全文获取类型
收费全文 | 330665篇 |
免费 | 4372篇 |
国内免费 | 1195篇 |
专业分类
化学 | 181523篇 |
晶体学 | 4551篇 |
力学 | 13398篇 |
综合类 | 7篇 |
数学 | 39130篇 |
物理学 | 97623篇 |
出版年
2021年 | 1940篇 |
2020年 | 2315篇 |
2019年 | 2304篇 |
2018年 | 2181篇 |
2017年 | 2094篇 |
2016年 | 4396篇 |
2015年 | 3686篇 |
2014年 | 4984篇 |
2013年 | 14890篇 |
2012年 | 11676篇 |
2011年 | 14379篇 |
2010年 | 8881篇 |
2009年 | 8828篇 |
2008年 | 13221篇 |
2007年 | 13418篇 |
2006年 | 13010篇 |
2005年 | 11892篇 |
2004年 | 10676篇 |
2003年 | 9369篇 |
2002年 | 9178篇 |
2001年 | 10366篇 |
2000年 | 7957篇 |
1999年 | 6346篇 |
1998年 | 5092篇 |
1997年 | 4938篇 |
1996年 | 5016篇 |
1995年 | 4584篇 |
1994年 | 4314篇 |
1993年 | 4147篇 |
1992年 | 4620篇 |
1991年 | 4434篇 |
1990年 | 4159篇 |
1989年 | 3985篇 |
1988年 | 4251篇 |
1987年 | 3888篇 |
1986年 | 3775篇 |
1985年 | 5458篇 |
1984年 | 5534篇 |
1983年 | 4486篇 |
1982年 | 4891篇 |
1981年 | 4931篇 |
1980年 | 4662篇 |
1979年 | 4782篇 |
1978年 | 4822篇 |
1977年 | 4745篇 |
1976年 | 4683篇 |
1975年 | 4602篇 |
1974年 | 4437篇 |
1973年 | 4590篇 |
1972年 | 2616篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
Fundamentals of the direct measurement of sound intensity and practical applications 总被引:1,自引:0,他引:1
Sound intensity is a measure of the magnitude and direction of the flow of sound energy. Developments in sound intensity measurement capabilities in the last quarter century have occurred because of several reasons. The main ones include the derivation of the cross-spectral formulation for sound intensity and developments in digital signal processing. This paper begins with a brief historical introduction of sound intensity measurements. Then elementary theory for sound intensity is presented. A section on sound intensity measurements is then included. The next section of the paper discusses sources of measurement error; the major sources of error are described in some detail. The paper continues with a discussion of the main applications of sound intensity measurements: sound power determination, noise source identification, and transmission loss measurements. The paper concludes with a discussion of ISO and ANSI intensity related standards and relevant references. 相似文献
132.
Pascher W. Den Besten J. H. Caprioli D. Leijtens X. Smit M. van Dijk R. 《Optical and Quantum Electronics》2003,35(4-5):453-464
Based on a rigorous vectorial analysis, a fast travelling-wave Mach–Zehnder modulator is modelled and designed. The cross-section of the semiconductor layer stack and the lossy electrodes are carefully modelled using the method of lines in order to investigate propagation characteristics, velocity and losses. This yields an accurate microwave and optical field distribution to explain the behaviour of the component. In order to enhance the modulation efficiency, design curves are derived and the cross-sectional dimensions for minimum microwave loss are determined. The loss of the optimized modulator agrees very well with small-signal measurements up to 40 GHz and HFSS simulations. The layerstack of the fabricated device is suitable for integration with InP multi-wavelength lasers. 相似文献
133.
2-Formyl glycals undergo rapid condensation with arylhydrazines under solvent-free conditions to give the corresponding optically pure 4-substituted pyrazoles in good yields with high selectivity. The stereochemistry of the products was assigned by various NMR experiments. 相似文献
134.
135.
Mrio J. Edmundo 《Mathematical Logic Quarterly》2005,51(6):639-641
We show that if G is a definably compact, definably connected definable group defined in an arbitrary o‐minimal structure, then G is divisible. Furthermore, if G is defined in an o‐minimal expansion of a field, k ∈ ? and pk : G → G is the definable map given by pk (x ) = xk for all x ∈ G , then we have |(pk )–1(x )| ≥ kr for all x ∈ G , where r > 0 is the maximal dimension of abelian definable subgroups of G . (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
136.
Solid state nuclear track detectors are commonly used for measurements of concentrations of radon gas and/or radon progeny. All these measurements depend critically on the thickness of the removed layer during etching. However, the thickness of removed layer calculated using the etching period does not necessarily provide a sufficiently accurate measure of the thickness. For example, the bulk etch rate depends on the strength of stirring during etching for the LR 115 detector. We propose here to measure the thickness of the removed layer by using energy-dispersive X-ray fluorescence spectrometry. In the present work, a reference silver nitrate pellet is placed beneath the LR 115 detector, and the fluorescence X-ray intensity for silver is then measured. We have found a linear relationship between the X-ray intensity and the thickness of the removed layer for LR 115 detector. This provides a fast method to measure the thickness of removed layer from etching of LR 115 detector. However, this method was found to be inapplicable for the CR-39 detector. Therefore, alternative methods have yet to be explored for the CR-39 detector. 相似文献
137.
We have simultaneously used adsorption isotherm volumetry and Fourier transform infrared spectroscopy in order to take the investigations on amorphous ice structure a step further, especially concerning porosity and annealing-induced modifications. We have studied surface reorganization during annealing and found that the number of surface sites decreases before crystallization, their relative ratios being different for amorphous and crystalline ice. We also present results confirming that ice can have a large specific surface area and nevertheless be non-microporous. 相似文献
138.
J. M. Martínez‐Burgos R. Benavente E. Prez M. L. Cerrada 《Journal of Polymer Science.Polymer Physics》2003,41(11):1244-1255
Several composites were prepared on the basis of an ethylene homopolymer and different copolymers of ethylene and 1‐hexene, synthesized with a metallocene catalyst, as matrices and a content of a 5 wt % of short glass fiber. The effect of the fiber incorporation on the structure and mechanical and viscoelastic behaviors was analyzed for the different samples. The glass fibers induced a slightly higher crystallinity, and the crystallite morphology significantly changed (long spacings and crystal orientation). The incorporation of fibers did not reinforce the different matrices under study at this low content; consequently, the mechanical parameters, such as Young's modulus, yielding stress, and microhardness, were lower in the composites as compared with those values found in the neat polyolefins. The location and apparent activation energies of distinct relaxation processes are also discussed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1244–1255, 2003 相似文献
139.
Gregory S. Constable Alan J. Lesser E. Bryan Coughlin 《Journal of Polymer Science.Polymer Physics》2003,41(12):1323-1333
An in situ ultrasonic spectroscopy technique was used to study the ring‐opening metathesis polymerization of dicyclopentadiene catalyzed by bis(tricyclohexylphosphine)benzylidene ruthenium dichloride. A reaction cell employing a flexible poly(ethylene terephthalate) window for pulse echo ultrasonic spectroscopy was used to monitor the polymerization. The changes in the density, wave speed, acoustic modulus, and attenuation were all simultaneously monitored. In comparison with Fourier transform infrared (FTIR) spectroscopy data, the changes in the density, velocity, and modulus only accurately measured the rate constant for the metathesis of the cyclopentyl unsaturation. The ultrasonic values were within 6% of the values determined by FTIR. The activation energy for metathesis of the cyclopentyl unsaturation was 84 kJ mol?1, following first‐order kinetics. Rate constants for the polymerization of the norbornyl unsaturation could not be determined by ultrasound. The gel point, vitrification, and qualitative information about the reaction rate could be determined from the change in the attenuation. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1323–1333, 2003 相似文献
140.
V. Balek T. Mitsuhashi I.M. Bountseva H. Haneda Z. Malek J. Šubrt 《Journal of Sol-Gel Science and Technology》2003,26(1-3):185-189
The diffusion structural analysis (DSA) was used to characterize microstructure changes of hydrous titania gel films under in situ conditions of heating. TG and DTA were used in order to elucidate the processes controlling the formation of anatase film during heating of hydrous titania gel film. The annealing of porosity and near surface structure defects of the dehydrated titania films was indicated by DSA in the temperature range 255–700°C as the decrease of radon release rate. It was demonstrated that the annealing was enhanced on heating in oxygen in comparison with heating in argon. The DSA experimental results were compared with model curves describing the radon diffusion mobility and the annealing of radon diffusion paths. 相似文献