全文获取类型
收费全文 | 546篇 |
免费 | 20篇 |
专业分类
化学 | 309篇 |
晶体学 | 1篇 |
力学 | 16篇 |
数学 | 123篇 |
物理学 | 117篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 29篇 |
2021年 | 23篇 |
2020年 | 25篇 |
2019年 | 19篇 |
2018年 | 17篇 |
2017年 | 11篇 |
2016年 | 28篇 |
2015年 | 24篇 |
2014年 | 29篇 |
2013年 | 33篇 |
2012年 | 49篇 |
2011年 | 43篇 |
2010年 | 26篇 |
2009年 | 24篇 |
2008年 | 31篇 |
2007年 | 30篇 |
2006年 | 23篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 4篇 |
1989年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1973年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有566条查询结果,搜索用时 15 毫秒
91.
Alessio Figalli Young-Heon Kim Robert J. McCann 《Archive for Rational Mechanics and Analysis》2013,209(3):747-795
Consider transportation of one distribution of mass onto another, chosen to optimize the total expected cost, where cost per unit mass transported from x to y is given by a smooth function c(x, y). If the source density f +(x) is bounded away from zero and infinity in an open region ${U' \subset \mathbf{R}^n}$ , and the target density f ?(y) is bounded away from zero and infinity on its support ${\overline{V} \subset \mathbf{R}^n}$ , which is strongly c-convex with respect to U′, and the transportation cost c satisfies the ${\mathbf{A3}_{\rm w}}$ condition of Trudinger and Wang (Ann Sc Norm Super Pisa Cl Sci 5, 8(1):143–174, 2009), we deduce the local Hölder continuity and injectivity of the optimal map inside U′ (so that the associated potential u belongs to ${C^{1,\alpha}_{loc}(U')}$ ). Here the exponent α > 0 depends only on the dimension and the bounds on the densities, but not on c. Our result provides a crucial step in the low/interior regularity setting: in a sequel (Figalli et al., J Eur Math Soc (JEMS), 1131–1166, 2013), we use it to establish regularity of optimal maps with respect to the Riemannian distance squared on arbitrary products of spheres. Three key tools are introduced in the present paper. Namely, we first find a transformation that under ${\mathbf{A3}_{\rm w}}$ makes c-convex functions level-set convex (as was also obtained independently from us by Liu (Calc Var Partial Diff Eq 34:435–451, 2009)). We then derive new Alexandrov type estimates for the level-set convex c-convex functions, and a topological lemma showing that optimal maps do not mix the interior with the boundary. This topological lemma, which does not require ${\mathbf{A3}_{\rm w}}$ , is needed by Figalli and Loeper (Calc Var Partial Diff Eq 35:537–550, 2009) to conclude the continuity of optimal maps in two dimensions. In higher dimensions, if the densities f ± are Hölder continuous, our result permits continuous differentiability of the map inside U′ (in fact, ${C^{2,\alpha}_{loc}}$ regularity of the associated potential) to be deduced from the work of Liu et al. (Comm Partial Diff Eq 35(1):165–184, 2010). 相似文献
92.
Alessio Boldrin Steffen Foss Hansen Anders Baun Nanna Isabella Bloch Hartmann Thomas Fruergaard Astrup 《Journal of nanoparticle research》2014,16(6):1-19
Information related to the potential environmental exposure of engineered nanomaterials (ENMs) in the solid waste management phase is extremely scarce. In this paper, we define nanowaste as separately collected or collectable waste materials which are or contain ENMs, and we present a five-step framework for the systematic assessment of ENM exposure during nanowaste management. The framework includes deriving EOL nanoproducts and evaluating the physicochemical properties of the nanostructure, matrix properties and nanowaste treatment processes as well as transformation processes and environment releases, eventually leading to a final assessment of potential ENM exposure. The proposed framework was applied to three selected nanoproducts: nanosilver polyester textile, nanoTiO2 sunscreen lotion and carbon nanotube tennis racquets. We found that the potential global environmental exposure of ENMs associated with these three products was an estimated 0.5–143 Mg/year, which can also be characterised qualitatively as medium, medium, low, respectively. Specific challenges remain and should be subject to further research: (1) analytical techniques for the characterisation of nanowaste and its transformation during waste treatment processes, (2) mechanisms for the release of ENMs, (3) the quantification of nanowaste amounts at the regional scale, (4) a definition of acceptable limit values for exposure to ENMs from nanowaste and (5) the reporting of nanowaste generation data. 相似文献
93.
We consider a set of macroscopic (classical) degrees of freedom coupled to an arbitrary many-particle Hamiltonian system, quantum or classical. These degrees of freedom can represent positions of objects in space, their angles, shape distortions, magnetization, currents and so on. Expanding their dynamics near the adiabatic limit we find the emergent Newton’s second law (force is equal to the mass times acceleration) with an extra dissipative term. In systems with broken time reversal symmetry there is an additional Coriolis type force proportional to the Berry curvature. We give the microscopic definition of the mass tensor. The mass tensor is related to the non-equal time correlation functions in equilibrium and describes the dressing of the slow degree of freedom by virtual excitations in the system. In the classical (high-temperature) limit the mass tensor is given by the product of the inverse temperature and the Fubini–Study metric tensor determining the natural distance between the eigenstates of the Hamiltonian. For free particles this result reduces to the conventional definition of mass. This finding shows that any mass, at least in the classical limit, emerges from the distortions of the Hilbert space highlighting deep connections between any motion (not necessarily in space) and geometry. We illustrate our findings with four simple examples. 相似文献
94.
A Terenzi C Ducani V Blanco L Zerzankova AF Westendorf C Peinador JM Quintela PJ Bednarski G Barone MJ Hannon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(35):10983-10990
The interaction with native DNA of a 2,7-diazapyrenium-based ligand 1 and its Pt(II) rectangular metallacycle 2 is explored through circular and linear dichroism and fluorescence spectroscopies. The metal-free ligand 1 binds through intercalation, with a binding constant of approximately 5×10(5) M(-1) , whereas the metallacycle 2 binds and bends the DNA with a binding constant of 7×10(6) M(-1) . PCR assays show that metallo-supramolecular box 2 interferes with DNA transactions in vitro whereas the intercalator 1 does not. The metallacycle is active against four human cancer cell lines, with IC(50) values ranging between 3.1 and 19.2?μM and shows similar levels of efficacy, but a different spectrum of activity, to cisplatin. 相似文献
95.
Spectroscopic techniques both in steady-state (in absorption and emission) and pulsed (absorption of excited states with femtosecond resolution) conditions were used to study the complexation process between six molecules belonging to the tetracycline family and Mg(2+); in the case of TC the study was extended to the metal ions Ca(2+) and Cu(2+). The study was carried out in aqueous solution at various pH values, where one acid-base form of the substrate prevails over the others. The processing of experimental results, performed by means of Singular Value Decomposition and Global Analysis methods, allowed us to evaluate the extent of interaction through the association constants, to identify the number of equilibria present in solution and the stoichiometry (1:1 or 1:2) of the tetracycline:metal ion complex, and to define the spectral and photophysical properties of the latter (in terms of fluorescence quantum yields, lifetimes and rate constants). In fact, the (allowed) radiative decay process is a minor root for the lowest excited state of the complexes which mainly decay to the ground state by internal conversion. Details of the complexation sites are proposed for the various protonated forms of tetracyclines, and for the various cations in the case of TC. In particular, the molecular structure seems to affect significantly the dynamics of interaction when the upper peripheral region of tetracycline is rich in additional hydroxyl groups. Moreover, the state of protonation of the substrate produces changes in the order of the complexation sites, whose affinity for the cation increases significantly when they are negatively charged owing to the loss of protons. Magnesium and calcium (hard cations) give similar interactions, at least in acid solution, while copper(ii) (borderline cation) binds more efficiently on different sites, thus forming complexes with different properties. 相似文献
96.
