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Pablo Wessig Philipp Wettstein Bernd Giese Markus Neuburger Margaretha Zehnder 《Helvetica chimica acta》1994,77(3):829-837
The chiral N-(2-benzoylethyl)-N-tosylglycinamides 1a-c were prepared from the C2-symmetric pyrrolidines 5a-c . Irradiation of these ketones 1a-c gave cis-3-hydroxyprolinamides 10-12 in moderate to good yields (Scheme 3). The de of the photocyclizations depended on the size of the substituents in positions C(2) and C(5) of the chiral pyrrolidine auxiliaries. In addition, the de varied with the reaction temperature, allowing the determination of activation-parameter differences. The structure of products 10-12 were established by NMR and X-ray analyses. 相似文献
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Reinmöller M Ulbrich A Ikari T Preiss J Höfft O Endres F Krischok S Beenken WJ 《Physical chemistry chemical physics : PCCP》2011,13(43):19526-19533
We have recently measured core level and valence band XPS, UPS, and MIES spectra of two room temperature ionic liquids composed of bis(trifluoromethylsulfonyl)imide anions ([Tf(2)N](-)) and either 1-ethyl-3-methyl-imidazolium ([EMIm](+)) or 1-octyl-3-methyl-imidazolium cations ([OMIm](+)). [T. Ikari, A. Keppler, M. Reinm?ller, W. J. D. Beenken, S. Krischok, M. Marschewski, W. Maus-Friedrichs, O. H?fft and F. Endres, e-J. Surf. Sci. Nanotechnol., 2010, 8, 241.] In the present work we analyze these spectra by means of partial density of states (pDOS) as calculated from a single ion pair of the respective ionic liquid using density functional theory (DFT). Subsequently we reconstruct the XPS and UPS spectra by considering photoemission cross sections and analyze the MIES spectra by pDOS, which provides us decisive hints to the ionic liquid surface structure. 相似文献
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Beckers H Esser S Metzroth T Behnke M Willner H Gauss J Hahn J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(3):832-844
Sulfenic acid (HSOH, 1 ) has been synthesized in the gas‐phase by low‐pressure high‐temperature (1150 °C) pyrolysis of di‐tert‐butyl sulfoxide (tBu2SO, 2 ) and characterized by means of matrix isolation and gas‐phase IR spectroscopy. High‐level coupled‐cluster (CC) calculations (CCSD(T)/cc‐pVTZ and CCSD(T)/cc‐pVQZ) support the first identification of the gas‐phase IR spectrum of 1 and enable its spectral characterization. Five of the six vibrational fundamentals of matrix‐isolated 1 have been assigned, and its rotational‐resolved gas‐phase IR spectrum provides additional information on the O–H and S–H stretching fundamentals. Investigations of the pyrolysis reaction by mass spectrometry, matrix isolation, and gas‐phase FT‐IR spectroscopy reveal that, up to 500 °C, 2 decomposes selectively into tert‐butylsulfenic acid, (tBuSOH, 3 ), and 2‐methylpropene. The formation of the isomeric sulfoxide (tBu(H)SO, 3 a ) has been excluded. Transient 3 has been characterized by a comprehensive matrix and gas‐phase vibrational IR study guided by the predicted vibrational spectrum calculated at the density functional theory (DFT) level (B3LYP/6‐311+G(2d,p)). At higher temperatures, the intramolecular decomposition of 3 , monitored by matrix IR spectroscopy, yields short‐lived 1 along with 2‐methylpropene, but also H2O, and most probably sulfur atoms. In addition, HSSOH ( 6 ), H2, and S2O are found among the final pyrolysis products observed at 1150 °C in the gas phase owing to competing intra‐ and intermolecular decomposition routes of 3 . The decomposition routes of the starting compound 2 and of the primary intermediate 3 are discussed on the basis of experimental results and a computational study performed at the B3LYP/6‐311G* and second‐order Møller–Plesset (MP2/6‐311G* and RI‐MP2/QZVPP) levels of theory. 相似文献
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The mechanism of biological dinitrogen reduction is still unsolved, and the structure of the biological reaction center, the FeMo cofactor with its seven iron atoms bridged by sulfur atoms, is too complicated for direct attack by current sophisticated quantum chemical methods. Therefore, iron-sulfur complexes with biologically compatible ligands are utilized as models for studying particular features of the reduction process: coordination energetics, thermodynamic stability of intermediates, relative stability of isomers of N2H2, end-on versus side-on binding of N2, and the role of states of different multiplicity at a single iron center. From the thermodynamical point of view, the crucial steps are dinitrogen binding and reduction to diazene, while especially the reduction of hydrazine to ammonia is not affected by the transition metal complex, because the complex-free reduction reaction is equally favored. Moreover, the abstraction of coordinated ammonia can be easily achieved and the complex is recovered for the next reduction cycle. Our results are discussed in the light of studies on various model systems in order to identify common features and to arrive at conclusions which are of importance for the biological mechanism. 相似文献