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31.
Laser-induced periodic surface structures (LIPSS) were generated on oriented and amorphous thick, as well as on spin-coated
thin, poly-carbonate films by polarized ArF excimer laser light. The influence of the film structure and thickness on the
LIPSS formation was demonstrated. Below a critical thickness of the spin-coated films the line-shaped structures transformed
into droplets. This droplet formation was explained by the laser-induced melting across the whole film thickness and subsequent
de-wetting on the substrate. The thickness of the layer melted by laser illumination was computed by a heat-conduction model.
Very good agreement with the critical thickness for spin-coated films was found. The original polymer film structure influences
the index of refraction of the thin upper layer modified by the laser treatment, as was proven by the dependence of the structure’s
period on the angle of incidence both for ‘s’- and ‘p’-polarized beams. The effect of the original surface roughness – grains in thick films or holes in thin films –
was studied using atomic force microscopy. It was shown that the oblique incidence of ‘s’-polarized beams results in an intensity confinement in the direction of the forward scattering and in asymmetrical interference
pattern formation around these irregularities. A new, two-dimensional grating-like structure was generated on spin-coated
films. These gratings might be used as a special kind of mask.
Received: 10 July 2001 / Accepted: 23 July 2001 / Published online: 30 August 2001 相似文献
32.
On UV.-irradiation in i-octane the α,β-unsaturated ketone 14 is transformed into a mixture of 15 and 16 . 相似文献
33.
The 3D profile surface parameter H
q
and fractal dimension D were tested as indicators of mechanical properties inferred from fracture surfaces of porous solids. High porous hydrated
cement pastes were used as prototypes of porous materials. Both the profile parameter H
q
and the fractal dimension D showed capability to assess compressive strength from the fracture surfaces of hydrated pastes. From a practical point of
view the 3D profile parameter H
q
seems to be more convenient as an indicator of mechanical properties, as its values suffer much less from statistical scatter
than those of fractal dimensions. 相似文献
34.
Dr. Maria Korabik Zuzana Repická Ladislav Martiška Jan Moncol Jozef Švorec Zdeňka Padělková Tadeusz Lis Milan Mazúr Prof. Dr. Dušan Valigura 《无机化学与普通化学杂志》2011,637(2):224-231
Polymeric salicylatocopper(II) complexes of unusual composition [C u(X‐ sal)2( μ‐denia)(H2O)]n [denia = diethylnicotinamide, and X‐sal = 5‐methylsalicylate ( 1 ), 3‐methylsalicylate ( 2 ), 4‐methoxysalicylate ( 3 ), 3,5‐dichlorosalicylate ( 4 ) and 3,5‐dibromosalicylate ( 5 )] were synthesized and characterized. Magnetic measurements were performed in the temperature range 1.8–300 K. The structural unit of all complexes consists of a CuII atom, which is monodentately coordinated by the pair of X‐salicylate anions in trans positions. Water and the diethylnicotinamide ligand occupy the other two basal plane positions of the tetragonal pyramid. The axial positions are occupied by a diethylnicotinamide oxygen atom of neighboring structural units, thus forming a spiral polymeric structure parallel to b axis. Magnetic measurements showed that all complexes 1 – 5 exhibit a susceptibility maximum at about 6–8 K. The obtained data fit to Bleaney–Bowers equation gave singlet‐triplet energy gaps 2J = –8.60 cm–1 for 1 , 2J = –6.57 cm–1 for 2 , 2J = –8.57 cm–1 for 3 , 2J = –6.82 cm–1 for 4 , and 2J = –6.45 cm–1 for 5 . The supramolecular structure based on hydrogen bonds [described by supramolecular synthons R22(10) and R22(12)] is the pathway for antiferromagnetic interactions of the magnetically coupled pairs of copper atoms of neighboring chains within the 2D supramolecular layers. The results of the magnetic measurements suggest involvement of the COO groups in the magnetic interaction pathway for all five complexes. 相似文献
35.
36.
Rose-Munch F Marti A Cetiner D Tranchier JP Rose E 《Dalton transactions (Cambridge, England : 2003)》2011,40(7):1567-1575
First Suzuki-Miyaura coupling reactions applied to (η(5)-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η(5)-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η(6)-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by X-ray diffraction study. 相似文献
37.
38.
A method is proposed for the automated generation of potential energy surfaces in high dimensions. It combines the existing algorithm for the definition of new energy data points, based on the interpolating moving least-squares algorithm with a simulated annealing procedure. This method is then studied in a haptic quantum chemistry environment that requires a fast evaluation of gradients on a potential energy surface with automatic improvement of its accuracy. As an example we investigate the nitrogen binding pathway in the Schrock dinitrogen fixation complex with this set-up. 相似文献
39.
40.
Wijnands F. Pendry J. B. Garcia-Vidal F. J. Bell P. M. Roberts P. J. Moreno L. Marti´n 《Optical and Quantum Electronics》1997,29(2):199-216
We present a new formalism for calculating the Green's function for Maxwell's equations. As our aim is to apply our formalism
to light scattering at surfaces of arbitrary materials, we derive the Green's function in a surface representation. The only
requirement on the material is that it should have periodicity parallel to the surface. We calculate this Green's function
for light of a specific frequency and a specific incident direction and distance with respect to the surface. The material
properties entering the Green's function are the reflection coefficients for plane waves at the surface. Using the close relationship
between the Green's function and the density of states (DOS), we apply our method to calculate the spontaneous emission rate
as a function of the distance to a material surface. The spontaneous emission rate can be calculated using Fermi's Golden
Rule, which can be expressed in terms of the DOS of the optical modes available to the emitted photon. We present calculations
for a finite slab of cylindrical rods, embedded in air on a square lattice. It is shown that the enhancement or suppression
of spontaneous emission strongly depends on the frequency of the light.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献