全文获取类型
收费全文 | 5057篇 |
免费 | 187篇 |
国内免费 | 16篇 |
专业分类
化学 | 3322篇 |
晶体学 | 54篇 |
力学 | 109篇 |
数学 | 555篇 |
物理学 | 1220篇 |
出版年
2023年 | 47篇 |
2022年 | 103篇 |
2021年 | 154篇 |
2020年 | 123篇 |
2019年 | 147篇 |
2018年 | 123篇 |
2017年 | 116篇 |
2016年 | 195篇 |
2015年 | 162篇 |
2014年 | 158篇 |
2013年 | 329篇 |
2012年 | 353篇 |
2011年 | 413篇 |
2010年 | 261篇 |
2009年 | 260篇 |
2008年 | 349篇 |
2007年 | 313篇 |
2006年 | 251篇 |
2005年 | 223篇 |
2004年 | 212篇 |
2003年 | 143篇 |
2002年 | 115篇 |
2001年 | 88篇 |
2000年 | 83篇 |
1999年 | 61篇 |
1998年 | 34篇 |
1997年 | 39篇 |
1996年 | 44篇 |
1995年 | 42篇 |
1994年 | 34篇 |
1993年 | 37篇 |
1992年 | 46篇 |
1991年 | 25篇 |
1990年 | 16篇 |
1989年 | 16篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 10篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 9篇 |
1978年 | 8篇 |
1977年 | 10篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1974年 | 7篇 |
1968年 | 4篇 |
排序方式: 共有5260条查询结果,搜索用时 15 毫秒
931.
D. S. L. Pontes E. Longo F. M. Pontes M. S. Galhiane L. S. Santos Marcelo A. Pereira-da-Silva J. H. D. da Silva A. J. Chiquito P. S. Pizani 《Applied Physics A: Materials Science & Processing》2009,96(3):731-740
Ferroelectric Pb1−x−y
Ca
x
Sr
y
TiO3 thin films (denoted by PCST90, PCST70, and PCST30) were deposited on the Pt/Ti/SiO2/Si substrates by a chemical solution deposition method. Their properties were investigated from the viewpoint of crystal
structure, microstructure, dielectric, and ferroelectric properties. X-ray diffraction patterns revealed the formation of
PCST90, PCST70, and PCST30 thin films without any secondary phases. Infrared and Raman spectroscopy results show that a gradual
phase transition from tetragonal to pseudocubic or cubic perovskite structure may occur in PCST thin films with the simultaneous
increase of Ca2+ and Sr2+ contents. Both substitution of isovalent Ca2+ and Sr2+ at Pb2+-site enhanced the dielectric constant and reduced the remnant polarization. In addition, ferroelectric test analyses show
that the PCST thin films undergo a ferroelectric-to-paraelectric phase transformation with an amount of Pb2+, Ca2+, and Sr2+ at 30%, 35%, and 35% mol, respectively. Hence, the absence of ferroelectric property may be attributed to a decreasing of
the octahedron distortion in the perovskite structure accompanied by a weakening of long-range ferroelectric order. 相似文献
932.
J. J. Camacho M. Santos L. Díaz J. M. L. Poyato 《Applied Physics A: Materials Science & Processing》2009,94(2):373-380
We have used ferrocene and paraffin wax as novel precursor and solvent for the growth of iron oxide nanoparticles. The proposed
method of growth has several advantages over existing methods of growth using iron pentacarbonyl a precursor. Highly crystalline
and monodispersed particles are obtained which assemble in two- and three-dimensional hexagonal closed packed superlattices.
Growth kinetics has been studied by varying concentration of the precursor and time of growth. A phenomenological model has
been proposed to explain the growth kinetics. 相似文献
933.
