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51.
A prototype generator for creating a continuous stream of explosive vapor was referenced quantitatively both to a standard weight from the National Institute of Standards and Technology (NIST) and to the response of an ion mobility spectrometer. Vapors from solid explosive, in a precision bore glass tube at constant temperature, diffuse into an inert gas flow. Mass output rates were determined by (1) sample temperature, and (2) sample tube dimensions (length and cross-sectional area). A reference to NIST was achieved gravimetrically though a microbalance calibrated with a reference weight; mass output rates were obtained for 2,4,6-trinitrotoluene (TNT), cyclotrimethylenetrinitramine (RDX) and pentaerythritol tetranitrate (PETN) at three or more oven temperatures between 79 degrees C and 150 degrees C. The mass output rate was stable over hundreds of hours of continuous operation and the output was adjustable from a few picograms per second to several nanograms per second through variation of the oven temperature. An independent calibration of the vapor generator for TNT at 79 degrees C using an ion mobility spectrometer matched exactly the gravimetric-based findings. In most instances, measured mass output rates compared favorably with theoretically calculated mass output rates, with discrepancies in a few cases resulting primarily from uncertainties in terms (vapor pressures and diffusion coefficients) used to perform the calculations. Agreement is generally not good for PETN, where molecular decomposition contributed to higher than expected measured mass outputs. 相似文献
52.
Matiide Angulo Mercedes Ruiz Montoya Rafael Marin Galvin José Miguel Rodriguez Mellado 《Electroanalysis》1997,9(4):345-349
The electroreductions of the NAD+ model compounds nicotinamide (I), N1-methyl nicotinamide (II), N′-methyl nicotinamide (III) and isonicotinamide (IV) on carbon electrodes have been studied in aqueous media in the pH range 0–12 by linear-sweep cyclic voltammetry (Scheme 1, I-IV). Logarithmic analyses of the reduction peaks were performed by computing the convolution of the current with time as a function of the potential. On the basis of the experimental results it was concluded that the irreversibility of the electron transfers increased when a glassy carbon electrode was used, and this irreversibility being more marked when a plastic formed carbon electrode was employed. The reduction processes occurred with more difficulty on carbon electrodes than on mercury electrodes. Both the reduction and the reoxidation (when occurred) processes changed with respect to those observed on mercury electrodes, being irreversible electron transfers the rate-determining steps in most cases. Thus, for compounds I, II and III at pH < 2 the reductions occurred by the uptake of two electrons and two H+ ions, and the rate determining step was found to be the first one-electron transfer, for I and III, and the irreversible second electron transfer, preceded by the uptake of an H+ ion, for II. At pH>3 the processes consisted of electrodimerization reactions, preceded by the protonation of the heterocyclic nitrogen in cases I and III. The second electron transfer of the electroreduction of IV always appeared irreversible, in contrast with that found for mercury electrodes. 相似文献
53.
Elettra L. Piacentino Edwin Rodriguez Kevin Parker Thomas M. Gilbert Richard A. J. O'Hair Victor Ryzhov 《Journal of mass spectrometry : JMS》2019,54(6):520-526
Gas‐phase C―C coupling reactions mediated by Ni (II) complexes were studied using a linear quadrupole ion trap mass spectrometer. Ternary nickel cationic carboxylate complexes, [(phen)Ni (OOCR1)]+ (where phen = 1,10‐phenanthroline), were formed by electrospray ionization. Upon collision‐induced dissociation (CID), they extrude CO2 forming the organometallic cation [(phen)Ni(R1)]+, which undergoes gas‐phase ion‐molecule reactions (IMR) with acetate esters CH3COOR2 to yield the acetate complex [(phen)Ni (OOCCH3)]+ and a C―C coupling product R1‐R2. These Ni(II)/phenanthroline‐mediated coupling reactions can be performed with a variety of carbon substituents R1 and R2 (sp3, sp2, or aromatic), some of them functionalized. Reaction rates do not seem to be strongly dependent on the nature of the substituents, as sp3‐sp3 or sp2‐sp2 coupling reactions proceed rapidly. Experimental results are supported by density functional theory calculations, which provide insights into the energetics associated with the C―C bond coupling step. 相似文献
54.
