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131.
Using the time differential perturbed angular correlation technique, the hyperfine interactions as titanium sites in ZnTiF6·6H2O and its decomposition products were determined between room temperature (300 K) and 1273 K. The different steps in the decomposition pattern were identified and a simple model is given for it. 相似文献
132.
R García-Flores X Z Wang T F Burgess 《The Journal of the Operational Research Society》2003,54(4):350-361
A project to improve inventory management in a small UK chemical company is described. A research group comprising university academics and company managers for logistics and information technology examined current practices and analysed a database of historical records of business operations of the company. Based on the analysis, a scheme to categorise stock and set ordering policies to optimise inventory costs was developed. Some comments are made on process issues and the learning that took place. 相似文献
133.
Esperanza Salfrn Carlos Seoaneb Margarita Surez Yamila Verdecia Amaury Alvarez Estael Ochoa Roberto Martínez‐Alvarez Nazario Martín 《Journal of heterocyclic chemistry》2004,41(4):509-516
Novel 4‐amino‐6‐aryl‐2‐phenylpyrimidine‐5‐carbonitriles have been prepared in one step procedure from the readily available 4‐aryl‐2‐amino‐3‐cyano‐5,6,7,8‐tetrahydro‐7,7‐dimethyl‐5‐oxo‐4H‐benzopyrans. The mass spectroscopy study under EI conditions shows molecular peaks with high intensity corresponding to the loss of benzonitrile from the C2 position of the pyrimidine ring. Semiempirical (AMI and PM3) and ab initio HF/6–31G* calculations reveal a favored distorted geometry where the three rings are not in the same plane. 相似文献
134.
Yi Liu David D. Díaz Adrian A. Accurso K. Barry Sharpless Valery V. Fokin M. G. Finn 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5182-5189
1,2,3‐Triazole‐based polymers generated from the Cu(I)‐catalyzed cycloaddition between multivalent azides and acetylenes are effective adhesive materials for metal surfaces. The adhesive capacities of candidate mixtures of azide and alkyne components were measured by a modified peel test, using a customized adhesive tester. A particularly effective tetravalent alkyne and trivalent azide combination was identified, giving exceptional strength that matches or exceeds the best commercial formulations. The addition of Cu catalyst was found to be important for the synthesis of stronger adhesive polymers when cured at room temperature. Heating also accelerated curing rates, but the maximum adhesive strengths achieved at both room temperature and high temperature were the same, suggesting that crosslinking reaches the same advanced point in all cases. Polytriazoles also form adhesives to aluminum, but copper is bound more effectively, presumably because active Cu(I) ions may be leached from the surface to promote crosslinking and adhesion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5182–5189, 2007 相似文献
135.
Testing goodness of fit for the distribution of errors in multivariate linear models 总被引:2,自引:0,他引:2
M.D. Jimnez Gamero J. Muoz García R. Pino Mejías 《Journal of multivariate analysis》2005,95(2):301-322
In this paper, to test goodness of fit to any fixed distribution of errors in multivariate linear models, we consider a weighted integral of the squared modulus of the difference between the empirical characteristic function of the residuals and the characteristic function under the null hypothesis. We study the limiting behaviour of this test statistic under the null hypothesis and under alternatives. In the asymptotics, the rank of the design matrix is allowed to grow with the sample size. 相似文献
136.
František Toman Ludvík Beneš 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(3-4):231-236
Differential molar adsorption enthalpies (DMAE) were determined by gas chromatographic measurements of specific retention
volume of vapors on the surface of two forms of Mg–Al hydrotalcite. A linear dependence of the DMAE on the number of the carbon
atoms in hydrocarbons was observed for both form of hydrotalcite. The dependence of the differential molar adsorption enthalpies
on the number of chlorine atoms in organic molecules is discussed. A linear dependence of DMAE on the molecular weight of
chloroderivatives of methane and ethylene on the basic form in an order monochloromethane < dichloromethane < trichloromethane
or vinylidene chloride < 1,1-dichloroethylene < trichloroethylene was found. 相似文献
137.
138.
J. A. Otero H. Cálas R. Rodríguez-Ramos G. A. Maugin G. Monsiváis R. Pérez-Alvarez 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2004,55(3):519-533
The transfer matrix and global matrix techniques are
used in the analysis of diffraction of transverse horizontal waves
in piezoelectric superlattices. The system is composed of a set of
different piezoelectric layers with quasiperiodic structure
according to the Fibonacci sequence. The diffraction spectrum of
different configurations of piezoelectric Fibonacci structures is
studied. Numerical results for the diffraction spectrum for the
piezoelectric Fibonacci superlattice are obtained and a comparison
between the results of the transfer and global matrix methods is
given, exhibiting the advantage of the latter. 相似文献
139.
If a and b are trace-class operators, and if u is a partial isometry, then , where ∥⋅∥1 denotes the norm in the trace class. The present paper characterises the cases of equality in this Young inequality, and
the characterisation is examined in the context of both the operator and the Hilbert–Schmidt forms of Young's inequality.
Received: 20 December 2001 / Revised version: 11 July 2002 / Published online: 10 February 2003
Mathematics Subject Classification (2000): 47A63, 15A60 相似文献
140.
Bruzón M. S. Gandarias M. L. Muriel C. Ramírez J. Saez S. Romero F. R. 《Theoretical and Mathematical Physics》2003,137(1):1367-1377
We use the classical and nonclassical methods to obtain symmetry reductions and exact solutions of the (2+1)-dimensional integrable Calogero–Bogoyavlenskii–Schiff equation. Although this (2+1)-dimensional equation arises in a nonlocal form, it can be written as a system of differential equations and, in potential form, as a fourth-order partial differential equation. The classical and nonclassical methods yield some exact solutions of the (2+1)-dimensional equation that involve several arbitrary functions and hence exhibit a rich variety of qualitative behavior. 相似文献