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Boris‐Marko Kukovec Zora Popovi Gordana Pavlovi 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(9):m389-m391
In the title compound, [Cd(C7H6NO2)2]n, the CdII ion has a distorted octahedral geometry. The 6‐methylpyridine‐2‐carboxylate anions are perpendicular to one another and act as bidentate and bridging ligands. Two carboxylate O atoms bridge the CdII ions, forming centrosymmetric dinuclear units. These units are further connected via carboxylate O atoms into a one‐dimensional polymeric chain which extends in the [100] direction. 相似文献
24.
Jan Andres Karel Pastor Pavla Šnyrychová 《Journal of Fixed Point Theory and Applications》2007,2(1):153-170
A multivalued version of Sharkovskiĭ’s theorem is formulated for M-maps on linear continua and, more generally, for triangular M-maps on a Cartesian product of linear continua. This improves the main result of [AP1] in the sense that our multivalued
analogue holds with at most two exceptions. A further specification requires some additional restrictions. For instance, 3-
orbits of m-maps imply the existence of k-orbits for all
k ? \mathbbNk \in {\mathbb{N}}
, except possibly for
k ?k \in
{4, 6}. It is also shown that, on every connected linearly ordered topological space, an M-map with orbits of all periods can always be constructed. This demonstrates that Baldwin’s classification of linear continua
in terms of admissible periods [Ba] is useless for multivalued maps. 相似文献
25.
Influence of boric acid on the electrochemical deposition of Ni 总被引:1,自引:0,他引:1
M. Šupicová R. Rozik L. Trnková R. Oriňáková M. Gálová 《Journal of Solid State Electrochemistry》2006,10(2):61-68
The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm−3 NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition
is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate
the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as
the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl− and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species
were also confirmed using elimination voltammetry with a linear scan. The evolution of gaseous hydrogen, catalyzed by the
freshly-deposited Ni, accompanies the electrodeposition process. The presence of boric acid at a sufficiently high concentration
inhibits the deposition of Ni and, at the same time, improves the morphology and brightness, as well as the adhesion of the
deposited Ni.
Elimination voltammetry with a linear scan is an efficient way to evaluate current–potential curves that reflect the electrodeposition
of one-component Ni coatings. By eliminating selected currents, additional interesting and useful information can be obtained
from voltammetric data. 相似文献
26.
Pavol Ševera 《Letters in Mathematical Physics》2006,75(3):273-277
We introduce an affine-invariant version of generating functions of symplectic transformations of affine symplectic spaces,
together with a generalization for other symmetric symplectic spaces. The composition of these functions has a nice connection
with the Moyal product. 相似文献
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We treat a free spinless quantum particle moving on a configuration manifold which consists of two identical parts connected in one point. Most attention is paid to the three-dimensional case when these parts are halfspaces with Neumann condition on the boundary; we also discuss briefly a more general boundary conditions. The class of admissible Hamiltonians is constructed by means of the theory of self-adjoint extensions. Among them, particularly important is a two-parameter family whose elements are invariant with respect to exchange of the halfspaces; we compute the transmission coefficient for each of these extensions. We discuss also the motion on two planes considered in our recent paper, obtaining another characterization of the admissible Hamiltonians. In conclusion, the two situations are compared as models for point-contact spectroscopical experiments in thin metal films.On leave of absence fromNuclear Physics Institute, Czechosl. Acad. Sci., 250 68 e near Prague, Czechoslovakia.On leave of absence fromNuclear Centre, Charles University, V Holeovikách 2, 180 00 Prague 8, Czechoslovakia. 相似文献
30.
The time dependence of the electron distribution function in helium afterglow, for pressures of 60–260 Pa, is calculated for the case in which metastable-metastable reactions are present. The time variation of the shape of the distribution function shows that careful consideration must be made of the time derivative of the distribution function in the Boltzmann equation for the calculation of the rate constant of such reactions from experimentally determined distribution function. 相似文献