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21.
Quantitative H–Al distances in acid sites of two zeolites with MFI and IFR framework topology were obtained by numerical simulation of 1H{27Al} rotational echo adiabatic passage double resonance (REAPDOR) experiments. A 27Al offset-dependent data set yields for each resolved 1H NMR line a corresponding nuclear electric quadrupole coupling constant of the neighboring 27Al site. This information is used for analyzing a second data set for on-resonance irradiation, where the dipolar evolution time (number of rotor cycles) was varied, to yield the 1H–27Al dipolar coupling constant. Numerical simulations indicate that the REAPDOR method does not depend significantly on the polar angles, defining the orientation of the electric field gradient tensor of 27Al with respect to the Al–H dipolar vector. In contrast, the transfer of populations in double resonance sequence is sensitive to these angles, and it can be thus used to measure them. 相似文献
22.
Lee Stephen; Harrison Martin C.; Robinson Carol L. 《Teaching Mathematics and its Applications》2007,26(3):111-118
In the past 6 years changes have occurred in GCE A-levels. Inparticular, there have been several major changes in A-levelMathematics courses. As engineering students are usually requiredto have studied A-level Mathematics, or its equivalent, thesechanges have had an effect on their prior mathematical knowledge.Moreover, engineering students traditionally obtained a goodgrounding in mechanics as part of their A-level Mathematicsqualification. However, mechanics, which was once included inthe core syllabus, is now optional. This article investigatesthe current availability and uptake of mechanics modules withinA-level Mathematics courses in schools. Comparisons are drawnbetween these results and results of a survey of schools in2004 and surveys of first year engineering students conductedin 2004 and 2005. It is found that there is a decline in theavailability of mechanics modules and the uptake of more thanone mechanics module has also decreased. The implications ofthese findings for engineering educators are discussed. 相似文献
23.
It can be conjectured that the colored Jones function of a knot can be computed in terms of counting paths on the graph of
a planar projection of a knot. On the combinatorial level, the colored Jones function can be replaced by its weight system.
We give two curious formulas for the weight system of a colored Jones function: one in terms of the permanent of a matrix
associated to a chord diagram, and another in terms of counting paths of intersecting chords.
Electronic supplementary material to this article is available at and is accessible to authorized users.
* S. G. was partially supported by an NSF and by an Israel-US BSF grant.
† M. L. was partly supported by GAUK 158 grant and by the Project LN00A056 of the Czech Ministry of Education. 相似文献
24.
25.
26.
We close a gap in the proof of Theorem 4.1 in our paper “The complexity of counting graph homomorphisms” [Random Structures Algorithms 17 (2000), 260–289]. © 2004 Wiley Periodicals, Inc. Random Struct. Alg., 2004 相似文献
27.
The effects of partial substitution of Mn for Co on the thermoelectric properties of Ca3MnxCo4−xO9 (x=0, 0.03, 0.9), prepared by sol-gel process, were investigated at the temperatures from 380 K down to 5 K. The results indicate that the substitution of Mn for Co results in increase in thermopower at temperatures >∼80 K, and substantial (23-31% at 300 K) decrease in lattice thermal conductivity in the whole temperature range investigated. The temperature behavior of ZT suggests that Ca3MnxCo4−xO9 with light Mn substitution would be a promising candidate for high-temperature thermoelectric applications. 相似文献
28.
Optical characterization of bromo-alkoxyl-substituted copper phthalocyanine derivative thin films 总被引:2,自引:0,他引:2
A series of thin films of copper phthalocyanine derivatives with bromine and alkoxyl substituents [CuPc(OC8H17)4Brm, m=0,1,2,4] were prepared on single-crystal silicon substrates by spin coating. The ellipsometric spectra of the films have been studied on a rotating analyzer–polarizer type of scanning ellipsometer. The optical, dielectric constants and absorption coefficients of the films in 500–800 nm wavelength region were obtained. The results show that the complex refractive index, dielectric constants and absorption coefficient of these thin films are influenced regularly by bromine substituent on conjugated macrocycle. It was found that there are approximately linear relationships between the resonance absorption wavelengths of the films and the average number of bromine atoms substituted on the phthalocyanine ring. 相似文献
29.
Martin Kneser 《Mathematische Semesterberichte》1995,42(2):153-162
Zusammenfassung.
Der Vierscheitelsatz sagt aus, da? die Krümmung einer
geschlossenen,
sich selbst nicht schneidenden, ebenen Kurve stets mindestens zwei
Maxima und zwei Minima besitzt. Er wurde unabh?ngig von Syamadas
Mukhopadhyaya und von Adolf Kneser bewiesen, und seitdem hat es eine
ganze Reihe weiterer Beweise gegeben. In der vorliegenden Note wird der
Satz aus einer elementargeometrischen Aussage über Kreisbogenvielecke
durch Grenzübergang hergeleitet und schlie?lich durch
Abschw?chung der Differenzierbarkeitsvoraussetzungen verallgemeinert.
Eingegangen am 13. Dezember 1994 / Angenommen
am 3. M?rz 1995 相似文献
30.
C. von Borczyskowski F. Cichos J. Martin J. Schuster A. Issac J. Brabandt 《The European physical journal. Special topics》2007,144(1):13-25
Optical spectroscopy in combination with wide field or confocal optical
microscopy enables the investigation of single quantum objects such as
organic molecules, II/VI semiconductor quantum dots and silicon nanocrystals.
They all have fluctuations of luminescence intensities on time scales longer
than μs in common. A comparison reveals that despite the large differences
of the nature of the respective quantum objects, the intensity fluctuations
are related to a slow ionisation process followed
by a trapping of the photoejected charge in the non-conducing environment.
Detailed aspects of the dynamics are controlled by the dielectric properties
of the matrix. 相似文献