The volatile fraction from aerial parts (flowers, stems and leaves) of Discaria americana Gillies & Hook (Rhamnaceae) was obtained by hydrodistillation and the chemical composition of this oil was determined by gas chromatography and gas chromatography-mass spectrometry. The major constituents resulted to be 4-methylphenol (15.5%), eugenol (11%), 3-methylindole (9.7%) and alpha-terpineol (6.2%). The essential oil of this plant displayed strong antioxidant activity (DPPH assay) that could be explained by the presence of active compounds like eugenol, 4-methylphenol, alpha-terpineol, linalool, thymol and cis-nerolidol. 相似文献
55.
56.
A new C19 hydroxylated enyne 15, as potential A-ring building block of vitamin D analogues, was synthesized in enantiomerically pure form in nine steps from (−)-(S)-limonene. This short synthesis involved ozonolyzis of 1,2-limonene oxide followed by a Criegee rearrangement, epoxide trans diaxial ring opening by lithium acetylide, elimination, epoxidation and syn β-elimination of the resulting homopropargylic oxirane. 相似文献
57.
Phillips B. Rodriguez R. G. Lau L. D. Steidley S. D. 《Plasma Chemistry and Plasma Processing》2004,24(2):307-323
The effect of showerhead design, number of holes and geometry, in a parallel plate reactor was studied by measuring the concentration of silane reactant by coherent anti-Stokes Raman scattering (CARS) spectroscopy as a function of radio frequency (rf) pulse width and peak power during pulsed power plasma enhanced chemical vapor deposition (PECVD) of silicon nitride thin films. Film deposition rate, stress, SiH/NH ratio, and thickness and index of refraction homogeneity were correlated with the change in silane concentration for each of the three head geometries: radial, square, and asymmetrical. The asymmetrical head caused plasma quality problems which affected the films' qualities. The square pattern showed good mixing qualities, but produced a film with high compressive stress. The radial head provided the most homogenous film, with respect to index of refraction and film thickness. With a 10 ms pulse width, however, the radial head plasma acted as a continuous plasma for depletion and stress data. The showerhead geometry affects plasma qualities, like stability and intensity, and reactant gas velocities, which in turn affect the nitride film thickness, nitride composition, and stress. 相似文献
58.
L. Desdin O. Dominguez J. Moreno L. Alfonso M. Rodriguez 《Journal of Radioanalytical and Nuclear Chemistry》1995,199(4):305-308
Determination of boric acid in high nickel content solutions during nickel cathode production was made by measuring the transmission loss of thermal neutrons. According to industrial requirements, adequate accuracy and reproducibility were obtained. 相似文献
59.
The mechanisms that govern the transport of colloids in the unsaturated zone of soils are still poorly understood, because of the complexity of processes that occur at pore scale. These mechanisms are of specific interest in quantifying water quality with respect to pathogen transport (e.g. Escherichia coli, Cryptosporidium) between the source (e.g. farms) and human users. Besides straining in pore throats and constrictions of smaller or equivalent size, the colloids can be retained at the interfaces between air, water, and grains. Theories competing to explain this mechanism claim that retention can be caused by adhesion at the air-water-interface (AWI) between sediment grains or by straining at the air-water-solid (AWS) contact line. Currently, there are no established methods for the estimation of pathogen retention in unsaturated media because of the intricate influence of AWI and AWS on transport and retention. What is known is that the geometric configuration and connectivity of the aqueous phase is an important factor in unsaturated transport. In this work we develop a computational method based on level set functions to identify and quantify the AWS contact line (in general the non-wetting-wetting-solid contact line) in any porous material. This is the first comprehensive report on contact line measurement for fluid configurations from both level-set method based fluid displacement simulation and imaged experiments. The method is applicable to any type of porous system, as long as the detailed pore scale geometry is available. We calculated the contact line length in model sediments (packs of spheres) as well as in real porous media, whose geometry is taken from high-resolution images of glass bead packs and sedimentary rocks. We observed a strong dependence of contact line length on the geometry of the sediment grains and the arrangement of the air and water phases. These measurements can help determine the relative contribution of the AWS line to pathogen retention. 相似文献
60.
The title amines were pyrolyzed in a stirred-flow reactor at 380–510°C, pressures of 8–15 torr and residence times of 0.3–2.4 s, using toluene as carrier gas. The substrates with an allyl group yielded propene and iminonitriles as reaction products. HCN is formed by decomposition of the iminonitriles. The first-order rate coefficients for propene formation fit the Arrhenius equations
- Allyl cyanomethyl amine:
- Diallyl cyanomethyl amine: