全文获取类型
收费全文 | 9710篇 |
免费 | 283篇 |
国内免费 | 6篇 |
专业分类
化学 | 6196篇 |
晶体学 | 168篇 |
力学 | 179篇 |
数学 | 1327篇 |
物理学 | 2129篇 |
出版年
2023年 | 49篇 |
2022年 | 207篇 |
2021年 | 280篇 |
2020年 | 159篇 |
2019年 | 198篇 |
2018年 | 186篇 |
2017年 | 174篇 |
2016年 | 343篇 |
2015年 | 261篇 |
2014年 | 362篇 |
2013年 | 738篇 |
2012年 | 509篇 |
2011年 | 610篇 |
2010年 | 433篇 |
2009年 | 407篇 |
2008年 | 507篇 |
2007年 | 480篇 |
2006年 | 421篇 |
2005年 | 353篇 |
2004年 | 315篇 |
2003年 | 304篇 |
2002年 | 226篇 |
2001年 | 162篇 |
2000年 | 141篇 |
1999年 | 110篇 |
1998年 | 116篇 |
1997年 | 83篇 |
1996年 | 89篇 |
1995年 | 112篇 |
1994年 | 63篇 |
1993年 | 46篇 |
1992年 | 74篇 |
1991年 | 52篇 |
1990年 | 71篇 |
1989年 | 60篇 |
1988年 | 76篇 |
1987年 | 56篇 |
1986年 | 67篇 |
1985年 | 102篇 |
1984年 | 109篇 |
1983年 | 77篇 |
1982年 | 66篇 |
1981年 | 71篇 |
1980年 | 84篇 |
1979年 | 60篇 |
1978年 | 65篇 |
1977年 | 69篇 |
1976年 | 66篇 |
1975年 | 51篇 |
1974年 | 48篇 |
排序方式: 共有9999条查询结果,搜索用时 62 毫秒
61.
Zbigniew Peradzyński Bogdan Kazmierczak 《Archive of Applied Mechanics (Ingenieur Archiv)》2005,74(11-12):827-833
The influence of mechano-chemical coupling on calcium concentration waves is considered. The propagation of calcium waves is described by a reaction–diffusion equation with the reaction term dependent on the mechanical stress responsible for the release of calcium. Similarly the balance of mechanical forces is influenced by the calcium concentration through the so-called traction force. 相似文献
62.
Dealing with infinite iterated function systems we introduce and develop the ergodic theory of Hölder systems of functions similarly as in [HU] and [HMU]. In the context of conformal infinite iterated function systems we prove the volume lemma for the Hausdorff dimension of the projection onto the limit set of a shift invariant measure. This can be considered as a Billingsley type result. Our cenral goal is to demonstrate the appearance of the "singularity-absolute continuity" dichotomy for equilibrium states of Hölder systems of functions which has been observed in [PUZ,I] and [PUZ,II] (see also [DU1] and [DU2]) in the setting of rational functions of the Riemann sphere. 相似文献
63.
64.
David Ribera Marta Giamberini Angels Serra Ana Mantecn 《Journal of polymer science. Part A, Polymer chemistry》2006,44(21):6270-6286
We reacted various dimeric, liquid‐crystalline epoxy–imine monomers, differing in the length of the central aliphatic spacer or the dipolar moments, with heptanedioic acid. The resulting systems showed a liquid‐crystalline phase in some cases, depending on the dimer and on the reaction conditions. The systems were characterized with respect to their mesomorphic properties and then were submitted to dynamic mechanical thermal analysis in both fixed‐frequency and frequency‐sweep modes in the shear sandwich configuration. The arrangement in the liquid‐crystalline phase seemed to be mainly affected both by the polarization of the mesogen and by the reaction temperature, which favored the liquid‐crystalline arrangement when it was lying in the range of stability of the dimer mesophase. In agreement with other recent literature data, dynamic mechanical thermal analysis results suggested that the presence of the mesogen directly incorporated into the main chain increased the lifetimes of the elastic modes both in the isotropic phase and in the liquid‐crystalline phase with respect to side‐chain liquid‐crystalline elastomers and that the time–temperature superposition principle did not hold through the liquid‐crystalline‐to‐isotropic transition. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44:6270–6286, 2006 相似文献
65.