Bratsos I Mitri E Ravalico F Zangrando E Gianferrara T Bergamo A Alessio E 《Dalton transactions (Cambridge, England : 2003)》2012,41(24):7358-7371
With the aim of expanding the structure-activity relationship investigation, the series of Ru(II) half sandwich coordination compounds of the type [Ru([9]aneS3)(chel)(L)](n+) previously described by us (where [9]aneS3 is the neutral face-capping ligand 1,4,7-trithiacyclononane, chel is a neutral or anonic chelating ligand, L = Cl(-) or dmso-S, n = 0-2) was extended to 1,4,7-triazacyclononane ([9]aneN3). In addition, new neutral N-N, and anionic N-O and O-O chelating ligands, i.e. dach (trans-1,2-diaminocyclohexane), pic(-) (picolinate), and acac(-) (acetylacetonate), were investigated in combination with both [9]aneS3 and [9]aneN3. Overall, ten new half-sandwich complexes were prepared and fully characterized and their chemical behaviour in aqueous solution was established. The single-crystal X-ray structures of eight of them, including the versatile precursor [Ru([9]aneN3)(dmso-S)(2)Cl]Cl (9), were also determined. The results of in vitro antiproliferative tests performed on selected compounds against MDA-MB-231 human mammary carcinoma cells confirmed that, in this series, only compounds that hydrolyse the monodentate ligand at a reasonable rate show moderate activity, provided that the chelate ligand is a hydrogen bond donor. 相似文献
97.
Cavallotti C Polino D Frassoldati A Ranzi E 《The journal of physical chemistry. A》2012,116(13):3313-3324
The cyclopentadienyl radical (cC(5)H(5)) is among the most stable radical species that can be generated during the combustion and pyrolysis of hydrocarbons and it is generally agreed that its contribution to the gas phase reactivity is significant. In this study the kinetics of one key cC(5)H(5) reaction channel, namely the reaction between cC(5)H(5) and cyclopentadiene (cC(5)H(6)), was investigated using ab initio calculations and RRKM/Master Equation theory. It was found that most of the excited C(5)H(5)_C(5)H(6) adducts formed by the addition of cC(5)H(5) to cC(5)H(6) decompose back to reactants and that the major reaction products are, in order of importance, indene, vinylfulvene (a most probable styrene precursor), phenylbutadiene, and benzene. The preferred reaction pathway of the C(5)H(5)_C(5)H(6) adduct is started by the migration of the tertiary hydrogen of the C(5)H(5) ring to a vicinal carbon and followed by the β-opening of the C(5)H(6) ring, which is the rate determining step. Successive molecular rearrangements lead to decomposition to the four possible products. The kinetic constants for the four reaction channels, calculated at atmospheric pressure and interpolated in cm(3) mol(-1) s(-1) between 900 and 2000 K, are k(indene) = 10(25.197)T(-3.935)?exp(-11630/T(K)), k(vinylfulvene) = 10(65.077)T(-14.20)?exp(-37567/T(K)), k(benzene) = 10(29.172)T(-4.515)?exp(-20570/T(K)), and k(phenylbutadiene) = 10(16.743)T(-1.407)?exp(-11804/T(K)). The predictive capability of the reaction set so determined was tested through the simulations of recent cC(5)H(6) pyrolysis and combustion experiments using a detailed kinetic mechanism. A quantitative agreement with experimental data was obtained by assuming that vinylfulvene converts rapidly to stryrene, increasing its reaction channel by a factor of 2, and assuming that phenylbutadiene rapidly decomposes with equal probability to styrene and benzene. 相似文献
98.
99.
Xheila Yzeiri Massimo Calamante Alessio Dessì Daniele Franchi Andrea Pucci Francesco Ventura Gianna Reginato Lorenzo Zani Alessandro Mordini 《Molecules (Basel, Switzerland)》2021,26(18)
Organic fluorophores have found broad application as emitters in luminescent solar concentrators (LSCs) for silicon photovoltaics. In particular, the preparation of organic conjugated systems with intense light-harvesting ability, emissions in the deep-red and NIR regions, and large Stokes shift values represent a very challenging undertaking. Here, we report a simple and easy way to prepare three symmetrical donor–acceptor–donor (DAD) organic-emitting materials based on a thienopyrazine core. The central core in the three dyes was modified with the introduction of aromatic substituents, aiming to affect their optical properties. The fluorophores were characterized by spectroscopic studies. In all cases, visible-NIR emissions with large Stokes shifts were found, highlighting these molecules as promising materials for the application in LSCs. 相似文献
100.