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The transformation of chemically bound gold into metallic gold during industrial scale roasting of an arsenical gold ore concentrate from the Fairview Mine, Eastern Transvaal, has been studied quantitatively by197Au Mössbauer spectroscopy. The iron compounds in the concentrate, mainly FeAsS and FeS2 and their transformations during roasting have been studied by57Fe Mössbauer spectroscopy. The bound gold is found to convert into the metal in parallel to the decomposition of FeAsS and the increase in cyanide leachability. this shows that the refractory character of the ore is caused by the chemical bonding of the gold rather than by the physical inclusion of small, discrete metallic particles in the matrix of FeAsS or FeS2. The ratio of thef-factors of gold bound in the FeAsS component of a refractory ore and of metallic gold was determined to bef(Au:FeAsS)/f(Au)=1.48±0.09. 相似文献
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Frédérick Adam Didier Thiébaut Fabrice Bertoncini Marion Courtiade Marie-Claire Hennion 《Journal of chromatography. A》2010,1217(8):1386-1394
This paper reports the conditions of online hyphenation of supercritical fluid chromatography (SFC) with twin comprehensive two-dimensional gas chromatography (twin-GC × GC) for detailed characterization of middle distillates; this is essential for a better understanding of reactions involved in refining processes. In this configuration, saturated and unsaturated compounds that have been fractionated by SFC are transferred on two different GC × GC columns sets (twin-GC × GC) placed in the same GC oven. Cryogenic focusing is used for transfer of fractions into the first dimension columns before simultaneous GC × GC analysis of both saturated and unsaturated fractions. The benefits of SFC–twin-GC × GC are demonstrated for the extended alkane, iso-alkane, alkene, naphthenes and aromatics analysis (so-called PIONA analysis) of diesel samples which can be achieved in one single injection. For that purpose, saturated and unsaturated compounds have been separated by SFC using a silver loaded silica column prior to GC × GC analysis. Alkenes and naphthenes are quantitatively recovered in the unsaturated and saturated fractions, respectively, allowing their identification in various diesel samples. Thus, resolution between each class of compounds is significantly improved compared to a single GC × GC run, and for the first time, an extended PIONA analysis of diesel samples is presented. 相似文献
46.
Andrea Retzbach Joachim Marschall Marion Rahnke Lukas Otto Michaela Maier 《Journal of nanoparticle research》2011,13(12):6231-6244
In this article, we report data from an online questionnaire study with 587 respondents, representative for the adult U.S.
population in terms of age, gender, and level of education. The aim of this study was to assess how interest in science and
knowledge as well as beliefs about science are associated with risk and benefit perceptions of nanotechnology. The findings
suggest that the U.S. public is still rather unfamiliar with nanotechnology. Those who have some knowledge mainly have gotten
it from TV and the Internet. The content of current media reports is perceived as fairly positive. Knowledge of scientific
methods is unrelated to benefit and risk perceptions, at least when other predictors are controlled. In contrast, positive
beliefs about science (e.g., its impact on economy or health) and more sophisticated epistemological beliefs about the nature
of scientific knowledge are moderately linked to more positive perceptions of nanotechnology. The only exception is the perception
of scientific uncertainty: This is associated with less positive evaluations. Finally, higher engagement with science is associated
with higher risk perceptions. These findings show that laypersons who are engaged with science and who are aware of the inherent
uncertainty of scientific evidence might perceive nanotechnology in a somewhat more differentiated way, contrary to how it
is portrayed in the media today. 相似文献
47.
Effects of wall-based skin-friction drag reduction strategies on the statistical properties of large-scale motions in moderate Reynolds number turbulent flows have been investigated by exploiting Direct Numerical Simulation of turbulent channels. To educe large scales, a new efficient parallel distributed memory algorithm has been implemented which delivers data-driven modes of increasing characteristic lengthscales: the Fast and Adaptive Bidimensional Empirical Mode Decomposition (FABEMD). The influence of wall-based skin friction reduction on large scales is studied by comparing single point statistics, such as r.m.s. fluctuations, and two-point statistics, as cross-correlation functions in controlled and uncontrolled channel flow fields at constant friction Reynolds number. The traditional way of observing large-scale footprinting at the wall, as cross-correlation of the streamwise velocity components at different wall distances, has been found to be unreliable when comparing drag-reduced flows, due to the arbitrary choice of a reference plane in the logarithmic layer. A more sound way of observing the footprinting via the correlation of the streamwise velocity with the friction velocity is addressed and shows an increase of the footprinting in drag-reduced flows. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
48.
Graziano Bonetti Patrick Pibarot Alain Chaintreau Jean Paul Marion 《Journal of separation science》1992,15(5):305-306
The use of diethylene glycol monoethyl ether as a flavor solvent is restricted. Since existing methods of quantitation are tedious or require sophisticated multi-dimensional GC instrumentation, a simple method has been developed using low cost GC-MS. Monitoring of ions 31 and 45 enables quantitation of DEGEE in essential oils at levels down to 1 μg/g with accuracy equal to or better than 15%. 相似文献
49.
Phase memory decays were obtained from the transient signals sampled within 50 ns of laser excitation by time resolved electron spin echo (ese) spectroscopy in normal protonated, deuterated, deuterated 15N photosynthetic algae and broken chloroplasts. Previously, it has been shown that application of time resolved ese to study these systems, in particular, gives rise to two kinds of signals (standard and special ese). The standard ese signal at g = 2.0023 and the special ese signal exhibit similar electron spin echo envelope modulation (eseem). The modulation frequency and pattern can be identified with that obtained from stable oxidized P700 in the same system. The two lower field resonances of the standard ese signal do not show eseem. The results support the proposed mechanism for formation of special ese and the notion that the standard ese is due to at least two radicals. It is also demonstrated that we can observe eseem of P+700 under ambient temperature conditions. 相似文献
50.
Dr. Jorge Pascual Dr. Diego Di Girolamo Marion A. Flatken Mahmoud H. Aldamasy Guixiang Li Dr. Meng Li Prof. Antonio Abate 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(12):e202103919
In 2020 dimethyl sulfoxide (DMSO), the ever-present solvent for tin halide perovskites, was identified as an oxidant for SnII. Nonetheless, alternatives are lacking and few efforts have been devoted to replacing it. To understand this trend it is indispensable to learn the importance of DMSO on the development of tin halide perovskites. Its unique properties have allowed processing compact thin-films to be integrated into tin perovskite solar cells. Creative approaches for controlling the perovskite crystallization or increasing its stability to oxidation have been developed relying on DMSO-based inks. However, increasingly sophisticated strategies appear to lead the field to a plateau of power conversion efficiency in the range of 10–15 %. And, while DMSO-based formulations have performed in encouraging means so far, we should also start considering their potential limitations. In this concept article, we discuss the benefits and limitations of DMSO-based tin perovskite processing. 相似文献