Lourdes Callau Marta Giamberini Jos Antonio Reina Ana Mantecn 《Journal of polymer science. Part A, Polymer chemistry》2006,44(6):1877-1889
The synthesis of two vinyl‐terminated side‐chain liquid‐crystalline polyethers containing benzylideneaniline moieties as mesogenic cores was approached in two different ways: by chemically modifying poly(epichlorohydrin) with suitable mesogenic acids or by polymerizing analogous glycidyl ester or glycidyl ether derivatives. In all the conditions tested, the first approach led to materials in which the imine group was hydrolyzed. The second approach led to the desired polymers PG2a and PG2b , but only from the glycidyl ether derivatives and when the initiator was the system that combined polyiminophosphazene base t‐Bu‐P4 and 3,5‐di‐t‐butylphenol. These polymers were chemically characterized by IR and 1H and 13C NMR spectroscopies. The estimated degrees of polymerization ranged from 30 to 36. The liquid crystalline behavior of the synthesized polymers was studied by differential scanning calorimetry, polarized optical microscopy (POM) and X‐ray diffraction. Both polymers behave like liquid crystals and exhibited a single mesophase, which was recognized as a smectic C mesophase, probably with a bilayer arrangement, i.e., a smectic C2 mesophase. The crosslinking of both polymers was performed with dicumyl peroxide as initiator, which led to liquid crystalline thermosets. POM and X‐ray diffraction confirmed that the mesophase organization mantained on the crosslinked materials. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1877–1889, 2006 相似文献
66.
X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) have been used to investigate the effect of reactive ion etching (RIE) on poly(methylhydrogensiloxane-co-dimethylsiloxane) surface in fluorine-based plasmas. Polysiloxane layers supported on the standard silicon wafers were etched using SF6 + O2 or CF4 + O2 plasmas. SEM studies show that the polysiloxane morphology depends on plasma chemical composition strongly. Presence of a columnar layer likely covered with a fluorine rich compound was found on the elastomer surface after the CF4 + O2 plasma exposure. After the SF6 + O2 or CF4 + O2 plasma treatment the polysiloxane surface enriches with fluorine or with fluorine and aluminum, respectively. Different morphologies and surface chemical compositions of the silicone elastomer etched in both plasmas indicate different etching mechanisms. 相似文献
67.
We describe phenomena occurring just before a saddle-node bifurcation for one-parameter families of interval maps. In particular, as a parameter approaches the bifurcation value, attracting periodic orbits of periodsk, k+1,k+2,k+3,... can appear. We make a detailed study of a family of cusp-shaped maps, where this phenomenon occurs in a pure form. 相似文献
68.
Summary In this paper we analize the reversibility of the diffusion property for the solution of certain infinite-dimensional systems of stochastic differential equations. Necessary and sufficient conditions ensuring this reversibility are given. The proofs use the techniques of the stochastic calculus of variations.This work was partly done when the first author was visiting the Centre de Recerca Matemàtica at Barcelona 相似文献
69.
Dr. A. Kaczyński Dr. S. J. Matysiak 《Archive of Applied Mechanics (Ingenieur Archiv)》1988,58(2):137-147
Summary This paper deals with the two-dimensional static punch problems in the presence of friction for a periodically layered half-space. Within the framework of the homogenized model of linear elasticity with microlocal parameters [8–11] the exact solutions of the considered problems are obtained. The case of the indentation of the composite body by a rigid rectangular punch has been discussed in detail.
Ebene Kontaktprobleme für ein periodisches elastisches Zweischichten-Komposit
Übersicht In dieser Arbeit wird das zweidimensionale statische Stempelproblem mit Reibung für einen periodisch geschichteten Halbraum betrachtet. Im Rahmen eines Homogenisierungsmodells der linearen Elastizitätstheorie mit mikropolaren Parametern werden die exakten Lösungen der betrachteten Probleme gewonnen. Im Detail wird das Eindringen eines rechteckigen starren Stempels behandelt.相似文献
70.
Margaret C. Etter Zofia Urbańczyk-Lipkowska Touradj M. Ameli Thomas W. Panunto 《Journal of chemical crystallography》1988,18(5):491-507
The crystal structures, solid-state infrared patterns, and thermal properties of two polymorphs of 4-nitrosalicylanilide are presented. In both polymorphs, intramolecular hydrogen bonds are found between the phenol oxygen and the amide proton, and intermolecular hydrogen bonds are found between the amide carbonyl oxygen and the phenol proton. These hydrogen bond patterns are compared to those found in other known salicylamide derivatives and an analysis is given of the factors contributing to preferences for intra- or intermolecular hydrogen bonds in these structures. Crystal data: polymorph, orthorhombic,Pbca,a=11.003(4),b=27.959(7),c=7.622(5) Å,Z=4,V=2345(3) Å3, andR=0.038 (1351 reflections); polymorph, monoclinic,P21/a,a=28.36(1),b=11.64(1),c=7.293(8) Å,=90.68(6)°,Z=8,V=2408 Å3, andR=0.043 (2425 reflections). 相似文献