification of the critical points here introduced. LED consistently complements the topological analysis of the electron density given by the quantum theory of atoms in molecules, by providing a graphical representation of the symmetry of the bonding interactions in molecular systems. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem 110:2418–2425, 2010 相似文献
78.
The absolute configurations of 2-cyclohexenone cis-diol metabolites resulting from the biotransformation of the corresponding phenols have been determined by comparison of their experimental and calculated circular dichroism spectra (TDDFT at the PCM/B2LYP/Aug-cc-pVTZ level), optical rotations (calculated at the PCM/B3LYP/Aug-cc-pVTZ level) and by stereochemical correlation. It is found that circular dichroism spectra and optical rotations of 2-cyclohexenone derivatives are strongly dependent on the ring conformation (M or P sofa S(5) or half-chair), enone non-planarity and the nature and positions of the hydroxy and alkyl substituents. The effect of non-planarity of the enone chromophore, including the distortion of the C=C bond, is determined for the model structures by TDDFT calculations at the PCM/B2LYP/6-311++G(2d,2p) level. Non-planarity of the C=C bond in the enone chromophore is commonly encountered in 2-cyclohexenone derivatives and it is a source of significant rotatory strength contribution to the electronic circular dichroism spectra. It is shown that the two lowest-energy transitions in acrolein and 2-cyclohexenone and its derivatives are n(C=O)-π(C=O)* and π(C=C)-π(C=O)*, as expected, while the shorter-wavelength (below 200 nm) transitions are of more complex nature. In 2-cyclohexenone and its alkyl derivatives it is predominantly a mixture of π(C=C)-π(C=C)* and π(C=C)-σ* transitions, whereas the presence of hydroxy substituent results in a dominant contribution due to the n(OH)-π(C=O)* transition. A generalized model for correlation of the CD spectra of 2-cyclohexenones with their structures is presented. 相似文献
79.
Kudavalli JS Boyd DR Coyne D Keeffe JR Lawlor DA MacCormac AC More O'Ferrall RA Rao SN Sharma ND 《Organic letters》2010,12(23):5550-5553
Benzene-cis- and trans-1,2-dihydrodiols undergo acid-catalyzed dehydration at remarkably different rates: k(cis)/k(trans) = 4500. This is explained by formation of a β-hydroxycarbocation intermediate in different initial conformations, one of which is stabilized by hyperconjugation amplified by an aromatic no-bond resonance structure (HOC(6)H(6)(+) ? HOC(6)H(5) H(+)). MP2 calculations and an unfavorable effect of benzoannelation on benzenium ion stability, implied by pK(R) measurements of -2.3, -8.0, and -11.9 for benzenium, 1-naphthalenium, and 9-phenanthrenium ions, respectively, support the explanation. 相似文献
80.
Accurate size measurement during nanoparticle production is essential for the continuing innovation, quality and safety of
nano-enabled products. Size measurement by analysing a number of separate particles individually has particular advantages
over ensemble methods. In the latter case nanoparticles have to be well dispersed in a fluid and changes that may occur during
analysis, such as agglomeration and degradation, will not be detected which could lead to misleading results. Atomic force
microscopy (AFM) allows imaging of particles both in air and liquid, however, the strong interactions between the probe and
the particle will cause the broadening of the lateral dimension in the final image. In this paper a new procedure to measure
the size of spherical nanoparticles from AFM images via vertical height measurement is described. This procedure will quickly
analyse hundred of particles simultaneously and reproduce the measurements obtained from electron microscopy (EM). Nanoparticles
samples that were difficult, if not impossible, to analyse with EM were successfully measured using this method. The combination
of this procedure with the use of a metrological AFM moves closer to true traceable measurements of nanoparticle dispersions. 相似文献