S. D. Baton M. Koenig J. Fuchs L. Gremillet C. Rousseaux D. Batani A. Morace M. Nakatsutsumi R. Kodama T. Norimatsu A. Nishida F. Dorchies C. Fourment J. J. Santos J. Rassuchine T. Cowan 《The European physical journal. Special topics》2009,175(1):77-82
We present experimental and numerical results obtained at LULI (Laboratoire pour l’Utilisation des Lasers intenses) on propagation and energy deposition of laser-generated fast electrons into conical targets. The experimental measurements
were performed by means of several diagnostics in order to assess the predicted benefit of conical targets over standard planar
ones. Various configurations have been tried, regarding the laser parameters with the aim of optimizing the laser-to-target
coupling. Our best results have been obtained when the laser was frequency-doubled at 0.53 μm, corresponding to interaction
conditions without laser pedestal due to the ASE (Amplified Spontaneous Emission). Our data pinpoint the detrimental influence of the pre-plasma generated by the laser pedestal at 1.057 μm, whose confinement
is enhanced in conical geometry as evidenced by shadowgraphic measurements which is also confirmed by 2D Cu-Ka transverse images obtained from Cu cones. The consequence is the filling of the cone, preventing the laser beam from efficiently
reaching the cone tip. These experimental results are compared to 2D PIC simulations modeling of the laser-cone interaction. 相似文献
934.
D. Martinez Santos 《Physics of Atomic Nuclei》2009,72(9):1548-1552
Due to its sensitivity to New Physics contributions, the branching ratio of the very rare decay B
s
0 → μ
+
μ
− is one of the most interesting measurements using the first data from the LHC accelerator. The analysis strategy for the
study of this channel in the LHCb experiment is presented, as well as a review of the potential of the experiment in such
study, using the latest simulations. With four months of nominal data taking, any enhancement from the Standard Model prediction
can be excluded. 相似文献
935.
R. Arnaldi K. Banicz K. Borer J. Castor B. Chaurand W. Chen C. Cicalò A. Colla P. Cortese S. Damjanovic A. David A. de Falco A. Devaux L. Ducroux H. En’yo J. Fargeix A. Ferretti M. Floris A. F?rster P. Force N. Guettet A. Guichard H. Gulkanyan J. Heuser M. Keil L. Kluberg Z. Li C. Louren?o J. Lozano F. Manso P. Martins A. Masoni A. Neves H. Ohnishi C. Oppedisano P. Parracho P. Pillot T. Poghosyan G. Puddu E. Radermacher P. Ramalhete P. Rosinsky E. Scomparin J. Seixas S. Serci R. Shahoyan P. Sonderegger H. J. Specht R. Tieulent A. Uras G. Usai R. Veenhof H. K. W?hri 《The European Physical Journal C - Particles and Fields》2009,64(1):1-18
The NA60 experiment has measured muon pair production in In–In collisions at 158 AGeV at the CERN SPS. This paper presents a high statistics measurement of φ→μ μ meson production. Differential spectra, yields, mass and width are measured as a function of centrality and compared to previous measurements in other colliding systems at the same energy. The width of the rapidity distribution is found to be constant as a function of centrality, compatible with previous results. The decay muon polar angle distribution is measured in several reference frames. No evidence of polarization is found as a function of transverse momentum and centrality. The analysis of the p T spectra shows that the φ has a small radial flow, implying a weak coupling to the medium. The T eff parameter measured in In–In collisions suggests that the high value observed in Pb–Pb in the kaon channel is difficult to reconcile with radial flow alone. The absolute yield is compared to results in Pb–Pb collisions: though significantly smaller than measured by NA50 in the muon channel, it is found to exceed the NA49 and CERES data in the kaon channel at any centrality. The mass and width are found to be compatible with the PDG values at any centrality and at any p T : no evidence for in-medium modifications is observed. 相似文献
936.
Carlos Franco-Paredes Peter Carrasco Jose Ignacio Santos Preciado 《Journal of immune based therapies and vaccines》2009,7(1):2-6
Influenza viruses pose a permanent threat to human populations due to their ability to constantly adapt to impact immunologically
susceptible individuals in the forms of epidemic and pandemics through antigenic drifts and antigenic shifts, respectively.
Pandemic influenza preparedness is a critical step in responding to future influenza outbreaks. In this regard, responding
to the current pandemic and preparing for future ones requires critical planning for the early phases where there is no availability
of pandemic vaccine with rapid deployment of medical supplies for personal protection, antivirals, antibiotics and social
distancing measures. In addition, it has become clear that responding to the current pandemic or preparing for future ones,
nation states need to develop or strengthen their laboratory capability for influenza diagnosis as well as begin preparing
their vaccine/antiviral deployment plans. Vaccine deployment plans are the critical missing link in pandemic preparedness
and response. Rapid containment efforts are not effective and instead mitigation efforts should lead pandemic control efforts.
