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61.
We consider statistics of the form
, where the Xj are i.i.d. random variables with finite sixth moment. We obtain the rate of convergence in the central limit theorem for
the one-term Edgeworth expansion. Furthermore, applications to Toeplitz matrices, quadratic form of ARMA-processes, goodness-of-fit,
as well as spacing statistics are included. Bibliography: 16 titles.
Published in Zapiski Nauchnykh Seminarov POMI, Vol. 341, 2007, pp. 81–114. 相似文献
62.
Vestgården JI Shantsev DV Olsen AA Galperin YM Yurchenko VV Goa PE Johansen TH 《Physical review letters》2007,98(11):117002
A theoretical model for how Bloch walls occurring in in-plane magnetized ferrite garnet films can serve as efficient magnetic micromanipulators is presented. As an example, the walls' interaction with Abrikosov vortices in a superconductor in close contact with a garnet film is analyzed within the London approximation. The model explains how vortices are attracted to such walls, and excellent quantitative agreement is obtained for the resulting peaked flux profile determined experimentally in NbSe(2) using high-resolution magneto-optical imaging of vortices. In particular, this model, when generalized to include charged magnetic walls, explains the counterintuitive attraction observed between vortices and a Bloch wall of opposite polarity. 相似文献
63.
I. A. Silanteva A. A. Yurchenko P. N. Vorontsov-Velyaminov 《Polymer Science Series A》2017,59(4):579-591
The method of entropic sampling within the Wang–Landau algorithm (a modern variant of the Monte Carlo method) is used to determine the densities of energy states of a strongly charged star-shaped polyelectrolyte within the framework of the lattice model. The equilibrium thermal and structural properties of the polyelectrolyte with the number of arms f ≤ 6 and the length of arms N arm ≤ 73 in a wide temperature range are determined from the density of states. Such characteristics as the free energy, the mean-squared radius of gyration, its components, and the parameters characterizing the shape of a polyion are calculated. It is found that the concentration, length, and number of arms affect the thermal and structural properties. The main attention is focused on the effect of temperature on these properties. The coil-to-globule transition is detected, while for the polyion with the highest length of arms (N arm = 24) the transition from the liquid globule to the crystal-like one is observed. Differences in the properties of the star-shaped and corresponding linear polyions are characterized. 相似文献
64.
Martínez-Mesa A Yurchenko SN Patchkovskii S Heine T Seifert G 《The Journal of chemical physics》2011,135(21):214701
The physisorption of molecular hydrogen in model carbon foams has been investigated from 50 K to room temperature. The study is carried out within the framework of the density functional theory for quantum liquids at finite temperatures. Calculations are performed in the grand canonical ensemble, i.e., the adsorbed fluid is assumed to be in equilibrium with an external gas of hydrogen molecules with concentrations ranging from 8×10(-4) kg m(-3) to n=71 kg m(-3). It is shown that, while strong zero-point energy effects are present even at room temperature, the adsorption isotherms exhibit only a weak dependence on the explicit incorporation of the bosonic exchange symmetry of hydrogen molecules. The increase of the average particle density prevents the deviations from the Maxwell-Boltzmann statistics to become noticeable if the system is cooled down. The volumetric storage capacity of these materials at low temperatures is about one half of the U. S. Department of Energy goal, while the gravimetric capacity is still far from the standards required by mobile applications. The relation between the microscopic structure of the hydrogen fluid and the calculated adsorption properties is also addressed. 相似文献
65.
Smetanina O. F. Yurchenko A. N. Kalinovsky A. I. Pushilin M. A. Slinkina N. N. Yurchenko E. A. Afiyatullov Sh. Sh. 《Russian Chemical Bulletin》2011,60(4):760-763
The new styrylpyrone derivative, viz. 4-methoxy-3-methylgoniothalamin (1), and the known compound sulochrin were isolated from the marine-derived fungi Penicillium glabrum and P. implicatum. The structure of compound 1 was determined by X-ray diffraction, 2D NMR spectroscopy, and high-resolution mass spectrometry. It was shown for the first
time that sulochrin increases expression of the protein Hsp70. 相似文献
66.
