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51.
52.
A series of 2-aryl-2H-pyrazolo[4,3-c]quinolin-3-ones derivatives 6 and 7 was conveniently prepared. A multistep synthesis was carried out starting from dichloro- and bromoanilines (1a-b) and diethyl 2-(ethoxymethylene)malonate using a slightly modified Gould-Jacobs reaction. In this work we present a novel chlorination strategy to prepare quinoline derivatives 4 in excellent yields as key intermediates in the synthesis of the target compounds. Several reaction conditions were evaluated to optimize the formation of pyrazoloquinolinone nucleus. Differences in chemical behavior of both chloroquinolinones 4a-b with aryl and benzyl-hydrazines are also discussed. 相似文献
53.
Marcelo Kobelnik Douglas Lopes Cassimiro Clóvis Augusto Ribeiro Diógenes dos Santos Dias Marisa Spirandeli Crespi 《Journal of Thermal Analysis and Calorimetry》2010,102(3):1167-1173
Two ONNO type naphtaldehyde derivative Schiff base compounds were reduced and two symmetric phenol-amine ligands containing
naphthalene groups were obtained; bis-N,N′[(2-hydroxy-1-naphtyl) methyl]-1,3-propanediamine (NAFLH) and bis-N,N′[(2-hydroxy-1-naphtyl) methyl]-2,2′-dimetyhyl-1,3-propanediamine (NAFLDMH). Homotrinuclear Ni(II) complexes of these ligands were prepared. The solid-state molecular structures of representative
nickel complex of NAFLDMH were determined using single crystal X-ray diffraction analysis. The terminal Ni(II) ions were found to be situated in between
the donor atoms of the organic ligand. The central Ni(II) ion was observed to be bonded via two different μ-bridges. The phenolic
oxygens and carboxylate ion were seen to form two different μ-bridges. TG analysis proved that the compounds have different
thermal characteristics than those cited in literature. The complexes showed extreme exothermic degradation reactions in inert
atmosphere. The complexes are ruptured with a two stepped exothermic reaction which appears huge heat over 300 °C. The heat
appeared in O2 atmosphere is observed to be higher than the heat appeared in inert atmosphere. Revealed heat is observed to be higher than
the conventional explosive materials. 相似文献
54.
55.
Hironori Tohmyoh M. A. Salam Akanda Masumi Saka 《Applied Physics A: Materials Science & Processing》2011,103(2):285-291
A mechanical testing methodology for determination of elastic-plastic properties of very thin metallic wires using small-span
bending under lateral load is described. Sufficient strain is locally developed in the tested section of wire by unsymmetrical
bending with two opposite probes where one end of the wire is fixed on a substrate with rigid joint by Joule heat welding.
From the load-displacement relationships obtained experimentally, Young’s modulus is determined by analytical formulation.
Moreover, yield stress and hardening modulus of the wire are identified using an optimization strategy with finite-element
analyses. The thin Pt wires with a nominal diameter of about 625 nm are examined by the testing scheme and the wires are found
to have higher yield stress compared to bulk Pt. 相似文献
56.
We give sufficient conditions on a real number β and on a closed set F in a general space of homogeneous type (X,d,μ) in such a way that μ(B(x,d(x,F)))β becomes a Muckenhoupt weight. In order to prove our result, we modify the underlying space so that it becomes 1-Ahlfors regular. 相似文献
57.
58.
59.
Sonia de Almeida Evaneide N. Lima Marisa S. Crespi Clóvis A. Ribeiro Valdir Schalch 《Journal of Thermal Analysis and Calorimetry》2009,97(2):529-533
Urban solid residues are constituted of food remaining, grass leaves, fruit peelings, paper, cardboard, rubber, plastic, etc.
The organic fraction formed represents about 50% during the decomposition yields biogas and leachate, which are sources of
pollution. Residue samples were collected from the landfill in different and cells from several ages and the corresponding
leachate, both after treatments, were submitted to thermal analysis. Kinetic parameters were determined using Flynn–Wall–Ozawa
method. The linear relation between the two kinetic parameters (ln A and E) was verified for organic residue urban’s samples, but not for leachate’s sample. The occurred difference can be attributed
to the constituents present in leachate. 相似文献
60.
Pons M Ahufinger V Wunderlich C Sanpera A Braungardt S Sen De A Sen U Lewenstein M 《Physical review letters》2007,98(2):023003
We demonstrate the possibility of realizing a neural network in a chain of trapped ions with induced long range interactions. Such models permit one to store information distributed over the whole system. The storage capacity of such a network, which depends on the phonon spectrum of the system, can be controlled by changing the external trapping potential. We analyze the implementation of error resistant universal quantum information processing in such systems. 相似文献