We suggest that development of vaccine/antiviral deployment plans is a key preparedness step that allows nations identify
logistic gaps in their response capacity. 相似文献
937.
Two extended cavity laser diodes are phase-locked, thanks to an intra-cavity electro-optical modulator. The phase-locked loop bandwidth is on the order of 10 MHz, which is about twice larger than when the feedback correction is applied on the laser current. The phase noise reaches −120 dBrad2/Hz at 10 kHz. This new scheme reduces the residual laser phase noise, which constitutes one of the dominant contributions in the sensitivity limit of atom interferometers using two-photon transitions. 相似文献
938.
C.S. Riccardi R.C. Lima M.L. dos Santos P.R. Bueno J.A. Varela E. Longo 《Solid State Ionics》2009,180(2-3):288-291
Cerium carbonate hydroxide (orthorhombic Ce(OH)CO3) hexagonal-shaped microplates were synthesized by a simple and fast microwave–hydrothermal method at 150 °C for 30 min. Cerium nitrate, urea and cetyltrimethylammonium bromide were used as precursors. Ceria (cubic CeO2) rhombus-shape was obtained by a thermal decomposition oxidation process at 500 °C for 1 h using as- synthesized Ce(OH)CO3. The products were characterized by X-ray powder diffraction, field-emission scanning electron microscopy, thermogravimetric analysis and Fourier transformed infrared spectroscopy. The use of microwave–hydrothermal method allowed to obtain cerium compounds at low temperature and shorter time compared to other synthesis methods. 相似文献
939.
Filipe Monteiro-Silva Carla Queirs Andreia Leite María T. Rodríguez María J. Rojo Toms Torroba Rui C. Martins Ana M. G. Silva Maria Rangel 《Molecules (Basel, Switzerland)》2021,26(16)
Functional organic dyes play a key role in many fields, namely in biotechnology and medical diagnosis. Herein, we report two novel 2,3- and 3,4-dihydroxyphenyl substituted rosamines (3 and 4, respectively) that were successfully synthesized through a microwave-assisted protocol. The best reaction yields were obtained for rosamine 4, which also showed the most interesting photophysical properties, specially toward biogenic amines (BAs). Several amines including n- and t-butylamine, cadaverine, and putrescine cause spectral changes of 4, in UV–Vis and fluorescence spectra, which are indicative of their potential application as an effective tool to detect amines in acetonitrile solutions. In the gas phase, the probe response is more expressive for spermine and putrescine. Additionally, we found that methanolic solutions of rosamine 4 and n-butylamine undergo a pink to yellow color change over time, which has been attributed to the formation of a new compound. The latter was isolated and identified as 5 (9−aminopyronin), whose solutions exhibit a remarkable increase in fluorescence intensity together with a shift toward more energetic wavelengths. Other 9-aminopyronins 6a, 6b, 7a, and 7b were obtained from methanolic solutions of 4 with putrescine and cadaverine, demonstrating the potential of this new xanthene entity to react with primary amines. 相似文献
940.
Roseany V. V. Lopes Nuno Pedro D. Loureiro José R. Zamian Pâmela S. Fonseca Júlio L. Macedo Maria L. dos Santos Maria J. A. Sales 《Macromolecular Symposia》2009,286(1):89-94
Although the petrochemical polymers have revolutionized the technological development, the intensive use of these materials have contributed to the global pollution. In this context, researches involving ecofriendliness materials are growing up, as well as, a current interest in developing materials from inexpensive and renewable resources, such as vegetable oils. In this work, is described the synthesis of polymeric materials by thermal polymerization from linseed oil (Linum usitatissimum L.) and passion fruit oil (Passiflora edulis) and their characterization by gas chromatographic (GC), Fourier transform infrared (FTIR) spectroscopy, solubility in organic solvents, thermogravimetry (TG), differential scanning calorimetry (DSC) and Raman spectroscopy. The TG curve shows that those polymeric materials present two stages of decomposition. DSC plots of the vegetable oils showed some endothermic and exothermic transitions which are not present in the DSC curves corresponding to oil-based polymers. The Raman spectra of the polymers indicate declining of absorbance in the region of CC stretching (∼1600 cm−1). This absorption was used to estimate the degree of polymerization (79% and 67.5% for linseed and passion fruit oils, respectively). 相似文献