Veronica V. Tomina Gabriella R. Yurchenko Alexandr K. Matkovsky Yuriy L. Zub Aljosa Kosak Aleksandra Lobnik 《Journal of fluorine chemistry》2011,132(12):1146-1151
Hydrolysis and polycondensation reactions of tetraethoxysilane (TEOS) with 3,3,3-trifluoropropyl-trimethoxysilane (TFMS) or 1H,1H,2H,2H-perfluorooctyltriethoxysilane (PFES) were used to synthesize xerogels functionalized with fluorine-containing groups. According to transmission electron microscopy, the skeletons of synthesized polysiloxane xerogels have globular structures and consist of agglomerates of particles with fluorinated groups on their surfaces. FTIR spectroscopy showed that primary xerogel particles possess spatial polysiloxane networks, with fluorinated groups along with silanol groups and water in the surface layer. According to thermal analyses, the water content was 3–8 wt.%, and it decreased with increasing length of the fluorinated chain. Thermal destruction of the surface layer starts above 300 °C. The sorbents that were obtained were predominantly mesoporous materials with well-developed porous structures (SBET = 400–960 m2 g−1, Vs = 0.66–0.93 cm3 g−1). The influence of the TEOS/functional silane ratio and the natures of the functional groups on the structural and adsorptive properties were shown. The samples synthesized are organophilic. The affinity for n-hexane increases with increasing length of the fluorine-containing chain (PFES) and the content of fluorinated groups in the surface layer. The hybrid organic–inorganic materials that were obtained can be used for adsorption of hydrocarbons, including oil, from water. 相似文献
67.
We report a new "spectroscopic" potential energy surface (PES) of formaldehyde (H(2)(12)C(16)O) in its ground electronic state, obtained by refining an ab initio PES in a least-squares fitting to the experimental spectroscopic data for formaldehyde currently available in the literature. The ab initio PES was computed using the CCSD(T)/aug-cc-pVQZ method at 30 840 geometries that cover the energy range up to 44 000 cm(-1) above equilibrium. Ro-vibrational energies of formaldehyde were determined variationally for this ab initio PES by means of the program TROVE [Theoretical ROtation-Vibration Energies; S. N. Yurchenko, W. Thiel, and P. Jensen, J. Mol. Spectrosc. 245, 126 (2007)]. The parameter values in the analytical representation of the PES were optimized in fittings to 319 ro-vibrational energies with J = 0, 1, 2, and 5. The initial parameter values in the fittings were those of the ab initio PES, the ro-vibrational eigenfunctions obtained from this PES served as a basis set during the fitting process, and constraints were imposed to ensure that the refined PES does not deviate unphysically from the ab initio one in regions of configuration space not sampled by the experimental data. The resulting refined PES, referred to as H(2)CO-2011, reproduces the available experimental J ≤ 5 data with a root-mean-square error of 0.04 cm(-1). 相似文献
68.
E. N. Yurchenko V. Yu. Prokofev A. P. Ilyin Yu. G. Shyrokov 《Reaction Kinetics and Catalysis Letters》1997,60(2):269-277
Structure-mechanical and rheological characteristics of pastes on the basis of TiO2 and Al2O3 are discussed. Optinum values to prepare honeycomb supports are determined. 相似文献
69.
70.
E. A. Paukshtis R. I. Soltanov E. N. Yurchenko 《Reaction Kinetics and Catalysis Letters》1981,16(1):93-96
Correlations between the adsorption heats of carbon monoxide on aprotic acidic centers and the v
CO values in IR spectra have been studied. In the case of aprotic centers formed by cations of non-transition metals, v
CO is shown to be linearly dependent on the adsorption heat.
v CO . , , , v CO .相似文献