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231.
F. Santos de Souza A. P. Gomes Barreto R. O. Macêdo 《Journal of Thermal Analysis and Calorimetry》2001,64(2):739-743
The present work proposes evaluation of the gelatinization processes of starch by means of DSC coupled with a photovisual
system. The use of DSC, TG and DTA for a fast and efficient evaluation of the starch is suggested. The DSC curves of starch
gels with water contents of 20, 30, 40 and 50% (mass/v) exhibited different phase transitions, corresponding to the gelatinization
processes at the different water contents for the different lots. The DSC-photovisual system confirmed calorimetric behaviour
differences between the starch lots studied.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
232.
Macêdo R. O. Barbosa-Filho J. M. da Costa E. M. de Souza A. G. 《Journal of Thermal Analysis and Calorimetry》1999,56(3):1353-1357
The terpenoids acetyl sitosterol, lupeol, acetyl diosgenin and stigmasterol were studied. Comparison of the thermogravimetric
curves and the activation energies of the terpenoids suggested the following sequence of thermal stability: acetyl sitosterol
< acetyl diosgenin < lupeol < stigmasterol. The DSC curves allowed determination of the melting points and the degrees of
purity. Comparison of the TG and DSC curves revealed the presence of phase transitions without mass loss that were attributed
to rearrangements in the terpenoid molecules.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
233.
João Marcos do Ó Everaldo Medeiros 《Journal of Mathematical Analysis and Applications》2008,342(1):432-445
This paper deals with a semilinear Schrödinger equation whose nonlinear term involves a positive parameter λ and a real function f(u) which satisfies a superlinear growth condition just in a neighborhood of zero. By proving an a priori estimate (for a suitable class of solutions) we are able to avoid further restrictions on the behavior of f(u) at infinity in order to prove, for λ sufficiently large, the existence of one-sign and sign-changing solutions. Minimax methods are employed to establish this result. 相似文献
234.
235.
We characterize active redundancy through compensator transform and use the reverse rule of order 2 (RR2) property between compensator processes to investigate the problem of where to allocate a spare in a k-out-of-n:F system of dependent components through active redundancy. 相似文献
236.
A two-dimensional (in-plane) numerical model for surface waves propagation based on the non-linear dispersive wave approach described by Boussinesq-type equations, which provide an attractive theory for predicting the depth-averaged velocity field resulting from that wave-type propagation in shallow water, is presented. The numerical solution of the corresponding partial differential equations by finite-difference methods has been the subject of several scientific works. In the present work we propose a new approach to the problem: the spatial discretization of the system composed by the Boussinesq equations is made by a finite element method, making use of the weighted residual technique for the solution approach within each element. The model is validated by comparing numerical results with theoretical solutions and with results obtained experimentally. 相似文献
237.
R F B Serpa E F O de Jesus M J Anjos L F de Oliveira L A Marins M G T do Carmo J D Corrêa Junior M S Rocha R T Lopes A M B Martinez 《Analytical sciences》2008,24(7):839-842
Knowledge about the spatial distribution and the local concentration of trace elements in tissues is of great importance, since trace elements are involved in many biological functions of living organisms. However, there are few methods available to measure the spatial (two (three)-dimensional) elemental distribution in animal brain. X-ray microfluorescence with synchrotron radiation is a multielemental mapping technique, which was used in this work to determine the topographic of iron, zinc and copper in coronal sections of female Wistar rats of different ages. Young (14 days old) and middle-aged (20 months old) rats (n = 8) were analyzed. The measurements were carried out at the XRF beam line at the Synchrotron Light National Laboratory (Campinas, Brazil). Two-dimensional scanning was performed in order to study the tendency of elemental concentration variation. The acquisition time for each pixel was 10 s/step and the step size was 300 microm/step in both directions. It was observed that the iron distribution was more conspicuous in the cortical area, thalamus and bellow the thalamus. On the other hand, the zinc distribution was more pronounced in the hippocampus. The iron, copper and zinc levels increased with advancing age. Therefore, this study reinforces the idea that these elements are involved in the chemical mechanisms of the brain that induce some neurological diseases, since they are also present in high levels in specific areas of the brain, such as the hippocampus and the substantia nigra of patients with these disorders. 相似文献
238.
