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21.
22.
Marta Knap 《Talanta》2007,71(1):406-410
An on-line preconcentration procedure for the determination of manganese using flow-injection approach with flame atomic absorption spectrometry as a detection method is described. The proposed method is based on the complexation between Mn(II) and 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin (TCPP). Two approaches were investigated for enrichment of manganese; the formation of Mn-TCPP complex in a solution followed by its retention on a sorbent and the sorption of manganese ions onto the TCPP-modified resin. The best results was obtained for the first approach when 10−5 M reagent was on-line mixed with an aqueous sample solution and passed through the microcolumn packed with anion-exchange resin Amberlite IRA-904 for 5 min. The sorbed complexes were then eluted with 0.5 ml of 2 M HNO3. A good precision (2.2-3.1% R.S.D. for 50 μg l−1 manganese) and the enrichment factor of 30 were obtained with the detection limit of 12 μg l−1 for 5 min loading time. The interference of anions and cations has been studied to optimize the conditions and the method was applied for determination of manganese in natural water samples. The results obtained by FI-FAAS and ETAAS (as a reference method) were not statistically different for a significance level of 0.05. 相似文献
23.
Aringhieri Roberto Bigharaz Sara Duma Davide Guastalla Alberto 《Central European Journal of Operations Research》2022,30(1):189-211
Central European Journal of Operations Research - Disaster management generally includes the post-disaster stage, which consists of the actions taken in response to the disaster damages. These... 相似文献
24.
Hereditarily finite sets and hypersets are characterized both as algorithmic data structures and by means of a first-order axiomatization which, despite being rather weak, suffices to make the following two problems decidable:
- (1) Establishing whether a conjunction r of formulae of the form: ? y1 ?? ym((y1?W1& ?&ym ?Wm) ←q), with q quantifier-free and involving only the relators =, ? and propositional connectives, and each yi distinct from all wj's, is satisfiable.
- (2) Establishing whether a formula of the form ? y q, q quantifier-free, is satisfiable.
25.
We study the topological structure of all 3-manifolds obtained by surgery along principal fibers of a closed orientable
-manifold. As a consequence, we give alternative proofs of some classical results due to W. Heil and L. Moser. Moreover, we completely specify the Seifert invariants for the considered manifolds. Finally we classify the manifolds obtained by surgery along certain Seifert links and determine geometric presentations of their fundamental groups.Work performed under the auspices of C.N.R. (National Research Council) of Italy and partially supported by Ministero della Ricerca Scientifica e Tecnologica within the projects Geometria Reale e Complessa and Topologia. 相似文献
26.
Let {
s,t
,(s,t
+
2
} be a white noise on
+
2
. We consider the hyperbolic stochastic partial differential equation {ie863-3} The purpose of this paper is to study the law of the solution to this equation. We analyze the existence and smoothness of the density using the tools of Malliavin Calculus. Finally we prove a large deviation principle on the space of continuous functions, for the family of probabilities obtained by perturbation of the noise in the equation.This work has been partially supported by the grant of the DGICYT No. PB 930052 and the EU Science project CT 910459. 相似文献
27.
Krull-Schmidt fails for serial modules 总被引:1,自引:0,他引:1
Alberto Facchini 《Transactions of the American Mathematical Society》1996,348(11):4561-4575
We answer a question posed by Warfield in 1975: the Krull-Schmidt Theorem does not hold for serial modules, as we show via an example. Nevertheless we prove a weak form of the Krull-Schmidt Theorem for serial modules (Theorem 1.9). And we show that the Grothendieck group of the class of serial modules of finite Goldie dimension over a fixed ring is a free abelian group.
28.
We introduce a new Monte Carlo algorithm for the self-avoiding walk (SAW), and show that it is particularly efficient in the critical region (long chains). We also introduce new and more efficient statistical techniques. We employ these methods to extract numerical estimates for the critical parameters of the SAW on the square lattice. We find=2.63820 ± 0.00004 ± 0.00030=1.352 ± 0.006 ± 0.025v=0.7590 ± 0.0062 ± 0.0042 where the first error bar represents systematic error due to corrections to scaling (subjective 95% confidence limits) and the second bar represents statistical error (classical 95% confidence limits). These results are based on SAWs of average length 166, using 340 hours CPU time on a CDC Cyber 170–730. We compare our results to previous work and indicate some directions for future research. 相似文献
29.
The interpretation of the infrared active fundamentals of TCNQ and chloranil monovalent anions is given for the first time. The rationalization of the infrared spectra was made possible by the recently achieved vibrational assignment of the corresponding neutral molecules and is mainly based on a set of judicious adjustments of their empirical valence force fields. 相似文献
30.
Reductive alkylatin of methylvinylketone has been accomplished by hydrogen abstraction from cyclic ethers with the redox couple: t-butyl hydroperoxide-titanous chloride. A redox radical mechanism is proposed and the selectivity of the hydrogen abstraction by t-butoxy radicals and reduction of α-ketoalkyl radical by titanous ions is discussed. 相似文献