Angel A. Recio Despaigne Jeferson G. da Silva Ana Cerúlia M. do Carmo Flavio Sives Oscar E. Piro Eduardo E. Castellano Heloisa Beraldo 《Polyhedron》2009,28(17):3797-3803
In the present work 2-formylpyridine-para-chloro-phenyl hydrazone (H2FopClPh) and 2-formylpyridine-para-nitro-phenyl hydrazone (H2FopNO2Ph) were obtained, as well as their copper(II) and zinc(II) complexes [Cu(H2FopClPh)Cl2] (1), [Cu(2FopNO2Ph)Cl] (2), [Zn(H2FopClPh)Cl2] (3) and [Zn(H2FopNO2Ph)Cl2] (4). Upon re-crystallization in DMSO:acetone conversion of 2 into [Cu(2FopNO2Ph)Cl(DMSO)] (2a) and of 4 into [Zn(2FopNO2Ph)Cl(DMSO)] (4a) occurred. The crystal structures of 1, 2a, 3 and 4a were determined. 相似文献
239.
D.J. Rogers F. Hosseini Teherani A. Largeteau G. Demazeau C. Moisson D. Turover J. Nause G. Garry R. Kling T. Gruber A. Waag F. Jomard P. Galtier A. Lusson T. Monteiro M.J. Soares A. Neves M.C. Carmo M. Peres G. Lerondel C. Hubert 《Applied Physics A: Materials Science & Processing》2007,88(1):49-56
2 cm diameter hydrothermal ZnO crystals were grown and then made into substrates using both mechanical and chemical-mechanical polishing (CMP). CMP polishing showed superior results with an (0002) Ω scan full width half maximum (FWHM) of 67 arcsec and an root mean square (RMS) roughness of 2 Å. In comparison, commercial melt-grown substrates exhibited broader X-ray diffraction (XRD) linewidths with evidence of sub-surface crystal damage due to polishing, including a downward shift of c-lattice parameter. Secondary ion mass spectroscopy revealed strong Li, Fe, Co, Al and Si contamination in the hydrothermal crystals as opposed to the melt-grown substrates, for which glow discharge mass spectroscopy studies had reported high levels of Pb, Fe, Cd and Si. Low temperature photoluminescence (PL) studies indicated that the hydrothermal crystal had high defect and/or impurity concentrations compared with the melt-grown substrate. The dominant bound exciton for the melt-grown substrate was indexed to Al. ZnO films were grown using pulsed laser deposition. The melt-grown substrates gave superior results with XRD (0002) Ω and 2θ/Ω WHM of 124 and 34 arcsec, respectively. Atomic force microscope measurements indicated a low RMS roughness (1.9 nm) as confirmed by fringes in the XRD 2θ/Ω scan. It was suggested that the improvement in XRD response relative to the substrate might be due to “healing” of sub-surface polishing damage due to the elevated Ts used for the growth. Indeed the c-lattice parameter for the homoepitaxial layer on the melt-grown substrate had become that which would be expected for strain-free ZnO. Furthermore, the stability of the PL peak positions relative to bulk ZnO, confirmed that the films appear practically strain free. 相似文献
240.
A simple and reliable FIA-potentiometric system for rapid assays of chloride in certain food samples is described and evaluated. The system is constituted by an aquarium air pump to propel the carrier solution, a manually operated injector, a homemade dialysis flow cell, a solid-state chloride detector (Ag/AgCl), a reference electrode and a multimeter connected to a microcomputer for data acquisition. The dialysis unit enables direct analysis of liquid food samples without any other previous treatment. The principal novelties are the precision (R.S.D. of 1.2% for whole milk) and rapidity (90 determinations/h) of FIA measurements near and below the lower end of the linear (Nernstian) response region of the chloride ion-selective electrode (ISE), with an estimated detection limit (3 s) of 0.4 mg L−1 Cl− in the sample injected in donor stream. Data of peak potential versus sample chloride concentration (donor stream) was accurately fitted with a quadratic polynomial over the range between 4 and 1000 mg L−1 (r2 = 0.9999) and used as a calibration curve. The method was applied to the determination of chloride in milk and in coconut water samples. The validation of the results was done by comparison with a NIST reference material (milk) or by capillary electrophoresis (coconut water). For all analysis, no significant difference at a 95% confidence level was observed. 相似文献